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金属矿山 ›› 2014, Vol. 43 ›› Issue (01): 167-171.

• 综合利用 • 上一篇    下一篇

内蒙古某煤矸石制备沸石试验

陈莉荣,张娜,杜明展,刘文   

  1. 内蒙古科技大学能源与环境学院,内蒙古 包头 014010
  • 出版日期:2014-02-14 发布日期:2014-02-25
  • 基金资助:

    内蒙古自治区高等学校教学研究项目(编号:NJZY13149)。

Research on Synthesis of Zeolite Using Coal Gangue in Inner Mongolia

Chen Lirong,Zhang Na,Du Mingzhan,Liu Wen   

  1. College of Energy and Environment,Inner Mongolia University of Science and Technology,Baotou 014010,China
  • Online:2014-02-14 Published:2014-02-25

摘要: 煤矸石作为一种巨量固体废弃物,研究其开发利用途径,对建设环境友好、资源节约型国家具有重要意义。以内蒙古某煤矸石为原料、模拟稀土生产的氨氮废水为吸附对象,采用碱熔—陈化—晶化工艺,研究了焙烧温度、陈化过程液固比、陈化时间、晶化时间对合成沸石吸附模拟废水中氨氮性能的影响。结果表明,在焙烧温度为600 ℃、陈化过程的液固比为14 mL/g、陈化时间为20 h、晶化时间为1 h条件下合成的煤矸石沸石对模拟废水中的氨氮具有较好的吸附性能,对应的氨氮吸附量为3.74 mg/g,去除率达74.80%。产品的SEM和XRD分析表明,碱熔使煤矸石组成发生了改变,碱熔产物经陈化—晶化,获得了结晶度较好的煤矸石合成沸石,该沸石属于A型沸石。

关键词: 煤矸石, 沸石, 碱熔法, 陈化, 晶化, 氨氮

Abstract: As huge volume of solid wastes,study on how to exploit and utilize coal gangue has a vital significance to establishing an environment friendly and resource saving country.The effects of roasting temperature,solid-liquid ratio in aging,aging time,crystallization time on absorption properties of simulated ammonia nitrogen wastewater with zeolite synthesis were studied by process of alkali fusion-aging-crystallization,using coal gangue from Inner Mongolia as raw material and ammonia-nitrogen wastewater from simulating production of rare earth as absorbing object.The result showed that with the roast temperature of 600 ℃,the liquid-solid ratio 14 mL/g,for 20 h's aging and 1 h's crystallization,the synthesized coal gangue zeolite had a good adsorption property to ammonia-nitrogen wastewater,with the adsorption capacity of ammonia-nitrogen at 3.74 mg/g,and the removal rate of up to 74.80%.SEM and XRD analysis on the products showed that alkali fusion changed the composition of coal gangue,and the synthesized zeolite with relatively better crystallinity was obtained after alkali fusion product were aged and crystallized.This zeolite belongs to A-type zeolite.

Key words: Coal gangue, Zeolite, Alkali fusion, Aging, Crystallization, Ammonia-nitrogen