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金属矿山 ›› 2018, Vol. 47 ›› Issue (12): 67-72.

• 矿物工程 • 上一篇    下一篇

浮选过程中的泡沫夹带研究进展

李洪强1,郑惠方1,戈武1,翁孝卿1,宋少先2,肖林波3   

  1. 1. 武汉工程大学兴发矿业学院,湖北 武汉 430073;2. 武汉理工大学资源与环境工程学院,湖北 武汉 430070;3. 湖北三宁化工股份有限公司,湖北 枝江 443206)
  • 出版日期:2018-12-15 发布日期:2019-01-17
  • 基金资助:

    基金项目:国家自然科学基金青年基金项目(编号:51504176),湖北省技术创新专项重大项目(编号:2017ACA187),湖北省大学生创新创业训练计划项目(编号:201710490023),武汉工程大学科学研究基金项目(编号:K201728)。

A Review of Froth Entrainment in Flotation Process

Li Hongqiang1,Zheng Huifang1,Ge Wu1,Weng Xiaoqing1,Song Shaoxian2,Xiao Linbo3   

  1. 1. Xingfa School of Mining Engineering, Wuhan Institute of Technology,Wuhan 430073,China;2. College of Resource and Environmental Engineering, Wuhan University of Technology,Wuhan 430070,China;3. Hubei Sanning Chemical Co. Ltd,Zhijiang 443206,China
  • Online:2018-12-15 Published:2019-01-17

摘要: 细粒矿物浮选过程中,亲水的脉石矿物泡沫夹带进入精矿中,导致精矿品位降低。揭示泡沫排液及排脉石过程中的相关理论,可以为浮选泡沫结构及泡沫夹带行为的研究提供理论基础。浮选过程中的脉石泡沫夹带是一种普遍现象,脉石夹带回收率与精矿水回收率呈线性关系;两相泡沫排液受重力、毛细作用力(表面张力)、黏滞力控制,不同含液率的两相泡沫排液遵循不同的排液公式;三相泡沫的排脉石过程遵循对流—扩散模型,脉石的夹带回收率受三相泡沫排液速率及脉石颗粒浓度分布控制。浮选操作条件、亲水脉石的特性、矿浆特性以及泡沫结构是影响泡沫夹带的主要因素;优化浮选操作条件,改变浮选流程结构和改变药剂制度可以有效降低脉石的泡沫夹带,提高浮选选择性。未来,还需开发表征浮选三相泡沫特征的方法、装置或仪器,三相泡沫的结构及形态、疏水矿物颗粒与亲水脉石颗粒在泡沫中的运动路径及分布规律、浮选三相泡沫排液及排脉石的数学模型还需要进一步的细致研究。另外,降低脉石泡沫夹带的技术对于部分浮选体系虽有一定效果,但脉石的泡沫夹带尚难以消除,须开发一些革命性的技术。

关键词: 泡沫夹带, 影响因素, 两相泡沫, 三相泡沫

Abstract: In the process of fine mineral flotation, hydrophilic gangue minerals report into concentrate by froth entrainment, which leads to the decrease of concentrate grade. To reveal the theories of water drainage and gangue particles drainage will provide theoretical basis for the research of foam structure and foam entrainment behavior in flotation. The froth entrainment of gangue is a common phenomenon in the process of flotation. There is a liner relationship between recovery of gangue entrainment and recovery of concentrate water. Two-phase foam drainage is controlled by gravity, capillary force (surface tension) and viscous force. The water drainage of two-phase foam with different liquid content follows different drainage formula. The drainage of gangue particles of three-phase foam follows the convection-diffusion model; the entrainment recovery rate of gangue is controlled by the water drainage and the concentration distribution of gangue particles. Flotation operation conditions, hydrophilic gangue characteristics, slurry characteristics and foam structure are the main factors affecting foam entrainment. Optimization of flotation operation conditions, change of flotation flow sheet and reagent scheme can effectively reduce the foam entrainment of gangue and improve flotation selectivity. In the future, it is necessary to develop methods, devices or instruments to characterize three-phase flotation froth. The structure and morphology of three-phase froth, the movement path and distribution law of hydrophobic mineral particles and hydrophilic gangue particles in the froth, the mathematical model of water drainage and gangue drainage in three-phase flotation froth also need to be detailed studied. In addition, although the technologies developed could effectively reduce the foam entrainment of gangue, it is still difficult to eliminate the froth entrainment of gangue, thus some revolutionary technologies must be developed.

Key words: Froth entrainment, Affecting factors, Two-phase foam, Three-phase froth