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金属矿山 ›› 2019, Vol. 48 ›› Issue (02): 71-75.

• 焙烧·磁选 • 上一篇    下一篇

岩浆岩型含钛铁精矿降钛研究

郭文达 1,2,韩跃新1,2,朱一民1,2,李艳军1,2,范志国3   

  1. 1. 东北大学资源与土木工程学院,辽宁 沈阳110819;2. 朝阳东大矿冶研究院,辽宁 朝阳 122606;3. 河北钢铁集团矿业有限公司承德柏泉铁矿,河北 承德 067500
  • 出版日期:2019-02-25 发布日期:2019-04-08
  • 基金资助:

    基金项目:国家自然科学基金重点项目(编号:51734005)。

Research on the Titanium Removal of Titanium-containing Magmatic Iron Concentrate

Guo Wenda1,2, Han Yuexin1,2, Zhu Yimin1,2, Li Yanjun1,2, Fan Zhiguo3   

  1. 1. School of Resources and Civil Engineering ,Northeastern University, Shenyang 110819, China; 2.Chaoyang NEU Mineral and Metallurgy Institute, Chaoyang 122606, China; 3. Chengde Baiquan Iron Mine, Hebei Iron and Steel Group Mining Co.,Ltd, Chengde 067500, China
  • Online:2019-02-25 Published:2019-04-08

摘要: 为了探究通过提高磨矿细度降低河北柏泉磁选铁精矿钛含量的可行性,采用搅拌磨细磨(超细磨)—弱磁选工艺对试样进行降钛研究,在磨矿细度d90为34.7 μm,弱磁选磁场强度为83.6 kA/m的条件下,铁精矿TFe品位可由63.39%增加到65.48%,TFe品位达到一级铁精粉要求,且TFe回收率为97.85%,但铁精矿中杂质TiO2含量仅能降低1.04个百分点。通过XRD分析以及工艺矿物学分析查明,试样中钛主要存在于钛磁铁矿中;搅拌磨细磨(超细磨)—弱磁选工艺可以脱除铁精矿中的钛铁矿和钛赤铁矿,但是钛磁铁矿与磁铁矿属于类质同象,物理化学性质非常相近,难以通过磁选分离,这是该铁精矿的钛元素难以大量脱除的原因。研究结果表明,此类岩浆岩型高钛铁精矿品质较优,但钛不能通过选矿脱除,可用作其他低钛铁精粉高炉冶炼的配料。

关键词: 含钛铁矿, 搅拌磨, 细磨(超细磨), 弱磁选, 降钛, 高炉配料

Abstract: In order to explore the feasibility of reducing the TiO2 content of magnetic iron concentrate from Baiquan mine by increasing the fineness of grinding, fine/ultrafine grinding-low intensity magnetic separation process was used for titanium removal of the titanium-bearing iron concentrate. Under the optimal conditions of grinding fineness d90=34.7 μm and magnetic field intensity of 83.6 kA/m, the TFe grade of iron concentrate could be increased from 63.39% to 65.48%, meeting the requirements of first grade iron concentrate, and the recovery rate was 97.85%. At the same time, the content of impurity TiO2 in iron concentrate could be reduced by 1.04 percentage points. X-ray diffraction analysis and mineralogy characteristics analysis of the titanium-containing concentrate revealed that titanium in the high ferrotitanium concentrate was mainly presented in titanomagnetite. The impurities ilmenite and titanium-hematite could be removed from the high ferrotitanium concentrate by fine/ultrafine grinding-low intensity magnetic separation process. However, titanomagnetite and magnetite belong to the same kind of similarity, and their physicochemical properties are very similar, which is difficult to separate by magnetic separation. This is the reason why the titanium element of the iron concentrate was difficult to remove significantly. The research results show that the titanium in such kind of high-titanium iron concentrate cannot be removed by beneficiation, but its quality is pretty good and it is very suitable for use as ingredients in other low-titanium iron concentrates.

Key words: Titanium-containing iron ore, Stirred mill, Fine/ultrafine grinding, Low intensity magnetic separation, Titanium removal, Furnace ingredients