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金属矿山 ›› 2019, Vol. 48 ›› Issue (02): 125-128.

• 浮选·浮选药剂 • 上一篇    下一篇

新型捕收剂DYM-1对菱镁矿浮选试验

朱一民1,2,孙升1,2,黄玉梅1   

  1. 1.东北大学资源与土木工程学院,辽宁 沈阳 110819;2.难采选铁矿资源高效开发利用技术国家地方联合工程研究中心,辽宁 沈阳 110819
  • 出版日期:2019-02-25 发布日期:2019-04-08

Experimental Study on Flotation of Magnesite by Novel Collector

Zhu Yimin1,2, Sun Sheng1,2, Huang Yumei1   

  1. 1. School of Resources and Civil Engineering, Northeastern University, Shenyang 110819,China;2. National-Local Joint Engineering Research Center of Refractory Iron Ore Resources Efficient Utilization Technology,Shenyang 110819,China
  • Online:2019-02-25 Published:2019-04-08

摘要: 以菱镁矿单矿物及其常见脉石矿物白云石和石英单矿物为研究对象,考察实验室自制改性脂肪酸类捕收剂DYM-1对各单矿物可浮性的影响。单矿物浮选试验结果表明,在25 ℃,矿浆pH=12.0,DYM-1用量为80.0 mg/L时,菱镁矿回收率可达到98%,白云石回收率为73%,石英回收率为21%,菱镁矿与白云石和石英的回收率差值最高,菱镁矿与2种脉石矿物的浮选分离效果最好。对DYM-1及其分别与各单矿物作用前后的红外光谱分析发现,DYM-1与3种单矿物均发生了氢键作用,并且与白云石表面发生了化学吸附;接触角检测结果表明,随着DYM-1用量的增加,菱镁矿和白云石的接触角均逐渐增大,且其接触角随着DYM-1用量增加的变化规律与回收率曲线相对应。

关键词: 菱镁矿, 捕收剂, 吸附机理, 浮选

Abstract: The effects of modified fatty acid collector DYM-1 on the floatability of single minerals magnesite, dolomite and quartz were investigated, using magnesite single mineral and common gangue minerals dolomite and quartz as research object. Single mineral flotation test results show that at 25 ℃, slurry pH=12.0, DYM-1 dose of 80.0 mg/L, magnesite recovery has reached to 98%, the recovery of dolomite was 73%, the recovery of quartz was 21%, recovery difference value of magnesite with dolomite and quartz is the highest, magnesite and the other 2 kinds of gangue minerals flotation separation effect is best. The spectrum analysis of both DYM-1 and its interaction with single minerals showed that the DYM-1 had hydrogen bond with three single minerals and had chemical adsorption with dolomite surface. The contact angle detection showed that with the dosage increase of DYM-1, the contact angle of magnesite and dolomite increased gradually, and the change rule of the contact angle with the increase of DYM-1 dosage corresponded to the recovery curve.

Key words: Magnesite, Collector, Adsorption mechanism, Flotation