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金属矿山 ›› 2019, Vol. 48 ›› Issue (04): 64-70.

• 矿物工程 • 上一篇    下一篇

新疆某铜镍硫化矿选矿工艺研究

王朝1,2,3,卜显忠1,翁存建1,2,3,王鹏程2,3,刘波4,罗仙平1,2,3,5   

  1. 1. 西安建筑科技大学资源工程学院,陕西 西安 710055;2. 青海省高原矿物加工工程与综合利用重点实验室,青海 西宁 810006;3. 青海省有色矿产资源工程技术研究中心,青海 西宁 810006;4. 新疆瑞伦矿业责任有限公司,新疆 哈密 839000;5. 江西理工大学资源与环境工程学院,江西 赣州 341000)
  • 出版日期:2019-04-15 发布日期:2019-05-13
  • 基金资助:

    * 国家自然科学基金项目(编号:50704018,51374116),青海省重大科技专项项目(编号:2018-GX-A7)。

Study on Beneficiation Process of a Copper-Nickel Sulfide Ore in Xinjiang

Wang Zhao1,2,3,Bu Xianzhong1,Weng Cunjian1,2,3,Wang Pengcheng 2,3,Liu Bo 4,Luo Xianping1,2,3,5   

  1. 1. School of Resources Engineering,Xi'an University of Architecture and Technology,Xi'an 710055,China;2. Key Laboratory of Plateau Mineral Processing Engineering and Comprehensive Utilization in Qinghai Province, Xining 810006,China;3. Qinghai Province Nonferrous Mineral Resources Engineering Technology Research Center, Xining 810006,China;4. Xinjiang Ruilun Mining Co., Ltd., Hami 839000,China;5. School of Resources and Environmental Engineering,Jiangxi University of Science and Technology, Ganzhou 341000,China
  • Online:2019-04-15 Published:2019-05-13

摘要: 新疆瑞伦某铜镍硫化矿原矿含铜0.14%,含镍0.51%,属于高镍低铜硫化铜镍矿。原矿中铜品位较低,同时含有大量易泥化的滑石、蛇纹石等脉石矿物,给该铜镍矿的高效回收带来不利影响。为高效开发利用该铜镍硫化矿石,进行了系统的选矿工艺研究。实验室小型闭路试验结果表明:在磨矿细度为-74 μm占75%,以碳酸钠为pH调整剂,硫酸铜为活化剂,水玻璃和CMC为抑制剂,Z-200、丁铵、丁黄和戊黄为捕收剂的条件下,经2粗4精3扫铜镍混合浮选,铜镍混合精矿以石灰为pH调整剂、Z-200为捕收剂、BK-204为起泡剂,可获得含铜26.12%、含镍0.55%,铜回收率76.49%、镍回收率0.44%的铜精矿,含镍10.42%、含铜0.39%,镍回收率73.14%、铜回收率9.97%,MgO降至5.88%的镍精矿。试验解决了镍精矿中氧化镁杂质含量较高的问题,提高了精矿质量,可以为现场生产提供理论依据。

关键词: 混合浮选, 镍黄铁矿, 黄铜矿, 蛇纹石, 滑石

Abstract: The raw ore of Xinjiang Ruilun copper-nickel ore contains 0.14% copper and 0.51% nickel, belonging to the high nickel and low copper sulfide copper-nickel ore. The copper grade in the ore is relatively low, and contains a large number of gangue minerals such as talc and serpentine which are easily muddy, which adversely affects the efficient recovery of the copper-nickel sulfide ore. In order to efficiently develop and utilize the copper-nickel sulfide ore, a systematic beneficiation process was carried out. The laboratory closed-circuit test results show that: the fineness of grinding is -74 μm, accounting for 75%, sodium carbonate is used as pH regulator, copper sulfate is used as activator, and sodium silicate and CMC are depressant. Z-200, ammonium butyl aerofloat, butyl xanthate and amyl xanthate are the collectors, after two roughing, four cleaning, three scavenging copper-nickel mixed flotation, copper-nickel mixed concentrate with lime as pH regulator, Z-200 as collector, BK-204 as foaming agent. Copper concentrate containing 26.12% copper, 0.55% nickel, 76.49% copper recovery and 0.44% nickel recovery, nickel concentrate containing 10.42% nickel, 0.39% copper, 73.14% nickel recovery, and 9.97% copper recovery was obtained. The MgO is reduced to 5.88% in nickel concentrate. It solves the problem of high content of magnesium oxide impurities in nickel concentrate, improves the quality of concentrate and provides theoretical basis for on-site production.

Key words: Mixed flotation, Nickel pyrite, Chalcopyrite, Serpentine, Talc