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金属矿山 ›› 2019, Vol. 48 ›› Issue (05): 183-187.

• 综合利用 • 上一篇    下一篇

铜渣转底炉直接还原回收铁锌工艺研究

刘占华1,陈文亮1,丁银贵1,曹志成1,吴道洪1,余文2   

  1. 1. 江苏省冶金设计院有限公司北京分公司,北京 102200;2. 江西理工大学资源与环境工程学院,江西 赣州 341000
  • 出版日期:2019-05-15 发布日期:2019-07-03
  • 基金资助:

    江西省自然科学基金资助项目(编号:20171BAB216021),中国博士后基金面上资助项目(编号:2018M642591)。

Study on Recovery of Iron and Zinc from Copper Slag by Direct Reduction Process in Rotary Hearth Furnace

Liu Zhanhua1,Chen Wenliang1,Ding Yingui1,Cao Zhicheng1,Wu Daohong1,Yu Wen2   

  1. 1. Beijing Branch of Jiangsu Metallurgical Design Institute Co., Ltd., Beijing 102200 ,China; 2. School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000 ,China
  • Online:2019-05-15 Published:2019-07-03

摘要: 为解决国内某铜渣的开发利用问题,以兰炭为还原剂、白云石为添加剂,采用模拟转底炉直接还原—磨矿—磁选工艺,对有价元素铁、锌的回收及杂质硫的脱除进行了研究。结果表明:在兰炭用量为25%,白云石用量为10%,还原温度为1 300 ℃,还原时间为35 min情况下,直接还原过程的锌脱除率为99.14%,可获得ZnO含量为79.59%的氧化锌粉,金属化球团经磨矿、磁选后,获得了铁品位为92.79%、铁回收率为88.12%、硫含量为0.08%的金属铁粉。机理分析表明,铜渣中的铁橄榄石、磁铁矿相大部分已转变为金属铁相,金属铁颗粒明显聚集长大,最大粒度超过100 μm,且与脉石矿物等存在清晰平滑的界面,有利于后续磨矿、磁选工序得到高品位的金属铁粉。

关键词: 铜渣, 转底炉, 直接还原, 金属铁粉

Abstract: In order to solve the problem of development and utilization of a copper slag in China, the recovery of valuable element iron and zinc, and as well as the removal of impurity sulfur were studied by direct reduction-grinding magnetic separation process in simulated rotary hearth furnace with semi-coke as reducing agent and dolomite as additive. The results showed that the removal rate of zinc in direct reduction process was 99.14%, the ZnO content was 79.59% in zinc oxide powder under the conditions of 25% semi-coke, 10% dolomite, 1 300 ℃ reduction temperature and 35 minutes reduction time, and the metallic iron powder with 92.79% iron grade and 0.08% sulfur content was obtained with an iron recovery of 88.12% by grinding and magnetic separation from metallized pellets. The mechanism analysis showed that most of the iron-bearing minerals in copper slag had been transformed into metallic iron phases, which presented obvious aggregation and growth. The maximum metal iron particles could reach more than 100 microns, and there was a clear edge between the iron and gangue minerals, which would be propitious to obtain high-grade metallic iron powder by subsequent grinding and magnetic separation processes.

Key words: Copper slag, Rotary hearth furnace, Direct reduction, Metallic iron powder