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金属矿山 ›› 2019, Vol. 48 ›› Issue (09): 199-200.

• 综合利用 • 上一篇    

改性粉煤灰对镍渣基地聚合物力学性能的影响

翟牧楠1,2,诸华军2,梁广伟1,2,吴其胜2,高胜2,华苏东3   

  1. 1. 江苏大学材料科学与工程学院,江苏 镇江 212013;2. 盐城工学院材料科学与工程学院,江苏 盐城224051;3. 南京工业大学材料科学与工程学院,江苏 南京211816
  • 出版日期:2019-09-15 发布日期:2019-10-10
  • 基金资助:

    基金项目:国家自然科学基金项目(编号:51502259),住房和城乡建设部科学技术项目(编号:2015-K4-007),江苏省“六大人才高峰”项目(编号:2016-XCL-070),江苏省重点研发计划项目(编号:BE2018697)。

Effect of Modified Fly Ash on Mechanical Properties of Nickel Slag-based Geopolymer

Zhai Munan1,2,Zhu Huajun2,Liang Guangwei1,2,Wu Qisheng2,Gao Sheng2,Hua Sudong3   

  1. 1. School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China;2. School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China;3. School of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China
  • Online:2019-09-15 Published:2019-10-10

摘要: 在碱激发剂作用下制备镍渣基地聚合物,考察自制改性粉煤灰对地聚合物力学性能的影响,并结合XRD、IR和SEM等测试方法,对试块的微观结构和性能进行研究。结果表明:改性粉煤灰的掺入有利于镍渣基地聚合物力学性能的提高。当改性粉煤灰掺量为20%时效果最佳,50 ℃养护7 d时地聚合物的抗折强度和抗压强度分别比镍渣地聚合物提高了32.0%和20.2%。主要是改性粉煤灰颗粒表面含有的β-C2S参与反应后产生更多的凝胶相,有利于改善地聚合物结构的致密性,增强与改性粉煤灰颗粒表面碱激发产物的胶结能力。同时,钙源的引入也有助于改性粉煤灰在碱溶液的溶解,提高体系反应速率。

关键词: 镍渣, 地聚合物, 改性粉煤灰

Abstract: The nickel slag-based geopolymer was prepared by alkali activators and the effect of self-made modified fly ash (MFA) on the mechanical properties of geopolymer was investigated. XRD, IR and SEM test techniques were adopted to study microstructure and properties of the products. The results showed that: the addition of MFA is beneficial to the mechanical properties improvement of nickel slag-based geopolymer. The best effect occurs with the replacement of 20% MFA. After maintaining at 50 ℃ for 7 days, the flexural strength and compressive strength of geopolymer increased by 32.0% and 20.2%, respectively. β-C2S on the surface of MFA particles took part in the reaction, which helped to produce more gel phase. Therefore, the structure compactness of geopolymer was improved and the cementation ability with the MFA particle surface production were enhanced. Meanwhile, the introduction of the calcium sources is beneficial to the dissolution of MFA in the alkali solution and accelerates the reaction rate of the system.

Key words: Nickel slag, Geopolymer, Modified fly ash