欢迎访问《金属矿山》杂志官方网站,今天是 分享到:
×

扫码分享

金属矿山 ›› 2020, Vol. 49 ›› Issue (09): 214-220.

• 综合利用 • 上一篇    

高岭土/锰尾矿渣-秸秆复合保温材料的制备及其性能研究

梁秋群,刘 峥,梁楚欣,杨瑞善,张淑芬   

  1. 1. 桂林理工大学化学与生物工程学院,广西 桂林 541004;2. 广西电磁化学功能物质广西区重点实验室,广西 桂林 541004;3. 大连理工大学精细化工重点实验室,辽宁 大连 116024
  • 出版日期:2020-09-15 发布日期:2020-10-19
  • 基金资助:
    “广西特聘专家”专项经费项目(编号:N02401007012)

Study on Preparation and Properties of Composite Insulation Materials with Kaolin/Manganese Tailings Slag and Straw

LIANG Qiuqun,LIU Zheng,LIANG Chuxin,YANG Ruishan,ZHANG Shufen   

  1. 1. College of Chemical and Biological Engineering, Guilin University of Technology, Guilin 541004, China; 2. Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, Guilin 541004, China; 3. Key Laboratory of Fine Chemical Engineering of Dalian University of Technology, Dalian 116024, China
  • Online:2020-09-15 Published:2020-10-19

摘要: 锰尾矿渣含有丰富的Si、Al等元素,可作为制备地聚物原料。为考察锰尾矿渣结合稻草秸秆作为保温材料的可能性,利用锰尾矿渣代替部分偏高岭土制备地聚物,并结合稻草秸秆,制备高岭土/锰尾矿渣-秸秆复合保温材料。研究了在自然条件下养护不同时间,添加不同掺量的稻草秸秆对复合保温材料力学性能、导热系数的影响。结果表明,当稻草秸秆粉掺量为3%,养护28 d时,复合保温材料抗压强度达到71.8 MPa,抗折强度达到9.8 MPa,导热系数为0.065 W/(m·K),密度为265 kg/m3,主要指标达到《建筑行业标准》(JG 158—2004)的要求。对高岭土/锰尾矿渣-秸秆复合保温材料进行耐高温实验,结果表明,当煅烧温度低于200~500 ℃时,地聚物对秸秆具有一定的保护作用。研究成果对提高锰尾矿渣、稻草秸秆的综合利用程度有一定的促进作用。

关键词: 高岭土, 锰尾矿渣, 秸秆, 复合保温材料, 力学性能

Abstract: Manganese tailings slag is rich in elements such as silicon and aluminum, which could be used as a raw material for preparing geopolymers. In order to investigate the possibility of combining manganese tailings slag with straw stalk as an insulation material, manganese tailings slag was used to replace some metakaolin for preparing geopolymer. After combining with straw stalk, kaolin/manganese tailings slag and straw composite insulation material was prepared. The effect of diffirent curing time under natural conditions and adding different proportions of straw on the mechanical properties and thermal conductivity of composite thermal insulation materials were studied. The results showed that when the addition of straw stalk powder was 3%, the compressive strength of the composite insulation material reaches 71.8 MPa after 28 days of curing with the flexural strength of 9.8 MPa, the thermal conductivity of 0.065 W/(m·K) and the density of 265 kg/m3. The main indicators meet the requirements of national standard Constrcution Industry Standard (JG 158-2004). The high temperature resistance tests of the composite insulation material was conducted. The results showed that the polymer has a certain protective effect on straw when the calcination temperature was lower than 200~500 ℃. The research results of the thesis have a certain promotion effect on improving the comprehensive utilization of manganese tailings and straw.

Key words: kaolin, manganese tailings slag, straw, composite insulation material, mechanical performance