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金属矿山 ›› 2021, Vol. 50 ›› Issue (03): 124-129.

• 矿物工程 • 上一篇    下一篇

重色浮联合选矿工艺回收某花岗岩型锂辉石中的锂

刘广学,彭团儿,刘磊,李树磊   

  1. 1. 中国地质科学院郑州矿产综合利用研究所,河南 郑州 450006;2. 自然资源部多金属矿综合利用评价重点实验室,河南 郑州 450006;3. 中国矿业大学国家煤加工与洁净化工程技术研究中心,江苏 徐州 221116
  • 出版日期:2021-03-15 发布日期:2021-03-17
  • 基金资助:
    中国地质调查局地质调查项目(编号:DD20190186)

Recovery of Lithium from a Granite Type Spodumene by Gravity-color-flotation

LIU Guangxue,PENG Tuaner,LIU Lei,LI Shulei   

  1. 1. Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, CAGS, Zhengzhou 450006, China; 2. Key Laboratory for Polymetallic Ores' Evaluation and Utilization, MNR, Zhengzhou 450006, China; 3. National Engineering Research Center of Coal Preparation and Purification, China University of Mining and Technology, Xuzhou 221116, China
  • Online:2021-03-15 Published:2021-03-17

摘要: 我国锂资源消耗量逐年攀升,而国内矿石型锂资源品位较低,卤水型锂资源开发难度较大,锂精矿产品难以满足国内生产需要。国外某锂辉石跳汰分选中矿作为进口锂精矿的附加产品购进,为探究其选矿 工艺,以矿石性质研究结果为基础,采用重色浮联合选矿工艺进行了选矿试验研究。结果表明:①试样中Li2O含量为3.60%,主要有价矿物为锂辉石,主要脉石矿物为长石、石英和云母。锂辉石粒度大部分在1 mm以上 ,主要脉石和连生体粒度为2 mm以上;②+0.5 mm粗粒原料在重液密度为2.85 g/cm3时,可以获得Li2O含量大于5.5%的锂辉石精矿,精矿作业回收率较高,经计算机模拟所得两段连续重介质旋流器分选预测结果与之契 合度高,工业推广可行性高;③+0.5 mm粗粒原料采用筛分分级—重悬浮液分选流程,在介质密度为2.70 g/cm3的条件下,可以抛掉产率为21.76%,Li2O品位为0.18%的重液尾矿,Li2O在重液尾矿中的金属量损失仅为 1.09%;④重液精矿经色选机分选,精矿Li2O品位由5.73%提高至6.18%,精矿质量提高一个等级,Li2O作业回收率高达89.23%;⑤色选尾矿、重液中矿和-0.5 mm矿石作为混合中矿,其Li2O品位高达2%~3.57%,以自主 研发的EL为锂辉石浮选捕收剂,经“1粗2精2扫”,最终获得Li2O品位6.53%、Li2O作业回收率91.51%的浮选精矿。全流程试验分选指标优异,有效降低了磨矿成本,具有一定工程推广应用价值。

关键词: 锂辉石, 重介质分选, 色选, 浮选

Abstract: The consumption of lithium resources in China is increasing by years. The grade of domestic ore-type lithium resources is low, and the development of brine type lithium resources is difficult. The lithium concentrate products can not meet the domestic production needs. A foreign spodumene jigging middling ore was purchased as an additional product of imported lithium concentrate. In order to explore its beneficiation process, the beneficiation test was carried out based on the research results of ore properties using gravity-color- flotation combination process. The results showed that: ① The content of Li2O in the sample is 3.60%. The main valuable minerals are spodumene, and the main gangue minerals are feldspar, quartz and mica. The granularity of spodumene is more than 1 mm, and the granularity of gangue and aggregate is more than 2 mm. ② When the density of heavy liquid is 2.85 g/cm3, spodumene concentrate with Li2O content greater than 5.5% can be obtained with a higher recovery rate. The predicted results of two-stage continuous heavy medium cyclone separation obtained by computer simulation are in good agreement with the experiment results, and the industrial promotion feasibility is high. ③ The coarse raw material beyond 0.5 mm adopts the process of screening classification and heavy suspension separation. Under the condition of medium density of 2.70 g/cm3, the heavy liquid tailings with yield of 21.76% and Li2O grade of 0.18% can be discarded. The metal loss of Li2O in the heavy liquid tailings is only 1.09%. ④ After the separation of heavy liquid concentrate by color separator, the grade of Li2O was increased from 5.73% to 6.18%, the concentrate quality was improved by one grade, and the recovery rate of Li2O was as high as 89.23%. ⑤ Color-separation tailings, heavy liquid middlings and ores below 0.5 mm were regarded as mixed middlings with the Li2O grade up to 2%~3.57%, a flotation concentrate with Li2O grade of 6.53% and Li2O operation recovery of 91.51% was finally obtained through "one roughing, two cleaning and two scavenging" with self-developed EL as spodumene flotation collector. The whole process test separation index is excellent, which effectively reduce the cost of grinding and has a certain value of engineering promotion and application.

Key words: spodumene, heavy media dressing, color sorting, flotation