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金属矿山 ›› 2022, Vol. 51 ›› Issue (01): 53-59.

• 工业固废资源化利用新理论与新技术 • 上一篇    下一篇

钢渣基多固废掺合料制备水泥砂浆及其力学性能研究

王宏宇1顾晓薇1张延年2胥孝川1王青1   

  1. 1.东北大学智慧水利与资源环境科技创新中心,辽宁 沈阳 110819;2.沈阳建筑大学土木工程学院,辽宁 沈阳 110168
  • 出版日期:2022-01-15 发布日期:2022-02-14
  • 基金资助:
    “十三五”国家重点研发计划项目(编号:2019YFC1907202);辽宁省重大科技专项(编号:2020JH1/10300005);辽宁省“兴辽英才计划”项目(编号:XLYC1905016)

Study on Preparation and Mechanical Properties of Cement Mortar with Steel Slag Based Solid Waste Admixture

WANG Hongyu1GU Xiaowei1ZHANG Yannian2XU Xiaochuan1WANG Qing1   

  1. 1.Technology Innovation Center for Intelligent Water Resources and Environment,Northeastern University,Shenyang 110819,China;2.School of Civil Engineering,Shenyang Jianzhu University,Shenyang 110168,China
  • Online:2022-01-15 Published:2022-02-14

摘要: 为解决钢渣粉作为单一掺合料的活性指数低的问题,将钢渣与粉煤灰、锂渣、磷渣复掺制备钢渣基多固废水泥砂浆。通过力学性能测试,讨论掺合料配合比对二元、三元钢渣基多固废掺合料活性的影响。利用XRD、SEM手段对典型掺合料水化产物及微观形貌进行分析。结果表明:钢渣早期和后期均表现出较低的活性,锂渣具有良好的早期活性,而磷渣早期强度较差;二元掺合料中钢渣-锂渣活性最高且大于两者单掺,钢渣、锂渣在碱性环境下发生水化并提供不同的活性组分,有利于砂浆强度的提升;三元掺合料中钢渣-磷渣粉-锂渣复掺比例为5∶1∶4时,砂浆抗压强度最高,28 d砂浆抗压强度37.21 MPa。钢渣、锂渣发生水化反应的同时,磷渣中硅酸盐玻璃体在碱性环境激发下解离出活性SiO2,生成了更多的C—S—H等水化产物,三者具有一定耦合作用。

关键词: 钢渣粉, 矿物掺合料, 水泥砂浆, 抗压强度, 活性指数

Abstract: In order to solve the problem of low activity index of steel slag powder as admixture,steel slag was mixed with fly ash,lithium slag and phosphorus slag to obtain multiple composite admixture.Through the mechanical performance test,the influence of the admixture ratio on the activity of the binary and ternary steel slagbased multisolid waste admixture was discussed.XRD and SEM were used to analyze the hydration products and microscopic morphology of typical admixtures.The results show that steel slag exhibits lower activity in the early and late stages,lithium slag has good early activity,and phosphorous slag has poor early strength.Among the binary admixtures,the steel slaglithium slag has the highest activity and is greater than the two alone.The steel slag and the lithium slag are hydrated in an alkaline environment and provide different active components,which is beneficial to the improvement of the strength of the mortar.When the steel slagphosphorus slag powderlithium slag compounding ratio is 5∶1∶4 in the ternary admixture,the compressive strength of the mortar is the highest,and the compressive strength of the 28 d mortar is 37.21 MPa.While steel slag and lithium slag undergo hydration reaction,the phosphorous slag silicate glass body dissociates active SiO2 under the excitation of alkaline environment,and more hydration products such as C—S—H are generated.Steel slag,lithium slag and phosphorous slag have a certain coupling effect.

Key words: steel slag powder, mineral admixture, cement mortar, compressive strength, activity index