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金属矿山 ›› 2022, Vol. 51 ›› Issue (01): 76-82.

• 工业固废资源化利用新理论与新技术 • 上一篇    下一篇

以铁尾矿为主的多元固废混凝土抗压性能与微观结构研究

杨博涵1张延年1顾晓薇2崔长青1韩东3闫飞3   

  1. 1.沈阳建筑大学土木工程学院,辽宁 沈阳 110168;2.东北大学智慧水利与资源环境科技创新中心,辽宁 沈阳 110819;3.辽宁省产品质量监督检验院,辽宁 沈阳 110032
  • 出版日期:2022-01-15 发布日期:2022-02-14
  • 基金资助:
    “十三五”国家重点研发计划项目(编号:2019YFC1907202);辽宁省重大科技专项(编号:2020JH1/10300005)

Study on Compressive Strength and Microstructure of Multicomponent Solid Waste Concrete with Containing Iron Tailings as the Main Material

YANG Bohan1ZHANG Yannian1GU Xiaowei2CUI Changqing1HAN Dong3YAN Fei3   

  1. 1.School of Civil Engineering,Shenyang Jianzhu University,Shenyang 110168,China;2.Technology Innovation Center for Intelligent Water Resources and Environment,Northeastern University,Shenyang 110819,China;3.Liaoning Provincial Product Quality Supervision and Inspection Institute,Shenyang 110032,China
  • Online:2022-01-15 Published:2022-02-14

摘要: 为实现铁尾矿、煤矸石等固废再利用,降低混凝土水泥用量,并缓解铁尾矿单独作为混凝土掺合料对抗压性能的不利影响,以铁尾矿-煤矸石-粉煤灰为复合掺合料,考察了复合掺合料掺量和配比对混凝土抗压强度及微观结构的影响。结果表明:①复合掺合料的掺入降低了混凝土的抗压强度,掺量为20%时对后期抗压强度影响较小,28 d抗压强度可达421 MPa,达到C40混凝土标准;掺量为30%时28 d抗压强度最高可达384 MPa。②铁尾矿材料活性较低,单独作为掺合料劣化了混凝土抗压性能,但其具有填充效应以及分散作用;粉煤灰和煤矸石都具有一定的火山灰活性,粉煤灰活性较高且具有滚珠效应,对混凝土抗压强度的贡献高于煤矸石;铁尾矿与粉煤灰、煤矸石协同作用缓解了铁尾矿单独作为掺合料对混凝土抗压性能的劣化,最优掺入比例为1∶2∶2。③掺量为20%的复合掺合料促进了界面过渡区附近的水泥水化,但劣化了整体孔结构,掺量为30%的复合掺合料优化了混凝土孔结构,明显降低了界面过渡区的孔隙率,但对水泥水化产生了消极影响。研究结果表明,复合掺合料改变了界面过渡区的孔隙率和水化进程,平衡界面过渡区的孔结构和水化进程是提高混凝土宏观强度的关键。

关键词: 铁尾矿, 煤矸石, 抗压强度, 孔结构, 水化进程

Abstract: In order to realize the reuse of iron tailings,coal gangue and other solid wastes,reduce the dosage of cement in concrete,and ease of iron tailings as concrete admixture solely against the negative impact of the compressive strength,composite admixture was prepared with the iron tailings,coal gangue and fly ash.The influence of dosing and ratio of composite admixtures on the compressive strength and microstructure of concrete were investigated.The results indicated: ①The addition of composite admixture reduces the compressive strength of concrete.When the contents of composite admixture was 20%,it has little influence on the compressive strength at the later stage,and the compressive strength at 28 d ages could reach 421 MPa,reaching the standard of C40 concrete.When the contents of composite admixture was 30%,the maximum compressive strength reached 384 MPa at 28 d ages.② The activity of iron tailings is low,which degrades the compressive properties of concrete as the sole admixtures,but it has the filling effect and dispersive effect.Both fly ash and coal gangue have certain pozzolanic properties.Fly ash has higher activity and ball effect and its contribution to the compressive strength of concrete is higher than coal gangue.The synergistic effect of iron tailings,fly ash and coal gangue alleviates the deterioration of concrete compressive property caused by iron tailings as the sole admixtures,and the optimal admixture mass ratio is 1∶2∶2.③ The composite admixture with 20% contents promotes cement hydration near the interface transition zone,but degrades the overall pore structure.The composite admixture with 30% contents optimizes the pore structure of concrete,obviously reduces the porosity rate of the interface transition zone,but has a negative effect on cement hydration.The results showed that the composite admixtures change the porosity rate and hydration process of the interfacial transition zone,and the balance of the pore structure and hydration process of the interfacial transition zone is the key to improve the macroscopic strength of concrete.

Key words: iron tailings, coal gangue, compressive strength, pore structure, hydration process