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金属矿山 ›› 2022, Vol. 51 ›› Issue (03): 129-136.

• 矿物工程 • 上一篇    下一篇

组合抑制剂在白钨矿与含钙脉石浮选分离中的作用及机理

王超1,2朱一民1,2刘杰1,2张淑敏1,2谢瑞琦1,2   

  1. 1.东北大学资源与土木工程学院,辽宁 沈阳 110819;2.难采选铁矿资源高效开发利用技术国家地方联合工程研究中心,辽宁 沈阳 110819
  • 出版日期:2022-03-15 发布日期:2022-04-02
  • 基金资助:
    国家自然科学基金项目(编号:51974067,51774069)

Effect and Mechanism of Combined Depressent in Flotation Separation of Scheelite and Calcium-containing Gangue Minerals

WANG Chao1,2ZHU Yimin1,2LIU Jie1,2ZHANG Shumin1,2XIE Ruiqi1,2   

  1. 1.School of Resources and Civil Engineering,Northeastern University,Shenyang 110819,China;2.Nationallocal Joint Engineering Research Center of Highefficient Exploitation Technology for Refractory Iron Ore Resources,Shenyang 110819,China
  • Online:2022-03-15 Published:2022-04-02

摘要: 白钨矿是钨金属工业原料的主要来源之一,但其脉石多为萤石、方解石和石英,因表面性质相似而难以获得合格的精矿指标。通过纯矿物浮选试验、红外光谱(FTIR)分析、接触角分析和Zeta电位分析,研究了羧化壳聚糖、木质素磺酸钠、腐植酸钠及组合抑制剂在白钨矿与萤石和方解石常温浮选分离过程中药剂吸附行为及作用机理。浮选试验结果表明,羧化壳聚糖、木质素磺酸钠、腐植酸钠较强地抑制了萤石和方解石,白钨矿也受到略微影响,可浮性差异较小;将木质素磺酸钠与腐植酸钠按质量比4∶1进行组合,命名为DWC1作为抑制剂进行浮选,白钨矿与2种脉石可浮性差异较大。红外光谱、接触角和Zeta电位分析表明,DWC1在白钨矿表面吸附程度要远小于萤石和方解石,且主要吸附形式为化学吸附。

关键词: 白钨矿, 组合抑制剂, 有机抑制剂, 浮选

Abstract: Scheelite is one of the main sources of tungsten industrial raw materials,but its gangues are mostly fluorite,calcite and quartz.It is difficult to obtain qualified concentrate index because of the similar surface properties.Through flotation test for pure mineral,FTIR analysis,contact angle analysis and Zeta potential analysis,the adsorption behavior and mechanism of carboxylated chitosan,sodium lignosulfonate,sodium humate and combined depressents in the flotation separation of scheelite from fluorite and calcite at room temperature were studied.The flotation test results showed that carboxylated chitosan,sodium lignosulfonate and sodium humate strongly restrained fluorite and calcite,scheelite also has a slight effect,and the difference of floatability is small.Sodium lignosulfonate and sodium humate were combined according to the mass ratio of 4∶1 and named DWC-1 as an depressent for flotation.There was a great difference in the flotability between scheelite and the two gangues.Infrared spectrum,contact angle and Zeta potential analysis showed that the adsorption degree of DWC-1 on scheelite surface is much less than that of fluorite and calcite,and the main adsorption form is chemical adsorption.

Key words: scheelite, combined depressent, organic depressent, flotation