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金属矿山 ›› 2022, Vol. 51 ›› Issue (11): 10-22.

• 专题综述 • 上一篇    下一篇

我国地电化学技术主要研究进展与展望

刘攀峰1,2,3 罗先熔1,3 文美兰1,3 郑超杰1,3 欧阳菲1,3 单江涛1 高文1,3
  

  1. 1.桂林理工大学地球科学学院,广西 桂林 541006;2.桂林理工大学环境科学与工程学院,广西 桂林 541006;3.广西隐伏金属矿产勘查重点实验室,广西 桂林 541006
  • 出版日期:2022-11-15 发布日期:2022-12-07
  • 基金资助:
    “十三五”国家重点研发计划项目(编号:2016YFC0600603;2017YFC0602600);国家自然科学基金项目(编号:42203067);桂林理工大学科研启动基金项目(编号:GUTQDJJ2019166)

Main Study Progress and Prospect of Geo-electrochemistry Technology in China

LIU Panfeng1,2,3 LUO Xianrong1,3 WEN Meilan1,3 ZHENG Chaojie1,3 OUYANG Fei1,3SHAN Jiangtao1 GAO Wen1,3 #br#   

  1. 1.College of Earth Sciences,Guilin University of Technology,Guilin 541006,China;2.College of Environmental Science and Engineering,Guilin University of Technology,Guilin 541006,China;3.Guangxi Key Laboratory of Hidden Metallic Ore Deposits Exploration,Guilin 541006,China
  • Online:2022-11-15 Published:2022-12-07

摘要: 在回顾我国地电化学技术发展历史的基础上概述了地电化学技术的发展进程,着重分析了2011年以来地电化学技术在以下几方面取得的研究进展:① 提出了“分段理论”成晕机理,包括成矿相关金属微粒产生(以电化学溶解为主)—金属微粒迁移(分为包气带区和饱水带区)—金属微粒卸载(地球化学障);② 优化了供电电源可控性,实现了地电化学提取过程中相关数据(瞬时电压、电流)的采集与记录,简化了提取电极制作工艺,提高了材料性能,完善了吸附材料(聚氨酯泡塑)预处理方法;③ 对地电化学技术整个流程(样品采集—样品处理—分析测试—报告编写)进行了规范化,并起草了《地电化学测量技术规程(征求意见稿)》;④ 在不同覆盖区(西北荒漠戈壁、东北原始森林、青藏高原冻土、内蒙风成砂等)的典型矿区取得了良好找矿成果,同时在土壤重金属修复中取得了预见性进展。在上述分析的基础上,进一步展望了地电化学技术未来的发展方向:① 从宏观角度研究浅地表(基岩/风化层—土壤)元素含量变化和赋存特征,从微观角度借助高分辨率电子显微镜观测元素迁移形式及可能影响其分布的因素,进一步完善方法机制;② 从轻便化、自动化、商品化角度出发,优化供电装置的时控性、数据储存功能,提升提取装置的可视化程度、环保材料的使用程度,并运用较为成熟的统计学方法提取地电数据中的弱异常信息,尽可能满足勘查市场需求;③ 加快编制相关技术规程,进一步深化地电化学技术在土壤重金属修复领域的应用,增强技术应用的普适性。

关键词: 地电化学, 隐伏矿, 成晕机理, 技术规范, 应用成效

Abstract: Based on a review of the development history of geoelectrochemical technology in China,the development of geoelectrochemical technology is summarized,and the research progress of geoelectrochemical technology made since 2011 is emphatically analyzed as follows:① The halo-forming mechanism of "segmented theory" is put forward,which is divided into the generation process for ore-forming-related metal particles (mainly electrochemical dissolution),the migration process of metal particle (containing aeration and saturated zone),and the unloading process of metal particle (geochemical barrier).② The manufacturing process of extraction electrode is simplified which maximizing the material performance and the preprocessing methods with adsorption material (polyurethane foam) is improved.Meanwhile,the controllability of the instrumentation power supply is optimized which resulting in the reality of relevant data (instantaneous voltage and current) collection and recordation during geo-electrochemical extraction.③ The whole progress of geo-electrochemical technology,from sample collection,processing,testing and analysis is standardized and the Technical Specification of Geo-electrochemical Measurement (Version for Comment) is drafted.④ In terms of application,favoring prospecting results and predictive progress have been respectively achieved not only in different coverage and typical mining areas but also in soil heavy metal remediation.Based on the above discussion results,the future development of geo-electrochemical technology is envisioned from three aspects:① From the macroscopically study perspective of elemental content changes and occurrence forms on the shallow surface (both on bedrock and weathering layer-soil):with the microscopic point of view,to observe the elemental migration forms and factors affecting their distribution with the help of high-resolution electron microscope to further improve the method and mechanism.② based on the concept of portability,automation and commercialization,further attention will be focused on optimizing the time control and data storage function of the power supply,and improving the visualization and application degree of the environmental protection materials for the extraction device,and applying more mature statistical methods to extract weak abnormal information from geoelectric data to meet the demand of the exploration market as far as possible.③ To enhance the universality of technology application in other fields,it is necessary to accelerate the compilation of technical regulations,which can further deepen the application of geo-electrochemistry technology in the field of soil heavy metal remediation.

Key words: geo-electrochemistry,concealed deposit,halo forming mechanism,technical specification,application result