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金属矿山 ›› 2023, Vol. 52 ›› Issue (05): 276-281.

• 矿物工程 • 上一篇    下一篇

SO2 气体介入中非某铜钴矿钴还原浸出反应的新工艺探讨 #br#

沈楼燕1 李文化1 胡申琛1 赵红波2 申 丽2
  

  1. 1. 中国瑞林工程技术股份有限公司,江西 南昌 330031;2. 中南大学资源加工与生物工程学院,湖南 长沙 410083
  • 出版日期:2023-05-15 发布日期:2023-06-15
  • 基金资助:
    国家自然科学基金项目(编号:51704331)。

Discussion on New Process of the Intervention of SO2 Gas into Cobalt Reduction-Leaching Reaction of a Copper-Cobalt Ore in Central Africa #br#

SHEN Louyan1 LI Wenhua1 HU Shenchen1 ZHAO Hongbo2 SHEN Li2 #br#   

  1. 1. China Nerin Engineering Co. ,Ltd. ,Nanchang 330031,China;2. School of Minerals Processing and Bioengineering,Central South University,Changsha 410083,China
  • Online:2023-05-15 Published:2023-06-15

摘要: 针对中非某铜钴矿钴还原浸出工艺中存在钴浸出率低、SO2 气体利用较低、SO2 气体外逸污染环境等难 题,通过 SO2 气体浸出钴的机理研究并结合现场试验研究,创造性采用 SO2 气体加压与常压联合介入的方式,通过 3 种工艺路径联合介入钴还原浸出反应,并研制了配套的专用装备。 新工艺及其专用装备通过 SO2 气体与溶液的充分 混合,有效控制了气体的逸散,显著提升了 SO2 气体的溶解度和利用率,加快了还原浸出剂 Fe2+的再生速率,通过增强 SO 2 与 Fe2+的协同还原浸出作用实现了钴的高效提取。 现场试验数据显示:新工艺及其专用装备能实现 SO2 气体利 用率提升 15 个百分点以上,钴浸出率提高 3 个百分点,在提高钴产能的同时还降低了生产成本,并有效解决 SO2 气体 外逸污染环境问题。 该研究成果能用于指导中非铜钴矿山企业优化改进现有的湿法提取铜钴矿物的生产工艺,显著 提升钴的浸出效率,从而增加钴的产能,并通过提升 SO2 气体利用效率,降低生产成本。

关键词: 中非铜钴成矿带, 协同浸出, SO2气体利用率, 钴浸出率

Abstract: In view of the difficulties in the process of cobalt reduction leaching of a copper-cobalt in Central Africa,such as low cobalt leaching rate,low utilization of SO2 gas,and environmental pollution caused by SO2 gas escape,according to the philosophy study of cobalt leaching with SO2 gas and field tests,the creative mode of SO2 gas pressurization and atmospheric pressure combination intervention is adopted by the intervention of three process routes into cobalt reduction and leaching reaction,and the supporting specialized equipment is developed. The new process and its specialized equipment significantly improve the solubility and utilization rate of SO2 gas by complete mixing of SO2 gas and solution and effective control of gas escape,accelerate the regeneration rate of reducing leaching agent Fe2+,and achieve efficient extraction of cobalt by enhancing the synergistic reduction and leaching of SO2 and Fe2+. The on-site test data showed that the new process and its specialized equipment can achieve an increase in the utilization rate of SO2 gas by above 15 percentage points,and a 3 percentage points increase in cobalt leaching rate. While increasing cobalt production capacity,it also reduces production cost and effectively solves the problem of environmental pollution caused by SO2 gas escaping. The study achievement can be used for optimization guidance of copper-cobalt mine enterprises in Central Africa and improve the existing production process of copper-cobalt minerals extraction by the hydrometallurgical process,significantly improve the leaching efficiency of cobalt,thus increasing the production capacity of cobalt,and reduce production cost by improving SO2 gas utilization rate.

Key words: copper-cobalt metallogenic belt in Central Africa,synergistic leaching,gas utilization rate of SO2,leaching rate of cobalt