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金属矿山 ›› 2023, Vol. 52 ›› Issue (09): 24-28.

• 采矿工程 • 上一篇    下一篇

某金矿全尾砂充填材料改性试验与配比优化研究

陈贺新1 胡立强2
  

  1. 1. 建研地基基础工程有限责任公司,北京 100013;2. 中国建筑科学研究院,北京 100013
  • 出版日期:2023-09-15 发布日期:2023-11-03
  • 基金资助:
    国家自然科学基金项目(编号:51474010)。

Study on Modification and Ratio Optimization of Unclassified Tailings Filling Material in a Gold Mine

CHEN Hexin1 HU Liqiang2 #br#   

  1. 1. CABR Foundation Engineering Co. ,Ltd. ,Beijing 100013,China;2. China Academy of Building Research,Beijing 100013,China
  • Online:2023-09-15 Published:2023-11-03

摘要: 针对某金矿充填材料具有变形大、强度低等问题,通过加入复合外掺料提高全尾砂填料强度、改良其收 缩性能并得出掺料的优化配比。 试验选用的复合材料组分包含矿渣纤维、粉煤灰、生石灰、水泥和尾砂,采用正交试验 确定掺料的最佳比例,并借助矿物衍射和扫描电镜技术,研究了改性材料的微观机理。 结果表明:充填材料的最佳配 比为纤维掺量、粉煤灰掺量、生石灰掺量和水泥掺量分别为 1. 6%、0. 5%、10. 0%和 20. 0%;改性后的填充材料抗折强 度和抗压强度分别提高了 3. 8 和 1. 6 倍且收缩率减小了 120%;XRD 图谱显示出不同的矿物成分随着养护龄期增加 而变化特征,侧面反映了水化反应的全过程;SEM 扫描图像清晰地展现出充填材料孔隙中充满水泥和生石灰颗粒且 矿渣纤维吸附大量溶液凝胶产物,从微观机理角度解释了强度和收缩性能提高的原因,表明强度提高和收缩性能变 化是由于加入掺料改变了原有的微观结构和生成了胶凝产物所致。

关键词: 充填开采, 全尾砂充填材料, 强度, 正交试验

Abstract: Aiming at the problems of large deformation and low strength of the filling material of a gold mine,the strength and shrinkage performance of the total tailings filler were improved by adding compound admixture,and the optimal ratio of admixture was obtained. The composite materials selected in the experiment included slag fiber,fly ash,quicklime,cement and tailing sand. The optimal proportion of additives was determined by orthogonal test. The microscopic mechanism of the modified materials was studied by means of mineral diffraction and scanning electron microscopy. The results show that the best filling material ratio is 1. 6% fiber content,0. 5% fly ash content,10. 0% quick lime content and 20. 0% cement content. The flexural strength and compressive strength of the modified packing are increased by 3. 8 and 1. 6 times respectively,and the shrinkage rate is reduced by 120%. XRD patterns show that different mineral compositions change with increasing curing age,which reflects the whole process of hydration reaction. The SEM scanning images clearly showed that the pores of the filler were full of cement and quicklime particles,and the slag fiber adsorbed a large number of solution gel products,which explained the reason for the improvement of strength and shrinkage properties from the perspective of microscopic mechanism,indicating that the increase in strength and shrinkage properties was due to the addition of additives to change the original microstructure and the formation of gelling products.

Key words: filling mining,unclassified tailings filling material,strength,orthogonal test