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金属矿山 ›› 2023, Vol. 52 ›› Issue (09): 111-116.

• 矿物工程 • 上一篇    下一篇

云南某硫化锑矿石选矿试验研究

何名飞1,2,3 汤优优1,2,3 贾 敏1,2,3 李国俊4 魏顺涛4 盘文周4
  

  1. 1. 广东省科学院资源利用与稀土开发研究所,广东 广州 510650;2. 稀有金属分离与综合利用国家重点实验室,广东 广州 510650;3. 广东省矿产资源开发和综合利用重点实验室,广东 广州 510650;4. 云南木利锑业有限公司,云南 广南 663304
  • 出版日期:2023-09-15 发布日期:2023-11-03
  • 基金资助:
    广东省科学院专项资金项目(编号:2022GDASZH-2022010104,2023GDASZH-2023010104)。

Experimental Study on Beneficiation of A Antimony Sulfide Ore in Yunnan

HE Mingfei1,2,3 TANG Youyou1,2,3 JIA Min1,2,3 LI Guojun4 WEI Shuntao4 PAN Wenzhou4 #br#   

  1. 1. Institute of Resource Utilization and Rare Earth Development,Guangdong Academy of Sciences,Guangzhou 510650,China;2. State Key Laboratory of Rare Metals Separation and Comprehensive Utilization,Guangzhou 510650,China;3. Guangdong Province Key Laboratory of Mineral Resource and Comprehensive Utilization,Guangzhou 510650,China;4. Yunnan Muli Antimony Co. ,Ltd. ,Guangnan 663304,China
  • Online:2023-09-15 Published:2023-11-03

摘要: 为高效开发利用云南某硫化锑矿,在原矿工艺矿物学研究的基础上,对其进行了详细选矿试验研究。 结果表明:矿石中主要有价元素锑品位为 2. 16%,锑主要以硫化物的形式存在,氧化率仅为 4. 15%;锑矿物主要为辉 锑矿,硫化物主要为黄铁矿,脉石矿物以石英、绢云母和方解石为主;辉锑矿的嵌布粒度较粗,主要分布在 0. 02 ~ 2. 56 mm 粒级,磨矿细度-0. 074 mm 占 74. 56%时锑矿物的单体解离度大于 90%。 基于矿石性质研究结果,在磨矿细度 -0. 074 mm 占 74. 56%的条件下,以六偏磷酸钠为分散剂、硝酸铅为活化剂、M7 为捕收剂、松醇油为起泡剂,采用“1 粗 3 精 2 扫”的闭路浮选流程,可获得锑品位为 35. 30%、锑回收率为 93. 52%的锑精矿。 研究结果可为矿山后续中深部 硫化矿石的选别及现有流程的优化提供有益参考。

关键词: 辉锑矿, 锑硫混浮, 浮选, 硫化锑

Abstract: In order to efficiently exploit and utilize an antimony sulfide ore in Yunnan Province,a detailed beneficiation experiment was conducted on the basis of the process mineralogy study of the raw ore. The results showed that the grade of the main valuable element antimony in the ore is 2. 16%,and the antimony mainly exists in the form of sulfide with the oxidation rate of 4. 15%. The antimony mineral is mainly stibnite,the sulfide is mainly pyrite,and the gangue mineral is mainly quartz, sericite and calcite. The distribution size of stibnite is coarse,mainly in the range of 0. 02~ 2. 56 mm. When the grinding fineness of -0. 074 mm is accounting for 74. 56%,the monomer separation degree of stibnite is greater than 90%. Based on the research results of ore properties,under the condition of grinding fineness of -0. 074 mm accounting for 74. 56%,using sodium hmetaphosphate as dispersant,lead nitrate as activator,M7 as collector and terpinol oil as foaming agent,antimony concentrate with a grade of 35. 30% and recovery rate of 93. 52% could be obtained after the closed-circuit flotation process of " one roughing,three cleaning and two scavenging" . The research results can provide a useful reference for the subsequent sorting of sulfide ores in middle and deep mines and the optimization of the existing process.

Key words: stibnite,antimony and sulfur mixed flotation,flotation,antimony sulfide