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金属矿山 ›› 2024, Vol. 53 ›› Issue (2): 97-.

• 采矿工程 • 上一篇    下一篇

聚丙烯纤维磷石膏胶结体早期力学强度特性及 增韧机理研究

张卫中1 周 凯1 孔德华2 吴倩倩1 康钦容1 潘 登3   

  1. 1. 武汉工程大学资源与安全工程学院,湖北 武汉 430073;2. 山东康格能源科技有限公司,山东 济南 250098; 3. 武汉工程大学土木工程与建筑学院,湖北 武汉 430073
  • 出版日期:2024-02-15 发布日期:2024-04-03
  • 基金资助:
    国家自然科学基金项目(编号:52174086);武汉工程大学研究生教育创新基金项目(编号:CX2022583)。

Study on Early Mechanical Strength Characteristics and Toughening Mechanism of Polypropylene Fiber-Phosphogypsum Cement

ZHANG Weizhong1 ZHOU Kai1 KONG Dehua2 WU Qianqian1 KANG Qinrong1 PAN Deng3   

  1. 1. School of Resources and Safety Engineering,Wuhan Institute of Technology,Wuhan 430073,China; 2. Shandong Kangge Energy Technology Co. ,Ltd. ,Jinan 250098,China; 3. School of Civil Engineering and Architecture,Wuhan Institute of Technology,Wuhan 430073,China
  • Online:2024-02-15 Published:2024-04-03

摘要: 在传统水泥基复合材料的研究领域,纤维增强了材料的强度、韧性、延展性和抗裂性。为了提高磷石膏 胶结体的早期强度,掺入聚丙烯纤维作为增强剂,开展了掺纤维磷石膏胶结体制备试验以及单轴抗压强度试验,分析 了纤维对磷石膏胶结体破坏规律的影响,并通过SEM 探究了纤维对磷石膏胶结体的增韧机理。研究结果表明:随纤 维掺量增加磷石膏胶结体单轴抗压强度呈先增加后降低的趋势,且纤维最优掺量为1%;掺入纤维的磷石膏胶结体能 延缓峰值抗压强度达到时间且破坏时的峰值应力更大,未掺入纤维的磷石膏胶结体在荷载超过应力峰值后快速失 稳,掺入聚丙烯纤维的磷石膏胶结体则呈缓慢降低趋势;随着纤维的掺入,磷石膏胶结体的裂纹数量逐渐减少,且裂 而不断,磷石膏胶结体的延性变形明显;微观下聚丙烯纤维表面附着有絮团状水化产物,且在磷石膏胶结体固结过程 中相互缠结形成稳定的网状结构。研究成果可为磷石膏基复合材料在固废胶结充填现场的应用提供一定参考。

关键词: 聚丙烯纤维 磷石膏胶结体 早期力学特性 裂纹演化

Abstract: In the research field of traditional cementitious composites,fibers enhance the strength,toughness,ductility and crack resistance of the materials. In order to improve the early strength of phosphogypsum cements,polypropylene fibers were doped as reinforcing agent,and fiber-doped phosphogypsum cements preparation test and uniaxial compressive strength test were carried out to analyze the effect of fibers on the damage law of phosphogypsum cements,and the toughening mechanism of fibers on phosphogypsum cements was investigated by SEM. The results show that:the uniaxial compressive strength of phosphogypsum cementum increased with the fiber dosage,the uniaxial compressive strength of phosphogypsum cementum showed a tendency to increase and then decrease,and the optimal dosage of fibers is 1%;the phosphogypsum cementum doped with fibers can delay the time of reaching the peak compressive strength and the peak stress is greater in destruction;the phosphogypsum cementum without doped fibers is rapidly destabilized after the load exceeded the peak stress,and the phosphogypsum cementum with doped polypropylene fibers showed a slow decrease in the trend;with the fiber dosage,the phosphogypsum cementum is slowly stabilized and the peak stress is reduced. With the incorporation of fibers,the number of cracks in the phosphogypsum cement gradually decreases,and the cracks are continuous,and the ductile deformation of the phosphogypsum cement is obvious;under the microscopic surface of polypropylene fibers,there are flocculated hydration products attached to the surface of the polypropylene fibers,and in the process of slurry solidification to form the mesh structure with mutual adhesive connection. The research results of this paper can provide certain reference for the application of phosphogypsum-based composites in solid waste cementation and filling site.

Key words: polypropylene fiber,phosphogypsum based composite cement,early mechanical properties,crack evolution