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金属矿山 ›› 2024, Vol. 53 ›› Issue (01): 213-219.

• 矿物工程 • 上一篇    下一篇

某黏土型风化铁铌多金属矿选矿工艺研究

胡红喜1,2,3 张忠汉1,2,3 刘 超1,2,3 陈志强1,2,3 杨记平1,2,3
  

  1. 1. 广东省科学院资源利用与稀土开发研究所,广东 广州 510650;2. 稀有金属分离与综合利用国家重点实验室,广东 广州 510650;3. 广东省矿产资源开发与综合利用重点实验室,广东 广州 510650
  • 出版日期:2024-01-15 发布日期:2024-04-21
  • 基金资助:
    广东省科学院发展专项资金项目(编号:2022GDASZH-2022010104,2023GDASZH-2023010104)。

Research on Beneficiation Technology of a Clay Type Weathered Iron-niobium Polymetallic Ore

HU Hongxi1,2,3 ZHANG Zhonghan1,2,3 LIU Chao1,2,3 CHEN Zhiqiang1,2,3 YANG Jiping1,2,3 #br#   

  1. 1. Institute of Resources Utilization and Rare Earth Development,Guangdong Academy of Sciences,Guangzhou 510650,China;2. State Key Laboratory for Separation and Comprehensive Utilization of Rare Metals,Guangzhou 510650,China;3. Guangdong Key Laboratory for Development and Comprehensive Utilization of Mineral Resources,Guangzhou 510650,China
  • Online:2024-01-15 Published:2024-04-21

摘要: 某黏土型风化铁铌多金属矿石矿物成分较复杂,嵌布关系紧密,微细粒黏土矿物的存在严重影响有价 元素铁、磷、铌的回收。 试验采用原矿脱泥—浮选磷灰石—磁选选铁—重选烧绿石的工艺开展研究,通过脱泥以降低 细泥对选别的影响,对脱泥后的物料进行磷灰石浮选试验,磷灰石浮选尾矿经磁选获得铁精矿,选铁尾矿采用选冶方 法回收烧绿石。 对含 P2O5 8. 56%、Fe 31. 16%的原矿,试验获得了磷精矿含 P2O5 30. 78%、Fe 9. 27%,对原矿磷回收率 为 45. 95%;烧绿石回收作业获得磷精矿含 P2O5 39. 79%、对原矿回收率 2. 75%,总磷回收率 48. 70%;获得的铁精矿含 Fe 60. 73%、P2O5 1. 00%,对原矿铁回收率为 45. 35%;获得铌渣含 Nb2O5 19. 64%,对原矿回收率 20. 98%。 相对于原 矿磷 49. 37%、铁 55. 45%的理论回收率,磷、铁资源得到了有效回收。

关键词: 黏土矿物, 脱泥, 磷灰石, 磁铁矿, 烧绿石, 综合回收

Abstract: The ore is a clay type weathered iron-niobium polymetallic ore in which the mineral composition is complex and the distribution relationship is close. The existence of fine clay affects the recovery of valuable elements Fe,P,Nb seriously. The process of desliming,apatite flotation,magnetic separation and pyrochlore gravity separation was adopted in the test. First of all,desliming was used to reduce the influence of fine mud on mineral separation. Then,the locked cycle test of apatite flotation was carried out for the materials after desliming,iron concentrate was obtained by magnetic separation from apatite flotation tailings. Finally,the pyrochlore was recovered from iron tailings by means of metallurgy. For the raw ore assaying P2O5 of 8. 56% and Fe of 31. 16%,the phosphorus concentrate assaying P2O5 of 30. 78%,Fe of 9. 27% with phosphorus recovery of 45. 95% was obtained;The phosphorus concentrate assaying P2O5 of 39. 79% with recovery of 2. 75% was obtained in the stage of pyrochlore recovery operation,the total recovery of phosphorus was 48. 70%. The iron concentrate assaying Fe of 60. 73%, P 2O5 of 1. 00% with recovery of 45. 35% was obtained;The content of Nb2O5 in niobium slag was 19. 64% with recovery of 20. 98% for raw ore. Compared with the theoretical recovery rate of phosphorus of 49. 37% and iron of 55. 45% in raw ore, phosphorus and iron was effectively recovered.

Key words: clay minerals,desliming,apatite,magnetite,pyroclore,comprehensive utilization