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金属矿山 ›› 2025, Vol. 54 ›› Issue (6): 107-113.

• 矿物工程 • 上一篇    下一篇

某含锌铁冶金粉尘提铁除杂工艺研究 

古明远1,2   杨志强1,2   青格勒1,2   郑志辉3   尹尤豪1,2   郭俊祥1,2    

  1. 1. 首钢集团有限公司技术研究院,北京 100043;2. 绿色可循环钢铁流程北京市重点实验室,北京 100043; 3. 首钢迁安钢铁有限责任公司,河北 唐山 063210
  • 出版日期:2025-06-15 发布日期:2025-07-09
  • 作者简介:古明远(1985—),女,工程师,博士。
  • 基金资助:
    国家自然科学基金项目(编号:52000172)。 

Study on the Process of Iron Recovery and Impurity Removal from a Zinc-Bearing Iron Metallurgical Dust 

GU Mingyuan 1,2   YANG Zhiqiang 1,2   QING Gele 1,2   ZHENG Zhihui 3   YIN Youhao 1,2   GUO Junxiang 1,2    

  1. 1. Research Institute of Technology,Shougang Group Co. ,Ltd. ,Beijng 100043,China; 2. Beijing Key Laboratory of Green Recyclable Process for Iron & Steel Production Technology,Beijing 100043,China; 3. Shougang Qian′an Iron and Steel Co. ,Ltd. ,Tangshan 063210,China
  • Online:2025-06-15 Published:2025-07-09

摘要: 钢铁生产过程中产生的含锌粉尘因铁品位较低、杂质含量较高而难以直接返回主生产工序。 为实现某 含锌粉尘的高值化利用,进行了造球直接还原—磨矿—磁选流程研究,探究了 Fe、Zn 和 S 元素的分离与富集行为。 结 果表明:在还原温度 1 200 ℃ 、还原时间 30 min、碳氧摩尔比 1. 5 的条件下,铁金属化率和锌挥发率分别达 90. 44%和 99. 26%,金属化球团的全铁含量达 66. 23%,锌、硫含量分别为 0. 13%和 0. 57%、碳含量为 6. 22%;金属化球团在磨矿 细度-0. 074 mm 占 59%、磁场强度 95. 49 kA/ m 的条件下,可以获得 TFe 品位 82. 37%、回收率 92. 17%的磁选精矿, 锌、硫含量分别降低至 0. 09%和 0. 29%。 XRD、SEM-EDS 分析表明,金属化球团中铁氧化物的衍射峰或消失或强度十 分弱小,几乎完全还原为金属铁;金属铁相与脉石相未充分单体解离是造成磁选精矿铁含量有待提高的根本原因。 研究结果对类似资源的高值化开发利用具有参考价值。 

关键词: 含锌粉尘,   直接还原,   磨矿 , 磁选分离,   有害元素脱除 

Abstract: The zinc-bearing dust generated during the steel making process cannot be directly reintroduced into the main production process due to its low iron grade and high impurity content. In order to achieve high-value utilization of zinc-bearing dust,a systematic investigation was conducted on the integrated pelletizing-direct reduction,grinding,and magnetic separation process,with particular focus on the separation and enrichment mechanisms of Fe,Zn,and S elements. The results indicated that under conditions of a reduction temperature of 1 200 ℃ ,reduction time of 30 min,and carbon-oxygen molar ratio of 1. 5, the metallization ratio of iron and the volatilization ratio of Zn were 90. 44% and 99. 26%,respectively. The total iron content in the metallized pellets was 66. 23%,with zinc and sulfur contents reduced to 0. 13% and 0. 57%,respectively,and a carbon content of 6. 22%. Under grinding conditions where -0. 074 mm particle size accounted for 59% and a magnetic field intensity of 95. 49 kA/ m,a magnetic separation concentrate with a TFe grade of 82. 37% and recovery rate of 92. 17% was obtained, with zinc and sulfur contents further reduced to 0. 09% and 0. 29%,respectively. XRD and SEM-EDS analyses revealed that the diffraction peaks of iron oxides in the metallized pellets either disappeared or became very weak,indicating that almost all iron oxides were reduced to metallic iron. The suboptimal iron content in the magnetic separation concentrate is fundamentally attributed to the inadequate monomer liberation between the metallic iron phase and the gangue phase. The research results provide valuable references for the high-value development and utilization of similar resources. 

Key words: zinc-bearing dust,direct reduction,grinding,magnetic separation,removal of harmful elements 

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