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金属矿山 ›› 2025, Vol. 54 ›› Issue (7): 66-72.

• 矿物工程 • 上一篇    下一篇

椰油酰甘氨酸钠对菱铁矿与赤铁矿的浮选分离 影响研究 

印万忠  张西山  马英强  吴春辉  张  瑞    

  1. 福州大学紫金地质与矿业学院,福建 福州 350108
  • 出版日期:2025-07-15 发布日期:2025-08-12
  • 作者简介:印万忠(1970—),男,教授,博士,博士研究生导师。
  • 基金资助:
    国家自然科学基金项目(编号:52374259)

Research on the Effect of Sodium Cocoylglycinate on Flotation Separation of Siderite and Hematite 

YIN Wanzhong  ZHANG Xishan  MA Yingqiang  WU Chunhui  ZHANG Rui    

  1. Zijin School of Geology and Mining,Fuzhou University,Fuzhou 350108,China
  • Online:2025-07-15 Published:2025-08-12

摘要: 为了解决含碳酸盐赤铁矿石分选指标不理想的问题,以菱铁矿和赤铁矿为研究对象、椰油酰甘氨酸钠+ 油酸钠(SCG+NaOL)为组合捕收剂,开展了高效浮选分离菱铁矿与赤铁矿的系统浮选试验研究。 并通过接触角测试、 Zeta 电位测试、红外光谱分析、表面张力测试和吸附量测试揭示了复配药剂与矿物的作用机理。 浮选试验结果表明: 组合捕收剂椰油酰甘氨酸钠+油酸钠(质量比为 7 ∶1)对菱铁矿具有良好的可浮性,对赤铁矿的可浮性较差;在 pH = 7、 椰油酰甘氨酸钠+油酸钠用量为 100 mg / L 条件下处理人工混合矿(菱铁矿与赤铁矿质量比 1 ∶4),可获得 FeO 含量为 44. 07%、菱铁矿回收率为 71. 92%的泡沫产品,分离指数为 6. 71,相较于淀粉+油酸钠体系,菱铁矿 FeO 品位和回收率 分别提高了 6. 14 和 32. 10 个百分点。 机理分析表明,SCG 与 NaOL 复配后可显著提升 SCG 的溶解性,SCG+NaOL 与 2 种矿物作用后,可显著提升菱铁矿的疏水性和赤铁矿的亲水性。 同时,与淀粉+NaOL 体系相比,SCG+NaOL 药剂制度 简单,可显著提升菱铁矿与赤铁矿浮选分离的选择性。 

关键词: 椰油酰甘氨酸钠(SCG)  复配药剂  菱铁矿  赤铁矿  浮选分离 

Abstract: In order to solve the problem of unsatisfactory separation indicators of carbonate-containing hematite,taking siderite and hematite as the research objects and sodium cocoylglycinate + sodium oleate (SCG+NaOL) as the combined collecting agent,a systematic flotation experimental study on the efficient flotation separation of siderite and hematite was carried out. The interaction mechanism between the compound reagent and minerals was revealed through contact angle tests,Zeta potential tests,infrared spectroscopy analysis,surface tension tests and adsorption capacity tests. The results of the flotation test showed that the combined collector sodium cocoyl glycinate + sodium oleate (with a mass ratio of 7 ∶1) has good floatability for siderite but poor floatability for hematite. When the artificial mixed ore (with a mass ratio of siderite to hematite of 1 ∶4) was treated under the conditions of pH= 7 and the dosage of sodium cocoyl glycinate + sodium oleate was 100 mg / L,a foam product with a FeO content of 44. 07% and a siderite recovery rate of 71. 92% could be obtained,and the separation index was 6. 71. Compared with the starch-to-sodium oleate system,FeO grade and recovery rate of siderite increased by 6. 14 and 32. 10 percentage points respectively. Mechanism analysis indicated that the compounding of SCG and NaOL can significantly enhance the solubility of SCG. After the interaction of SCG+NaOL with the two minerals,the hydrophobicity of siderite and the hydrophilicity of hematite can be significantly improved. Meanwhile,compared with the starch +NaOL system,the SCG+NaOL reagent system is simple and can significantly improve the selectivity of siderite and hematite flotation separation. 

Key words: sodium cocoylglycinate (SCG),compounding agent,siderite,hematite,flotation separation 

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