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金属矿山 ›› 2026, Vol. 55 ›› Issue (1): 109-116.

• 矿物工程 • 上一篇    下一篇

硅酸钠体系下玉米淀粉对赤铁矿团聚磁选的影响

张鑫宇1,2 王旱雨1,2 李文博1,2   

  1. 1. 东北大学资源与土木工程学院,辽宁 沈阳 110819;
    2. 难采选铁矿资源高效开发利用技术国家地方联合工程研究中心,辽宁 沈阳 110819
  • 出版日期:2026-01-15 发布日期:2026-02-12
  • 通讯作者: 李文博(1985—),男,教授,博士,博士研究生导师。
  • 作者简介:张鑫宇(1999—),男,硕士研究生。
  • 基金资助:
    国家自然科学基金项目(编号:51974068);国家高层次人才支持计划-青年拔尖人才项目(编号:QNBJ-2023-03);兴辽英才计划青年拔
    尖项目(编号:XLYC2403075);辽宁省优秀青年科学基金项目(编号:2022-YQ-10)。

Effect of Corn Starch on Magnetic Separation of Hematite Agglomeration in Sodium Silicate System

ZHANG Xinyu1,2 WANG Hanyu1,2 LI Wenbo1,2   

  1. 1. School of Resources and Civil Engineering,Northeastern University,Shenyang 110819,China;2. National-Local Joint Engineering
    Research Center of High-Efficient Exploitation Technology for Refractory Iron Ore Resources,Shenyang 110819,China
  • Online:2026-01-15 Published:2026-02-12

摘要: 微细粒弱磁性铁矿物的高效回收问题一直是选矿领域关注的重点与难点。本研究聚焦于-20 μm 赤铁
矿在高梯度磁选中捕获效率低下的问题,通过构建人工混合矿的“分散—选择性桥联团聚—高梯度磁捕获”的协同强
化分选方法,系统探究硅酸钠、交联玉米淀粉及矿浆pH 值对分选效率的调控规律,并通过激光粒度分析仪、动电位
仪、紫外分光光度计、矿相显微镜和扫描电镜多尺度表征,阐明界面化学-团聚形貌-磁选行为的关系。试验结果表
明,在交联玉米淀粉用量为15 mg/ L、硅酸钠用量为15 mg/ L、pH= 9 的最佳条件下,铁品位和回收率分别提高了3. 84
和16. 69 个百分点。机理分析表明,适量的硅酸钠能够提高赤铁矿与石英的分散性,但当硅酸钠用量过多会导致赤铁
矿表面吸附位点减少,从而减弱团聚效果;此外,交联玉米淀粉对赤铁矿的团聚作用主要由于其表面静电吸附效应,
然而过量交联玉米淀粉会引发空间位阻效应,促使团聚体内部形成疏松多孔结构并产生分散排斥行为,这种非选择
性团聚行为导致赤铁矿与石英的分离特性减弱,最终造成高梯度磁选分离效率的下降。本研究为“分散—选择性桥
联团聚—高梯度磁捕获”技术提供了理论和技术支撑。

Abstract: The efficient recovery of fine-grained weakly magnetic iron ores remains a critical challenge in mineral processing,
particularly for hematite with low magnetic susceptibility. The present research focuses on the low capture efficiency of
-20 μm hematite in high gradient magnetic separation,and investigates the regulation of sodium silicate,crosslinked corn
starch(CLCS) and pulp pH on the separation efficiency by constructing a synergistic method of "dispersion-selective bridging
agglomeration-high gradient magnetic capture" for artificial mixed ores,and then investigates the regulation of sodium silicate,
crosslinked corn starch and pulp pH on the efficiency of the separation. The interfacial chemistry-agglomeration morphologymagnetic
response relationships were analyzed via laser particle size analysis (LPSA),Zeta potential measurement,UV-Vis
spectroscopy,mineralogical microscopy,and scanning electron microscopy (SEM). The experimental findings demonstrated that
the iron grade and beneficiation efficiency exhibited an enhancement of 3. 84 and 16. 69 percentage points,respectively,under
the optimal conditions of crosslinked corn starch dosage of 15 mg/ L,sodium silicate dosage of 15 mg/ L,and pH=9. The mechanism
analysis revealed that the optimal dosage of sodium silicate enhances the dispersion of hematite and quartz. However,
when the sodium silicate dosage exceeds the optimal level,it leads to a reduction in the adsorption sites on the hematite surface,
thereby weakening the agglomeration effect. CLCS on hematite is primarily attributable to the electrostatic adsorption effect
on the surface of the static adsorption effect. However,excessive crosslinked corn starch can induce a spatial site-disturbing
effect,which in turn leads to the formation of a loose porous structure and dispersion phase repulsion in the agglomerates. This
non-selective agglomeration behavior leads to the weakening of the interface separation characteristics between hematite and
quartz,which eventually leads to the attenuation of the separation efficiency of high gradient magnetic separation. This study provides theoretical and technical support for the "dispersion-selective bridging agglomeration-high gradient magnetic capture"
technology.

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