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金属矿山 ›› 2026, Vol. 55 ›› Issue (3): 63-70.

• 采矿工程 • 上一篇    下一篇

磷石膏基复合充填材料早期力学强度特征及水化机理

薛改利1 曹 帅2   

  1. 1. 太原理工大学矿业工程学院,山西 太原 030024;2. 北京科技大学资源与安全工程学院,北京 100083
  • 出版日期:2026-03-15 发布日期:2026-03-31
  • 作者简介:薛改利(1987—),女,副研究员,博士,硕士研究生导师。
  • 基金资助:
    中国博士后科学基金项目(编号:2022M711432);山西省基础研究计划(自由探索类)青年项目(编号:202103021223114)。

Early Mechanical Strength Characteristics and Hydration Mechanism of Phosphogypsum-based Composite Filling Materials

XUE Gaili1 CAO Shuai2   

  1. 1. College of Mining Engineering,Taiyuan University of Technology,Taiyuan 030024,China;
    2. School of Resources and Safety Engineering,University of Science and Technology Beijing,Beijing 100083,China
  • Online:2026-03-15 Published:2026-03-31

摘要: 通过开展不同石膏类型和磷石膏基复合激发的胶结充填体单轴压缩力学试验,分析了各因素对胶结充
填体早期力学强度的影响效应和最优掺量,并结合扫描电镜SEM 和EDS 定量分析技术,揭示了复合充填材料的微观
结构特征和水化机理。结果表明:掺加磷石膏胶结充填体的早期力学强度显著降低,但随着养护龄期延长磷石膏的
不利影响效应减弱;磷石膏基胶结充填体早期力学强度的显著影响因素为磷石膏和芒硝,NaOH 掺量不宜超过3%,芒
硝最优掺量为1. 0%,磷石膏掺量可达到40%;掺加磷石膏抑制了复合充填材料的早期水化反应进程,且充填体早期
变形随着磷石膏掺量增加逐渐增大,其破坏模式以平行于加载方向的张拉破坏为主。研究成果可为促进磷石膏资源
化利用提供参考,有助于降低矿山充填成本。

Abstract: Through uniaxial compression mechanical tests of different gypsum types and phosphypsum composite excitation
cemented backfill,the effects of various factors on the early mechanical strength of cemented backfill and the optimal dosage
were analyzed. The microstructure characteristics and hydration mechanism of the composite filling materials were revealed
by means of SEM and EDS quantitative analysis techniques. The results show that the early mechanical strength of the cemented
backfill mixed with phosphogypsum decreases significantly,but the adverse effect of phosphogypsum decreases with the prolongation
of curing age. The significant factors affecting the early mechanical strength of phosphogypsum based cemented backfill
are phosphogypsum and glauberite. The content of NaOH is not more than 3%,the optimal content of glauberite is 1. 0%,
and the content of phosphogypsum can reach 40%. The addition of phosphogypsum inhibited the early hydration reaction
process of the composite backfill material,and the early deformation of the cemented backfill gradually increased with the increase
of phosphogypsum content,and the failure mode was mainly tensile failure parallel to the loading direction. The research
results provide reference for improving the resource utilization of phosphogypsum and help to reduce the cost of mine filling.

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