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金属矿山 ›› 2026, Vol. 55 ›› Issue (3): 110-115.

• 矿物工程 • 上一篇    下一篇

浮选浓度对铜钼分离的影响及动力学研究

朱贤文1 刘润清1 张慧婷2 董文超1 江 锋1   

  1. 1. 中南大学资源加工与生物工程学院,湖南 长沙 410083;2. 西部矿业集团科技发展有限公司,青海 西宁 810006
  • 出版日期:2026-03-15 发布日期:2026-03-31
  • 通讯作者: 刘润清(1979—),女,教授,博士,博士研究生导师。
  • 作者简介:朱贤文(1991—),男,博士研究生。
  • 基金资助:
    “十四五”国家重点研发计划项目(编号:2022YFC2904502,2022YFC2904501)。

Effect of Flotation Concentration on Copper-Molybdenum Separation and Its Kinetic Study

ZHU Xianwen1 LIU Runqing1 ZHANG Huiting2 DONG Wenchao1 JIANG Feng1   

  1. 1. School of Minerals Processing and Bioengineering,Central South University,Changsha 410083,China;
    2. Technology Development of Western Mining Group Co. ,Ltd. ,Xining 810006,China
  • Online:2026-03-15 Published:2026-03-31

摘要: 浮选浓度是影响浮选指标的关键因素之一。适宜的浮选浓度不仅有助于提升分离指标,还能降低浮选
成本。针对铜钼浮选分离过程中动力学规律不明的问题,考察了不同矿浆浓度下铜钼分离的钼富集及回收情况,研
究了浓度变化对钼浮选动力学的影响规律,并选取经典一级动力学模型进行了阶段速率常数(k)的分析。结果表明,
浓度对某铜钼混合精矿浮选分离影响较大,适当提高浮选浓度,可提高钼浮选回收率;浮选动力学拟合结果表明,各
矿浆浓度下拟合优度值(R2)均大于0. 99,一阶浮选动力学模型对该试验数据的拟合良好;随着浓度的增大,所拟合的
速率常数(k)先上升后降低,浓度为35%时最高。综合考虑,该铜钼混合精矿粗选适宜的浓度为35%~40%。结合现
场工艺流程,采用“铜钼分离—钼粗精矿再磨再精选”的流程,获得的钼精矿含钼48. 78%、含铜1. 23%,钼回收率
92. 49%;铜精矿含铜21. 79%、含钼0. 06%,铜回收率99. 92%。本研究明确了铜钼分离粗选浓度对速率常数(k)的调
控作用,为铜钼分离浮选工艺优化提供理论支撑,并为同类铜钼混合精矿的浮选分离提供了技术参考。

Abstract: Flotation concentration is one of the key factors affecting flotation performance. An appropriate flotation concentration
not only enhances separation efficiency but also reduces cost. Addressing the unclear kinetic patterns in copper-molybdenum
flotation separation,this study examined molybdenum enrichment and recovery under varying pulp concentrations. It
investigated the influence of concentration changes on molybdenum flotation kinetics and analyzed the stage rate constant (k)
using the classical first-order kinetic model. The results indicate that concentration significantly influences the flotation separation
of this copper-molybdenum mixed concentrate. Increasing the flotation concentration enhances molybdenum recovery. Flotation
kinetic fitting results show that the coefficient of determination (R2) exceeds 0. 99 at all pulp concentrations,demonstrating
that the first-order flotation kinetic model fits the experimental data well. As concentration increased,the fitted rate constant
(k) first rose then declined,peaking at 35% concentration. Overall,the optimal concentration for roughing of this coppermolybdenum
mixed concentrate was determined to be 35%~40%. Integrating with the field process flow,molybdenum concentrate
assaying Mo of 48. 78% and Cu of 1. 23% with a molybdenum recovery of 92. 49%,and a copper concentrate assaying Cu
of 21. 79% and Mo of 0. 06% with a copper recovery of 99. 92% were obtained with the "copper-molybdenum separation,regrinding
and re-concentration of molybdenum rough concentrate" process. This study clarifies the regulatory effect of concentration
on the rate constant (k) during copper-molybdenum separation roughing,providing theoretical support for optimizing copper-
molybdenum separation flotation processes and offering technical reference for the flotation separation of similar copper-molybdenum
mixed concentrates.

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