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金属矿山 ›› 2026, Vol. 55 ›› Issue (4): 108-115.

• 采矿工程 • 上一篇    下一篇

超细铁尾矿—氧化钙共烧协同矿渣制备碱激发充填胶凝材料#br#

赵利鼎1 王凯锋2 史政坤2   

  1. 1. 吕梁学院资源与机械工程系,山西 吕梁 033000;2. 太原理工大学矿业工程学院,山西 太原 030000
  • 出版日期:2026-04-15 发布日期:2026-05-08
  • 作者简介:赵利鼎(1985—),男,讲师。
  • 基金资助:
    吕梁市重点研发项目(编号:2025GY19) 。

Preparation of Alkali-Activated Filling Cementitious Material by Ultrafine Iron Tailings-Calcium Oxide Co-firing and Slag#br#

ZHAO Liding1 WANG Kaifeng2 SHI Zhengkun2   

  1. 1. Department of Resources and Mechanical Engineering,University of Lüliang,Lüliang 033000,China;
    2. College of Mining Engineering,Taiyuan University of Technology,Taiyuan 030000,China
  • Online:2026-04-15 Published:2026-05-08

摘要: 提高铁尾矿利用率对推动铁矿山可持续发展具有重要意义。采用铁尾矿与氧化钙共烧改性协同矿渣
制备了硫酸盐激发的复合充填胶凝材料,在固定胶砂比和质量浓度下,系统研究了矿渣掺量对充填料浆流动性、力学
性能和微观结构的影响。结果表明,随矿渣掺量增加,料浆扩展度呈小幅下降趋势;充填体强度显著提升,但掺量超过
50%后强度增幅减缓。微观分析表明,改性铁尾矿与矿渣共存体系中形成了丰富的水化产物,C-S-H 凝胶与钙矾石
交织形成的水化产物网络显著改善了充填体微观结构的致密性。二者的协同作用机制表现为矿渣快速水化生成的
凝胶产物构筑了早期强度骨架,而改性铁尾矿颗粒通过微集料效应有效填充了内部孔隙,其活性组分也参与了水化
反应,这种物理填充与化学反应的耦合效应显著提高了充填体的整体强度。改性铁尾矿协同30% ~50%矿渣掺量的
方案可实现性能与经济效益的平衡,为铁尾矿资源化利用提供了新思路和技术支持。

关键词: 改性铁尾矿 , 碱激发 , 充填胶凝材料 , 微观结构

Abstract: Improving the utilization rate of iron tailings is of great significance to promote the sustainable development of
iron ore mines. Sulfate-activated composite filling cementitious materials were prepared by co-combustion of iron tailings and
calcium oxide with slag. The effects of slag content on the fluidity,mechanical properties and microstructure of filling slurry
were systematically studied under fixed cement-sand ratio and mass concentration. The results show that the slurry expansion
decreases slightly with the increase of slag content. The strength of the filling body is significantly improved,but the strength increase
slows down after the content exceeds 50% . The microscopic analysis shows that abundant hydration products are formed
in the coexistence system of modified iron tailings and slag,and the hydration product network formed by the interweaving of CS-
H gel and ettringite significantly improves the compactness of the microstructure of the filling body. The synergistic mechanism
of the two is that the gel product generated by the rapid hydration of slag constructs the early strength skeleton,and the
modified iron tailings particles effectively fill the internal pores through the micro-aggregate effect,and its active components also
participate in the hydration reaction. The coupling effect of physical filling and chemical reaction significantly improves the
overall strength of the filling body. The scheme of modified iron tailings with 30%-50% slag content can achieve the balance
between performance and economic benefits,which provides new ideas and technical support for the resource utilization of iron
tailings.

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