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金属矿山 ›› 2026, Vol. 55 ›› Issue (6): 129-139.

• 矿物工程 • 上一篇    下一篇

某铁矿伴生钴的赋存机制与回收可行性研究

王祥洪1 刘 军2 杨昌龙1   

  1. 1.安徽庐江龙桥矿业股份有限公司,安徽 合肥 231500;2.中钢集团马鞍山矿山研究总院股份有限公司,安徽 马鞍山 243000
  • 出版日期:2026-07-15 发布日期:2026-07-08
  • 作者简介:王祥洪(1986—),男,工程师。

Study on the Occurrence Mechanism and Recovery Feasibility of Associated Cobalt in an Iron Ore

WANG Xianghong1 LIU Jun2 YANG Changlong1   

  1. 1.Anhui Lujiang Longqiao Mining Co.,Ltd.,Hefei 231500,China; 2.Sinosteel Maanshan General Institute of Mining Research Co.,Ltd.,Maanshan 243000,China
  • Online:2026-07-15 Published:2026-07-08

摘要: 为实现某沉积-热液改造型铁矿中伴生钴资源的综合利用,本研究以选矿流程中的硫铜混合精矿为对 象,综合运用化学分析、X射线荧光光谱(XRF)、扫描电镜(SEM)、电子探针(EPMA)及光学显微镜等多种技术手段, 开展了系统的工艺矿物学研究。结果表明:钴主要以类质同象形式赋存于黄铁矿(含钴0.149%)与黄铜矿(含钴 0.045%)中,分布率合计达87.07%;独立钴矿物辉钴矿含量极低(0.06%)。浮选探索试验证实,钴在硫铜分离时富集 于硫精矿中,品位为0.14%~0.16%;有害元素砷亦同步富集于硫精矿(砷含量0.59%),难以有效脱除,严重影响其质 量。从硫精矿中进一步富集钴的尝试表明,钴虽可在尾矿中富集至0.30%,但砷含量也同步升高至2.20%。本研究 最终得出结论:由于钴分散赋存且砷难以分离,从该物料中单独回收钴不具备可行性,建议将钴作为硫精矿的伴生组 分进行综合回收。

关键词: 硫铜混合精矿 , 钴 , 工艺矿物学 , 赋存状态 , 浮选探索试验

Abstract: To achieve the comprehensive utilization of associated cobalt resources in a sedimentary-hydrothermal re formed iron deposit,a systematic process mineralogy study was conducted on the sulfur-copper mixed concentrate from the ben eficiation process.Multiple techniques,including chemical analysis,X-ray fluorescence (XRF),scanning electron microscopy (SEM),electron probe microanalysis (EPMA),and optical microscopy,were employed.The results reveal that cobalt is prima rily hosted in pyrite (0.149% Co) and chalcopyrite (0.045% Co) via isomorphism,with a combined distribution rate of 87.07%.The independent cobalt mineral,cobaltite,is present in very low abundance (0.06%).Flotation exploratory tests confirmed that cobalt reports to the sulfur concentrate during copper-sulfur separation,with a grade ranging from 0.14% to 0.16%.The harmful element arsenic is also concurrently enriched in the sulfur concentrate (0.59% As),which is difficult to remove effectively and severely impacts the concentrate quality.Attempts to further concentrate cobalt from the sulfur concen trate showed that while cobalt could be enriched to 0.30% in the tailings,the arsenic content simultaneously increased to 2. 20%.This study concludes that separate recovery of cobalt from this material is not feasible due to its dispersed occurrence and the difficulty of arsenic separation.It is,therefore,recommended that cobalt be recovered as a associated component of the sul fur concentrate.

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