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金属矿山 ›› 2026, Vol. 55 ›› Issue (6): 148-155.

• 矿物工程 • 上一篇    下一篇

某含磁黄铁矿的复杂硫化铜锌矿的优先浮选-磁选联合工艺研究

王亚运,康金星,王 鑫,姜志学,刘志国   

  1. 中国恩菲工程技术有限公司,北京 100038
  • 出版日期:2026-07-15 发布日期:2026-07-14
  • 作者简介:王亚运(1990—),男,高级工程师,博士。
  • 基金资助:
    “十四五”国家重点研发计划项目(编号:2023YFC2907903)。

Study on Preferential Flotation-Magnetic Separation Combined Process of a Complex Copper-Zinc Sulfide Ore Containing Pyrrhotitee

WANG Yayun,KANG Jinxing,WANG Xin,JIANG Zhixue,LIU Zhiguo   

  1. China ENFI Engineering Corporation,Beijing 100038,China
  • Online:2026-07-15 Published:2026-07-14

摘要: 在常规黄药类捕收剂体系下,含磁黄铁矿的硫化铜锌矿中,磁黄铁矿的可浮性与活化后的闪锌矿相当, 易成为锌精矿中的主要杂质,导致锌分选效率低、精矿品位不达标、资源回收率偏低等问题。针对这一难题,本研究以 某含磁黄铁矿的硫化铜锌矿为对象,在系统开展工艺矿物学研究的基础上,进行了选矿工艺流程探索,确定了“优先 选铜—磁选脱除磁黄铁矿—再浮选选锌”的最优工艺流程。在此基础上,依次开展了铜浮选、磁选、锌浮选条件试验, 优化了各作业关键参数,最后进行了全流程闭路试验。试验结果表明,全流程闭路试验可获得铜品位25.080%、铜回 收率76.56%的铜精矿,以及锌品位50.82%、锌回收率93.23%的锌精矿。该工艺有效解决了磁黄铁矿对铜锌分选的 干扰,实现了铜、锌资源的高效分离与回收,可为同类复杂难选硫化铜锌矿的工业化选矿提供可靠的技术参考。

关键词: 磁黄铁矿 , 硫化铜锌矿 , 优先浮选 , 磁选 , 分离与回收

Abstract: In copper-zinc sulfide ores containing pyrrhotite,the floatability of pyrrhotite differs little from that of activated sphalerite in conventional xanthate collector systems,making pyrrhotite a major gangue impurity in zinc concentrate.This often leads to low zinc separation efficiency,substandard concentrate grade,and poor resource recovery.To address these challenges, this study takes a copper-zinc sulfide ore containing pyrrhotite as the research object.Based on systematic process mineralogy studies,beneficiation process exploration was conducted,and the optimal process flow of “preferential copper flotation,magnetic separation to remove pyrrhotite and zinc flotation” was determined.Subsequently,condition tests for copper flotation,magnetic separation,and zinc flotation were carried out to optimize the key parameters of each operation,followed by full-process closed circuit tests.The test results show that the full-process closed-circuit test yields a copper concentrate with a copper grade of 25.080% and a copper recovery of 76.56%,and a zinc concentrate with a zinc grade of 50.82% and a zinc recovery of 93.23%.This process effectively eliminates the interference of pyrrhotite in copper-zinc separation and achieves efficient sepa ration and recovery of copper and zinc resources,providing a reliable technical reference for the industrial beneficiation of simi lar complex refractory copper-zinc sulfide ores.

Key words: pyrrhotite,copper-zinc sulfide ore,preferential flotation,magnetic separation,separation and recovery

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