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    15 May 2023, Volume 52 Issue 05
    Technical Path of New Intelligent Mode of Open-pit Mine under the Background of "Dual Carbon" 
    GU Qinghua, LI Xuexian, LU Caiwu, RUAN Shunling, JIANG Song
    2023, 52(05):  1-13. 
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    With the continuous development of intelligent mining technology,the mining model needs to be continuously innovated. At present,there are still many urgent problems that should be tackled in the intelligent construction of open-pit mine in China. The traditional mining design and technology can no longer adapt to the development of unmanned,new energy and other intelligent equipment,and new challenges are proposed to the original production mode and equipment under the background of " dual carbon" . By reviewing the current status of intelligent construction of open-pit mine,this paper focuses on the transformation and upgrading of low carbon intelligent mining under the background of " dual carbon" ,and explores a new mode of low carbon,continuous,efficient and safe intelligent construction named as the CDEC mining mode. The mode includes four aspects:clean energy development and carbon storage and utilization ( Carbon),new concept of open-pit mining design (Design),customized scheme of new energy intelligent equipment (Equipment) and continuous production process of open-pit mine (Continuous). Then,the technical path of this mode is explored from three aspects:establishing a renewable energy system with multiple energy sources complementing each other,exploring a low-carbon continuous production process in open-pit mine,and developing a carbon storage and ecological carbon sink technology system. In the end,the green energy supply and utilization style of " renewable energy utilization+ new energy equipment + carbon storage and utilization" will be realized,and the unmanned continuous production process of " mobile surge loader (optional) + unmanned driving + crushing system + belt transport or lifting device" will be formed,thus providing guidance for the intelligent construction of open-pit mine under the background of " dual carbon" .
    Progress and Prospect for Disater Mitigtion and Damage Reduction Green Mining Theory and Technology of Super-high Water Material Backfill
    WANG Fangtian, LIU Chao, HAO Wenhua, HU Shijie, FENG Guangming, LI Huaizhan, GUO Guangli
    2023, 52(05):  14-30. 
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    Safe and efficient mining of deep coal seam and ecological environment protection is one of the major problems in green mining of coal resources. Backfill mining has remarkable effects on preventing deep well dynamic impact disasters,reducing surface subsidence and protecting ecological environment. The water volume ratio of super-high water material backfill is high,and backfill mining has the characteristics of simple process,strong adaptability,less materials and high backfill rate, which can effectively solve the prominent contradiction between surface environmental protection and coal resource mining damage. Meet the requirements of the new development concept of coal resource disaster mitigation and loss reduction green intelligent mining. On the basis of summarizing the research and development background of backfill mining technology,the technical principle,process flow and material properties of super-high water backfill mining are clarified. The mechanism of dynamic disaster prevention in backfill mining is mainly revealed from the aspects of surface subsidence control " backfill body-coal pillar" and " backfill body-support-coal body" collaborative load. The key technologies of disaster reduction and loss reduction in green mining power disaster prevention,intelligent perception,surface deformation monitoring and prediction and intelligent control of backfill equipment are put forward,which have been successfully conducted super-high water material backfill mining practice in Yineng Coal Mine in Shandong Province,and the safe and efficient intelligent green mining of deep coal seams under buildings,railways,and water bodies is realized. In order to promote the construction of ecological civilization and environmental protection,and realize the green mining of disaster mitigation and loss reduction in modern mines,the research direction of super-high water material backfill is prospected as follows:deepen the basic theory of rock control for deep super-high water material backfill mining,improve the intelligent level of super-high water backfill mining technology,innovate the collaborative mining technical system of super-high water backfill mining and coal measures associated resources,combine super-high water backfill mining with carbon capture,storage and reuse technology,optimize the monitoring and evaluation system and method of intelligent green mining,so as to provide scientific basis for the realization of deep resources green mining.
    Present Situation and Prospect of Backfilling Consolidation Process Monitoring for Metal Mine
    WANG Yong, LI Jian, WANG Zhenqi, NA Qing , BI Cheng , WU Aixiang
    2023, 52(05):  31-44. 
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    Backfilling mining technology is an important support technology for the green and high-quality development of metal mines. The branch research direction of monitoring of backfilling solidification process in the field of filling was proposed by the research group,aiming to break the bottleneck problem of in-situ strength monitoring and characterization of metal mine stope backfilling fields. Combined with the relevant research progress of the group,the technical ideas of the theory and application of metal mine backfilling and curing research are summarized. The research status of the theory and application of multifield performance monitoring of metal mine backfilling and curing process is systematically expounded from the aspects of multi-field performance monitoring technology, multi-field performance evolution law, multi-field performance mechanism, multi-field performance correlation mechanism,backfill strength and multi-field performance characterization model,numerical simulation of backfilling and curing process,and engineering application. On the basis of the above analysis,the future development direction is foreseen from three levels:theory,technology and device,and the subsequent focus needs to be tackled as follows:real stope field-wide numerical simulation,backfill safety early warning technology based on curing process monitoring, development of wireless,accurate and low-cost curing process monitoring sensors and engineering promotion application.
    Research Progress of Rock Mass Structure and Mechanical Parameter Characterization Based on Measurement While Drilling Technology
    YU Qinglei, WANG Yuheng, LI You , CAO Yongsheng, PU Jiangyong
    2023, 52(05):  45-58. 
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    The rock mass structure characterization and mechanical parameters determination are hot issue in the field of rock mechanics and serve as crucial basis for metal mining design. How to determine the mechanical parameters of rock mass has always been a challenging task in the field of rock mechanics due to the complexity and spatial variability of natural rock mass structures. Measurement while drilling (MWD) technology provides an easy and rapid in-situ testing method that enables the assessment of rock mass characteristics and strength during the drilling process by utilizing the response of the drill bit,and the MWD has incomparable advantages combined with drilling and blasting in the mining industry. Extensive studies have been conducted on MWD both domestically and internationally,leading to significant achievements. This paper provides a comprehensive overview of the MWD research findings from the 1970s to the present and recent advances in MWD research,including the test facility for MWD research,rock mass characterization while drilling,and rock strength estimation while drilling,and the limitations of the MWD research are also analyzed. Finally,based on the studies and findings of our group,the possible development directions for MWD are pointed out,providing a reference for future research and application of the technology.
    Basic Concepts and Research Contents about Intelligent Blasting
    WU Chunping, WANG Xuguang
    2023, 52(05):  59-63. 
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    In order to properly guide its development direction,any new theory has an application scope and needs to be accurately defined. It has become a consensus in the industry to promote intelligent blasting,but there are still different opinions in the industry on how to define intelligent blasting and what should be studied about intelligent blasting. According to the extension and connotation of intelligence and the domain of blasting,the definition of intelligent blasting can be summed as:the use of 5G,artificial intelligence,big data,cloud computing and other new generation of information technology,the gamut of manufacturing activities from blasting design and operation to management and services are combined with each other and fused to establish a comprehensive integrated blasting technology characterized by a range of functional capabilities such as self-perception of deep information,smart-based optimum self-decision making and precision-controlled self-execution,and to solve some blasting issues required human experts to deal with previously,for the purpose of safe,green,intelligent and efficient engineering. Beyond the definition,the main research contents of intelligent blasting are specified as follows:theories and methods of intelligent blasting,collecting and processing technologies of blasting multiple heterogeneous information,intelligent sensing technologies for perceiving blasting surroundings,highly intelligent equipment and technologies of blasting operations,transmission,interaction and processing technologies of blasting information,besides that,the typical industrial application scenarios of intelligent blasting is disscussed. Finally,the development direction of intelligent blasting is given for the future,so as to provide reference for the similar studies.
    Research Progress in Theory and Technology of Energy Regulation for Rock Drilling and Blasting
    LENG Zhendong, GAO Qidong, LU Wenbo, CHEN Ming, ZHOU Guisong, FAN Yong
    2023, 52(05):  64-76. 
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    The process of rock drilling and blasting involves a complex interaction of Thermal-Hydrological-MechanicalChemical (T—H—M—C) coupling processes,which essentially involves the release,transmission,and transformation of explosive energy. Investigating the theory and technology of blasting energy regulation is of great significance for improving the energy utilization rate of explosives and reducing harmful effects. This article systematically reviews the research progress in the mechanism of energy release,transmission,and transformation of explosives in rock drilling and blasting,with a focus on non-ideal detonation models of explosives,energy release laws of explosives,interaction mechanisms between explosive and rock mass,blasting energy transfer models,and blasting energy distribution laws. The study results show that the energy utilization rate of rock fragmentation by blasting depends on the pressure distribution of the entire detonation wave. A large amount of energy is released in the sparse wave behind the detonating wave for non-ideal detonation. The traditional impedance matching theory is too simplistic for the blasting process,and cannot reasonably describe the energy transfer process between explosives and rocks. The regulation of blasting energy can be achieved through the release and transmission of explosive energy. Energy regulation technology mainly includes blasting energy regulation technology based on performance adjustable explosives,precise delay blasting with electronic detonators,initiation position and mode,and charge structure optimization,and so on. Based on the above analysis,the development status and main problems of energy regulation theory and application technology for rock drilling and blasting are summarized,and the research and development trend of this technology is discussed.
    Study Progresses on the Pressure Desensitization of Emulsion Explosives in the Drilling and Blasting Operation
    CHENG Yangfan, ZHU Shoujun, LI Zihan, WEI Xiao, LI Xiang, YAO Yingkang
    2023, 52(05):  77-85. 
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    Emulsion explosive generally refers to a kind of water-in-oil ( W / O) type of water-resistant industrial explosive prepared by emulsion technology. In the deep hole and deep water blasting operations,the emulsion explosive in the hole would be subjected to static pressure. In the delayed blasting,the shock wave generated by the earlier initiated emulsion explosive would produce dynamic load on the later detonated ones. When emulsion explosive is subjected to the external pressure,its internal sensitization bubbles are easy to be destroyed,and the emulsion matrix around the sensitization bubbles would be locally demulsified,resulting in the explosive " misfire" or " semi-explosion" ,this phenomenon is named " pressure desensitization" . In this paper,the study status of pressure desensitization of emulsion explosive under dynamic and static pressure is investigated,and the study methods,influencing factors and countermeasures of pressure desensitization are systematically summarized. The study results are helpful to improve the safety and construction efficiency of blasting mining,and provide a reference for the study of pressure desensitization of emulsion explosives in future
    Study Progress and Prospect of Overtopping Erosion Failure Mechanism and Process of Tailings Dam
    JING Xiaofei, MAO Jingxin, LI Xiaoshuang, XIE Dongxu, NIE Wen, WU Shangwei
    2023, 52(05):  86-96. 
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    Flood overtopping is a prominent type of tailings dam accidents,and a profound comprehension of the erosion and damage mechanisms and processes of tailings dam overtopping holds significant importance in advancing disaster prevention and reduction in tailings dams. To investigate the failure mechanism of tailings dam overtopping and proficiently forecast the occurrence of flood overtopping accidents,numerous scholars have conducted extensive research in recent years,resulting in an array of impressive research outcomes that offer scientific guidance for the prevention and control of tailings dam flood overtopping disasters. The research accomplishments on overtopping failure of tailings dams both domestically and internationally have been summarized and analyzed thoroughly,with particular attention given to the overtopping erosion failure of tailings dams through model experiments,mathematical models,numerical simulations,and other perspectives. The research findings have revealed the spatiotemporal laws of the development of tailings dam breach under the action of overtopping water flow and the evolution of tailings flow discharge,uncovering the mechanism of overtopping erosion failure of tailings dams. However,some limitations exist:① Regarding physical model tests,dam failure process,and impact analysis,single-factor tests are currently the primary means,failing to fully consider the coupling effects of multiple factors such as dam accumulation mode, boundary conditions,and material mechanical properties,leading to significant discrepancies between the test results and the actual situation. ② In terms of mathematical model analysis,the theories and formulas of earth-rock dams are still being referenced,resulting in notable differences between tailings dams and earth-rock dams in terms of structural shape,dam material, stacking technology,and storage capacity,as well as various differences in the properties of debris flows formed. Consequently, the conclusions drawn have significant errors compared to the actual tailings dam overtopping failure. Then,the current mathematical models of tailings pond overtopping failure prediction all consider the flood overtopping failure prediction of unreinforced tailings dams,and the reinforcement belt will play an important role in the development of flood overtopping failure of tailings dams. ③ The current mathematical models for predicting overflow and collapse of tailings dams primarily focus on the prediction of flood overflow and failure of unreinforced tailings dams,with reinforcement strips having a considerable impact on the development of flood overflow and collapse of tailings dams. In terms of numerical simulation calculations,the accuracy deviation of terrain measurement data and the lack of validation of corresponding large-scale model experiments pose challenges to ensuring the credibility of its calculation conclusions. To address these issues,several future research directions are proposed: ① Adopting multi-scale experimental models by combining large-scale model experiments with small-scale experiments for exploration and mutual verification. ② Developing more precise new soil collection instruments to obtain soil erosion coefficients and enhance existing soil erosion rate models. ③ Based on model experiments on the erosion process of tailings dam overtopping under the coupling effect of multiple factors,more comprehensive mathematical models should be developed for numerical simulation calculation.
    Shear Strength and Failure Characteristics of Cemented Backfill-rock Combination
    LU Hongjian, WU Xiaojun, CAI Xiaosheng, WANG Yiren
    2023, 52(05):  97-103. 
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    In order to study the shear strength and failure characteristics of the stope backfill and the surrounding rock combination,which are important for the stability of the filling stope. Taking open stoping with subsequent filling stope as the physical prototype,the backfill and surrounding rock were systematically considered to generalize the mechanical model of the cemented backfill-surrounding rock combination,and a calculation method for determining the shear resistence strength parameters of the combination based on the common tangent method of Mohr stress circle and Mohr-Coulomb strength criterion was proposed. The ANSYS numerical simulation test of the combination under different confining pressures was adopted to study the shear strength and failure characteristics of the backfill-wall rock combination with different inclination angles. The study results show that when the inclination angle of the cementation surface is 0° ~ 15°,the failure of the combination mainly occurs in the filling area,and the failure mode is tension shear composite failure. When the dip angle of the cementation surface is 30° ~ 60°,the failure of the combination occurs in the area of the filling body and the contact surface,and the failure mode is shear failure,and as the confining pressure increases,the combined surface will slip and as the cemented surface inclination angle increases,the shear failure surface gradually coincides with the combined surface. When the inclination angle of the cementaiion surface is 75° ~ 90°,the ultimate failure mode of the combination is mainly shear failure of backfill. The study results expand the method for obtaining the shear strength parameters of the backfill-surrounding rock combination,reveal the failure characteristics of the backfill-surrounding rock combination with different contact angle,and provide theoretical support for the stability analysis of the underground backfill stope.
    Slope Stability Numerical Analysis and Mining Depth Optimization of Open-pit Gold Mine
    TAO Zhigang, ZHANG Hui, CHENG Le, YANG Xiaojie, SHI Guangcheng
    2023, 52(05):  104-112. 
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    With the increasing depth of mining,the study of safe mining depth has become more and more important. At present,the slope stability is mainly analyzed by limit equilibrium method,and the stability state of the structural surface is less studied for precise analysis. In view of the current mining situation in the northeast quarry of Changshanhao Gold Mine,through the investigation of engineering geological conditions and rock integrity,the detailed analysis of the damage characteristics of overturning instability of the slope was done. Based on the data of engineering geological investigation and historical borehole logging data,the complex three-dimensional overall model of the northeast quarry of the mine was established by using 3DMine software,and the stability of the final state model of the slope under the current mining design conditions was analyzed. Based on discontinuous deformation analysis (DDA) method,five profiles of the north gang of the quarry were established,and the stability of the slope under the current mining condition and different excavation depths was analyzed. The results show that the complex geological structure of the northeast quarry,the development of joints and fissures,and the extreme fragmentation of the rock body are the key factors for the deformation and damage of the north slope. The current mining design plan will cause the slope destabilization and damage during the excavation and construction process. The analysis of the DDA model verifies the actual speculative damage and simulates the stability under different excavation depth conditions,and the critical depth occurs when the bottom of the pit is 84 m away from the final design boundary,which provides relevant reference for the design of open-pit mining.
    Optimization Method of Hole Density in Rock Roadway Blasting with Digital Electronic Detonator
    WANG Yanbing, WANG Guohao, BAO Zhouqi, XIE Ping, ZHANG Yinghao
    2023, 52(05):  113-121. 
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    The density of shot holes in most projects in rock roadway driving is 5 per square meter,and the high number of holes restricts the efficiency of rock roadway driving to a certain extent. How to reduce the number of holes under the premise of ensuring the blasting efficiency has become an urgent problem to be solved. In this paper,relevant research is carried out from literature inspection method and field experiments. By sorting out relevant literature of coal mine and metal mine roadway excavation,several dimensions,such as section size,section area,hole density and cut area proportion,are analyzed and studied. At the same time,the proportion of cut area and shot hole density are fitted linearly. The results show that in practical engineering cases,the larger the cut area,the lower the hole density. On this basis,a perforation arrangement scheme combining digital electronic detonator is proposed,and it is applied to Gubei Coal Mine in Huainan City. The test results show that compared with the original scheme,the new scheme can increase the utilization rate of shot holes by 14. 34%,reduce the number of shot holes by 28. 33%,and reduce the cycle period from 10. 8 h to 9. 9 h,which can greatly indicate the monthly footage roadway excavation,and is expected to be popularized and applied in rock tunneling construction.
    Effect and Mechanism of Novel Organic Inhibitors on Flotation Separation of Fluorite and Calcite
    ZHOU Hepeng, WU Handan, GONG Lei, TANG Xuekun, LUO Xianping
    2023, 52(05):  122-128. 
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    Fluorite and calcite have similar surface properties,that is,the same active calcium particles,which makes it very difficult to separate the two minerals in the flotation process. In this paper,the environmental protection water-soluble phosphonate sodium ethylenediamine tetramethylene phosphonate (EDTMPS) was proposed for the first time to strengthen the flotation separation of fluorite and calcite,and related flotation tests were carried out. The results show that EDTMPS can effectively inhibit the flotation of calcite,but has little effect on the flotation behavior of fluorite when the pH value of pulp is 7~ 9. The flotation test of artificial mixed ore proves that the separation of calcite and fluorite can be realized by using EDTMPS as an inhibitor. The mechanism of separation of calcite from fluorite by EDTMPS inhibitor was studied and analyzed. It was found that phosphonate ions in EDTMPS molecular structure chemically adsorbed with calcium ions on calcite surface,which hindered the further adsorption of oleate ions. Comparatively speaking,EDTMPS had little adsorption on fluorite surface and little floatability. Generally speaking,EDTMPS inhibitors can selectively inhibit calcite,which has a wide application prospect in the flotation separation of calcite and fluorite.
    Mechanism of Selective Flocculation of Hematite and Quartz with Ca(Ⅱ )-XG Complexes
    YANG Zhichao, HAN Yingqi, TENG Qing, ZHANG Guoyang
    2023, 52(05):  129-136. 
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    Ca(Ⅱ ) being the coagulant and xanthan gum being the flocculant were used in the system of selective flocculation separation of hematite from quartz,but Ca(Ⅱ ) -XG complex was formed by calcium ion and xanthan gum inevitably. The study,Ca(Ⅱ )-XG selective flocculation separation hematite from quartz,is significance for the hematite ore quality improvement. Flocculation settling tests combined with microscopic observation,Zeta potential,solution chemical calculation,and infrared spectra analysis were used to study the behavior and mechanism of Ca( Ⅱ )-XG selective flocculation separation hematite from quartz. The results of flocculation settling tests showed that the gap in settling between hematite and quartz decreased with increasing of the pH value of pulp,and the effect of Ca(Ⅱ ) on the gap in settling between hematite and quartz was insignificancy. Furthermore,the complexes made by combining xanthan gum with calcium chloride at a mass ratio of 1 ∶9 demonstrated strong selective flocculation of hematite and quartz. At pH = 2,the gap in settling rates between the two minrals was the greatest,reaching 85% and 30%,respectively. The results of microscopic observation indicated that quartz particles essentially nonflocculation whereas the hematite particles flocculated by complexes tend to form larger flocs. Zeta potential,solution chemical calculation and infrared spectra analysis showed that there was chemisorption and the electrostatic gravitational force between the complexes and hematite and quartz,in which the chemical interaction with hematite being stronger than the interaction with quartz. Based on the experimental data and analytical,a model schematic for the complexes′ selective flocculation of hematite with quartz was created. So,the selective flocculation separation of hematite from quartz can be made by changing the ratio of xanthan gum and Ca(Ⅱ ) in Ca(Ⅱ )-XG complex and the pH value of pulp,which could provide new strategy and theoretical basis for selective flocculation separation of hematite ore.
    Research on Collision Characteristic of Media in Vertical Stirred Mill Based on EDEM
    LI Guofeng, LI Chunnan, LIU Liwei, LI Yanfeng
    2023, 52(05):  137-143. 
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    The stirred mill is more suitable for fine grinding of ore than ball mill. In the actual grinding process,it is difficult to measure the internal working state of the stirred mill directly. It has become one of the important research methods to analyze the internal working state of the stirred mill with the help of simulation technology. In this study,a laboratory vertical stirred mill was taken as the prototype. The collision characteristics of media in stirred mill were analyzed using EDEM discrete element simulation software. The influences of process parameters,such as medium ratio,filling rate,and agitator speed,on the motion velocity of media,number of collisions,collision force,and collision energy were investigated systematically. The results showed that the motion velocity of the media,maximum normal force of collision,and collision energy increased with increasing the media ratio of ϕ5 mm and ϕ3 mm,but the number of collisions decreased. With increasing filling rate,the number of collisions was increased,but the motion velocity of media,maximum normal force of collision,and collision energy was decreased gradually. Meanwhile,a higher rotate speed of stirrer gave an increased motion velocity of the media,number of collisions,maximum normal force of collision,and collision energy. The results of this paper revealed the motion state of the media in the stirring mill,which also provided certain guiding for the selection of suitable grinding process parameters.
    Experimental Study on the Evolution of Acoustic Emission and Wave Velocity of Rock under True Triaxial Step-loading
    LI Nan, CHEN Peng, LI Yan, CAI Chao, TANG Zhenyu, YANG Congxin
    2023, 52(05):  144-154. 
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    In order to study the evolution law of acoustic emission and wave velocity of rock under true triaxial step-loading. The self-developed rock true triaxial testing machine,acoustic emission monitoring system and ultrasonic testing system are adopted. The acoustic emission location monitoring and ultrasonic testing experiments of rock under true triaxial graded loading were carried out. The study results show that the change trend of AE cumulative energy and cumulative count can be used as the precursor information of rock fracture. In the first stage,the increase is small as the rock is compacted. In the second,third and fourth stages,the internal fractures of sandstone began to develop and their growth rate increased slowly. The fifth stage is the main stage of sandstone damage,with an increase of more than 80%. It is inferred that the sandstone in the fifth stage is unstable due to the stress reaching the peak strength. Acoustic emission location technology can well characterize the crack morphology and propagation law. In the first,second and third stages,acoustic emission localization events rarely occur in the sandstone and the distribution is relatively scattered. In the fourth and fifth stages,a large number of acoustic emission localization events occurred and concentrated on the fracture surface and fracture zone on both sides of the minimum and intermediate principal stress directions. The variation of ultrasonic wave velocity has a good response to the internal deformation and fracture propagation of rock. The rock wave velocity is anisotropic during loading. The wave velocity in the direction of maximum principal stress increases as the rock is compacted. And the increase of wave velocity decreases with the decrease of rock compaction. The wave velocity in the direction of the intermediate principal stress increases first as the rock is compacted. And then the wave velocity decreases with the formation of rock fracture surface. The wave velocity in the direction of the minimum principal stress first increases with the compaction of the rock. Subsequently,as the rock forms a penetrating fracture surface and is accompanied by a fracture zone,the wave velocity rapidly attenuates and plummets to a lower level.
    Study on the Effect of Water on the Damage and Temperature Rise of Quartz Sandstone by Microwave Radiation
    CHEN Denghong, WANG Chaojia, WANG Zhipeng, LU Depei, TANG Yunying, YANG Bo
    2023, 52(05):  155-164. 
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    Compared with drilling and blasting and mechanical rock breaking,microwave assisted rock breaking is considered as a promising new method for hard rock excavation because of its advantages such as selective heating,high efficiency and strong controllability. In order to explore the influence of water on the assisted rock-breaking effect of microwave radiation on quartz sandstone with low wave-absorbing capacity,1. 4 kW microwave radiation was applied to quartz sandstone with different water content for 0~ 300 s to explore the relationship between temperature rise,damage and water content. According to the damage factors represented by wave velocity,such as damage factor Dm,surface temperature difference FT after microwave irradiation and Brazilian splitting tensile strength σt,the influence rule of temperature rise damage was comprehensively analyzed. The results show that the quartz sandstone in microwave radiation drying state presents a rapid temperature rise in the early stage,a slow and stable trend in the later stage,and the temperature difference increases first and then decreases. In addition to saturated water,the temperature rise rate of specimens with different moisture content in 90 s radiation increased from fast to slow down and opened a gap at 6 h after absorbing water (average moisture content 1. 88%). The change amplitude of FT,Dm and σ t does not change gradients with the increase of immersion time. The wave velocity and the damage factor Dm represented by the immersion time (water content 1. 69% ~ 1. 88%) show an " inflection point" of decrease and increase. The average decrease in the former increased by 5. 18%,while the latter increased by 0. 092,σt has increased by 25. 9%. The temperature rise damage process in rock microwave field is the result of multi-scale and multi-medium comprehensive response under the influence of water-rock coupling. Specific water content (1. 69% ~ 1. 88%) and radiation duration (more than 90 s) can promote the generation of thermal stress gradient after microwave absorption of quartz sandstone,thus causing pore damage and reducing ultimate tensile strength,making it more vulnerable to destruction. The analysis results can provide a reliable reference for the study and analysis of microwave radiation heating damage to hard rock under similar conditions.
    Development and Application of Comprehensive Monitoring and Early Warning System for Ground Pressure Disaster in Deep Broken Roadway
    WANG Wenjie, HUO Chunze, YANG Jinwei, KOU Yongyuan
    2023, 52(05):  165-174. 
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    Based on the concept of browser / server ( B / S) layered architecture design,combined with connection pooling,multi-threading,front and back-end separation and other technologies,a comprehensive monitoring and early warning system for ground pressure disasters with multiple sources of information such as acoustic emission,stress,displacement and microseismic Internet of Things (IoT) has been developed to address the problem of ground pressure disasters that are prone to occur after mines enter deep mining. The cumulative difference index and fuzzy comprehensive evaluation algorithm are used to analyze the acoustic emission parameters and establish a multi-index early warning model for acoustic emission,which is embedded in the Quartz timing task framework to realize the integration of real-time acoustic emission monitoring data and intelligent risk warning. Through the real-time disaster monitoring and early warning test of the filling body roof in the No. 2 layered stope of 1 018 m level Ⅴ panel of Jinchuan No. 2 mining area,the results show that:the early warning result of the acoustic emission cumulative difference multi-index comprehensive early warning model is consistent with the actual situation,which overcomes the defect of one-sided early warning of a single index and improves the reliability of early warning;The system realizes the functions of remote configuration of different types of equipment,automatic collection,analysis,early warning and visualization of monitoring data,and has important guiding significance for ground pressure disaster monitoring and early warning of deep broken roadways.
    Design and Development of Signal Synchronous Transmission System for Transmission Detection in Mine Working Face
    XU Xianlei, LI Jinglin, GUO Aijun, ZHANG Di, LIANG Peng
    2023, 52(05):  175-184. 
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    Mine geological transparency is the basic guarantee of intelligent coal mining,CT transmission detection based on geological radar can realize high-precision detection of hidden disaster causing bodies in large-span (80 ~ 300 m) mining area,and whether the nanosecond-level high-frequency synchronous pulse signal and personnel communication information of geological radar can achieve long-distance real-time mobile transmission directly determines the working efficiency and detection accuracy of CT transmission detection of large-span working face geological radar. In view of the problem of low signal transmission efficiency and difficult synchronization,this paper proposes a mine face CT transmission detection optical fiber transmission and communication control scheme based on geological radar,designs and develops an intelligent signal synchronous transmission communication system,uses STM32F407 as the main control chip supplemented by voice acquisition and playback circuit,photoelectric conversion and transmission circuit and other hardware parts of the communication system,and designs and develops the control software part of the communication system based on the Keil uVision5 development environment. A prototype communication handheld terminal has been formed,aiming to realize CT transmission and synchronous communication of CT transmission detection of mine working face. The test results show that the real-time transmission distance of the system can reach 6 000 m under mine conditions,and the transmission delay time of high-frequency synchronization signal and voice signal of geological radar is 5. 93 ns / m and 1. 9 ms / m,respectively. Compared with the existing transmission and communication methods,the system simplifies the structure of the radar system, realizes the long-distance real-time mobile transmission of high-frequency synchronous signals and voice signals of geological radar,and provides technical support for the construction of mine geological security assurance platform.
    Case Study of Rock Mass Multi-source Acoustic Equipment in Monitoring and Prevention of Ground Pressure and Roof Disaster
    DONG Longjun, YAN Xianhang, PEI Zhongwei, SUN Daoyuan
    2023, 52(05):  185-194. 
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    With the increase of mining depth,underground mining conditions tend to be complicated,and it is easy to form ground pressure problems such as roof falling,caving,and caving in the mining process. The internal fracture signal of rock material and multi-source external disturbance are monitored by acoustic equipment for nondestructive testing of the dynamic failure behavior of rock material. Compared with other monitoring equipment,it has the characteristics of a wide frequency band,high locating accuracy of the focal source,accurate identification of danger area,and multi-index joint warning of instability disaster. Particularly,a large number of noise signals such as blasting and drilling are used for wave velocity field imaging after positioning and identification by changing " waste noise" to " useful signal" . This technology breaks through the technical defects of the traditional monitoring methods of " point" and " line" ,and realizes the transformation to " field" and " volume" monitoring and recognition. On the basis of analyzing the propagation principle of internal fracture signals of rock materials and acoustic signals of multi-source external disturbance,a multi-source acoustic acoustics sensing acquisition system is developed independently by the research group,and it is applied to the Zhen′ao Pb-Zn Mine in Shaanxi Province and the No. 2 mining area of Jinchuan Group. The stability of the goaf roof and filling body roof is monitored and analyzed by microseismic tomography and multi-source acoustic parameters in real-time. In conclusion,some advice for the identification and warning of underground pressure and roof instability disasters is constructed by these cases. The study results show that the abnormal position of wave velocity field and rock mass multi-source acoustic parameters can be intuitively and effectively found in the monitoring area,and the health condition of the roof in the mining process can be reflected in real-time,which plays a vital role in disaster monitoring and prevention and control. It is worth noting that,even if the monitoring results temporarily show that the roof is relatively stable, there may be events with large energy and seismic magnitude due to the influence of the mining process,subsidence and delamination of the backfill body,etc. Therefore,it is necessary to combine the actual site situation, mining plan,and the changing trend of multi-source acoustic parameters of rock mass,and check relevant hidden dangers on site. Combined with centralized leadership organization and overall arrangement and management,the multi-source acoustic intelligent monitoring and early warning level of mine disasters have been improved.
    Development and Application of Quantitative Analysis Software for Blasting Dust Reduction Effect Based on Matlab
    WANG Quan, YANG Li′ao, LI Ye, HUANG Xiaoming, LI Rui
    2023, 52(05):  195-201. 
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    The process of open-pit mining generates a large amount of dust,which is characterized by fast diffusion,high concentration and transient nature,endangering the health of site workers and causing pollution to the environment. In recent years,scholars have conducted more research on blasting dust movement law and dust reduction technology,but the specific blasting dust reduction effect data testing is tedious,and the accuracy is not enough,which leads to a more perfect quantitative evaluation system for the effect of blasting dust reduction in open-pit mines has not been formed yet. To address this problem, the relationship between image grayscale values and dust concentration is analyzed based on the characteristics of the open-pit mine environment,and combined with the rule that blasting dust in open-pit mines is mainly concentrated in the dust clusters formed after blasting,a quantitative analysis software of blasting dust reduction effect based on Matlab software is designed and developed by using image analysis means. The software can calculate the dust reduction efficiency of dust reduction blasting, show the spatial distribution of dust concentration based on the given blasting dust image information,and conduct field application studies with an open-pit mine of Anhui Conch Group as the study example. The results show that the error of the software on the calculation of dust reduction efficiency is lower than 8%,and the operation process is convenient to meet the actual testing requirements. The software can quantitatively analyze the blasting dust reduction effect,and provide reliable reference for the evaluation and optimization of the effects of blasting dust reduction operations.
    Rockburst Grade Prediction Based on Grey Correlation Analysis and SSA-RF Model
    MAN Ke, WU Liwen, LIU Xiaoli, SONG Zhifei, LIU Zongxu, LIU Ruilin, CAO Zixiang
    2023, 52(05):  202-212. 
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    Rockburst disasters occur frequently in mine roadways,traffic tunnels and other projects,and rockburst prediction has become particularly important. In order to improve the prediction accuracy of rockburst grade and the generalization of prediction model,an SSA-RF model using sparrow search algorithm (SSA) to optimize the random forest algorithm (RF) model was proposed. Considering the rationality of the rockburst grade prediction indicators,the four sets of schemes were selected based on the characteristics of rockburst genesis and the grey correlation analysis results to determine the best combination of prediction indicators,and the importance analysis of model was used to verify the rationality of the best combination of prediction indicators. The first scheme retained all the prediction indicators as a comparison item,the second scheme sieved out the two prediction indicators of low grey correlation with rockburst grade,the third scheme adopted composite indicators,and the fourth scheme adopted independent indicators. A total of 151 rockburst sample data were collected as model datasets,the prediction effect of SSA-RF model was compared with seven other prediction methods,and the sensitivity analysis of model for different sample sizes was analyzed. The results show that the second scheme is the best one,and the best combination of prediction indicators is tangential stress in surrounding rock, stress coefficient, elastic energy index and uniaxial compressive strength. Compared with the other seven prediction methods,the SSA-RF model has the highest prediction accuracy and the average accuracy reaches 88. 09% in the four sets of schemes,and even reaches 95. 23% in the best scheme. The prediction indicators of SSA-RF model are more reasonable in importance ranking than that of RF model,and effectively verify the rationality of the best combination of prediction indicators. The use of SSA algorithm to optimize the RF model can improve the prediction accuracy and generalization of the RF model for different rockburst sample volumes,and effectively compensate for the shortcomings of the randomness of the RF model. In summary,it can be seen that the SSA-RF model is feasible and effective for predicting the rockburst grade of actual engineering.
    Assessment of Short-term Ecological Environment Losses Induced by Tailings Dam-break Based on Ecosystem Service Value
    JIANG Shuihua, PENG Hao, YU Qi, YAO Chi, HUANG Jinsong
    2023, 52(05):  213-220. 
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    The dam-break of tailings reservoir not only threatens the downstream life and property safety,but also seriously destroys the local ecological environment. To quantitatively assess the ecological environment losses caused by the tailings dam-break,based on the simulation of the evolution process of the dam-break tailings flow,a assessment method for ecological environment losses induced by tailings dam-break based on ecosystem service value is proposed. An iron tailings reservoir in Jiangxi Province is taken as a typical case to simulate the evolution process of discharged tailings flow due to dam-break. The distribution and risk degree zoning of the downstream affected area of the tailings reservoir are obtained. Based on these,the short-term ecological environment losses induced by the tailings dam-break are evaluated from the perspective of ecosystem service value. The results indicate that the evolution process of the dam-break tailings flow can be effectively simulated using Bingham rheological model,and the disaster situation in the downstream area of tailings reservoir can be obtained. The ecosystem affected by dam-break in the downstream area of tailings reservoir mainly includes forest ecosystem and farmland ecosystem,among which the forest ecosystem suffers the largest proportion of losses. The proposed method can provide a theoretical reference for ecological environment losses assessment caused by overtopping dam-break in similar tailings reservoir projects.
    Improved Kriging Location Method Based on Particle Swarm Optimization and Simulated Annealing Algorithms
    HU Qingsong, LIANG Tianhe, LI Shiyin, SUN Yanjing
    2023, 52(05):  221-227. 
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    Location information is very important for personnel management and post-disaster rescue in mine operation. Fingerprint location can significantly improve the accuracy of mine location,but the time-consuming and laborious process of fingerprint database construction hinders its large-scale application. Therefore,a Kriging interpolation algorithm (PSO-SA-Kriging) based on particle swarm optimization and simulated annealing was proposed. Only partial data of fingerprint sampling points were collected in the initial stage,and all fingerprint data sets were obtained by Kriging model interpolation based on the data of these sampling points,and the Kriging theoretical model was optimized by particle swarm optimization and simulated annealing algorithms. The constructed fingerprint database is more suitable for the actual mine environment. The algorithm takes advantage of the particle swarm convergence speed to solve the problem of rapid construction of fingerprint database. At the same time,simulated annealing is used to overcome the defect that particle swarm may fall into local optimal,which makes model fitting more accurate and interpolation results more accurate. Based on the above analysis results,by collecting fingerprint data in the mine environment,a total sampling database,a mixed database of half sampling and interpolation are established,and the nearest neighbor algorithm (KNN) is used to verify the proposed method. The results show that POS-SA-Kriging algorithm not only greatly reduces the fingerprint construction workload,but also significantly improves the location accuracy,realizing the joint optimization of the fingerprint database construction speed and target location accuracy.
    Intelligent Detection Algorithm of Obstacles in Front of Open-pit Mine Cars Based on Swin Transformer and CNN
    JIANG Song, KONG Ruonan, LI Pengcheng, LU Caiwu, ZHANG Sai, LI Meng
    2023, 52(05):  228-236. 
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    With the deepening of metal open-pit mining,the road transportation conditions become more and more complex,and unmanned mining cards driving on the road faces the safety hazards of various obstacles,so the intelligent detection of obstacles for unmanned mine cards has put forward higher requirements. In this paper,a fusion of Swin Transformer and Convolutional Neural Network (CNN) for the intelligent detection of obstacles in front of open-pit mining trucks is proposed. The obstacle detection model needs to establish long-term dependencies to deal with increasing image data,and Swin Transformer can focus on global semantic information,which is beneficial to long-term modeling. The Swin Transformer is incorporated into the backbone feature extraction network of the YOLOX model to make full use of the multi-headed attention mechanism to preprocess image features,and the CBAM attention mechanism module is added to the enhanced feature extraction network to enable the model to extract more representational information in the subsequent feature extraction. The datasets used in the model are all from field mines and are pre-processed using data enhancement. After field mine data comparison and validation experiments,the results show that:the method can effectively identify unstructured road obstacles in metal open-pit mine with a complex background,and the detection accuracy reaches 91. 57% mAP,the detection speed reaches 56. 86 fps,with better small target and multi-scale target detection performance,which can meet the unmanned mine card in metal open pit with high accuracy detection requirements.
    Subway Tunnel Point Cloud Semantic Segmentation Network Model Based on Spatial Geometric Feature Fusion
    ZHANG Qiuzhao, LIANG Jiahui, DUAN Haoran, WANG Zongwei, DUAN Wei
    2023, 52(05):  237-246. 
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    The tunnel point cloud semantic segmentation technology based on deep learning can recognize and classify objects in large-scale point cloud data,and realize the extraction and management of object information in tunnel scenes. A subway tunnel point cloud semantic segmentation network model based on enhanced spatial geometric feature fusion is proposed in this paper,which takes into account the spatial distribution characteristics and geometric features of subway tunnel facilities. A spatial geometric feature extraction module is designed to extract the relative spatial positions and geometric distribution features of tunnel facilities and combines them with the features of the network encoding layer through channel concatenation,enhancing the network′s perception of multi-scale feature information. A feature fusion encoding layer based on channel attention mechanism is designed to extract the weight of features between different channels,and to perform weighted fusion of the information from different spatial scales,so as to fully utilize information of different scales to improve model representation and generalization abilities. The network model proposed in this paper is verified using a dataset made by the point cloud data of a tunnel in Nanjing Subway. The experimental results demonstrate that the proposed network achieved a training mIoU value of 0. 955 6. The predicted results on the test dataset showed a weighted average F1 score of 0. 995 9 and a weighted average IoUvalue of 0. 963 1. For the communication cables,pipeline racks,and contact hangers classes with poor IoU values in the PointNet++ network,the IoU values of the proposed network reached 0. 845,0. 825,and 0. 999,respectively,which effectively improved the overall accuracy of point cloud segmentation of subway tunnel and provided a technical reference for realizing automatic disease inspection and facility management of subway tunnel.
    3D Training Image Construction Method for Reserve Calculation of Mineral Resources
    WANG Yongzhi, CHEN Yuliang, XIE Minmin, YU Mengrou, HU Xiaoyu, WANG Baojuan
    2023, 52(05):  247-253. 
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    The calculation of mineral resources reserves is helpful to the rational development and utilization of mineral resources. At present,multi-point geostatistics is a popular technology for the calculation of mineral resources reserves,but it is difficult to construct high-quality three-dimensional training images in multi-point geostatistics. Therefore,a 3D training image construction method for mineral resource reserve calculation was proposed. Firstly,the 3D geological model is constructed based on the original borehole data,and the volume element model was obtained by using the irregular tetrahedral mesh. Secondly, based on the borehole attribute data,the regular volume element grade model was constructed by interpolation algorithm,and the attribute was assigned by Euclidean distance to the volume element model to obtain the 3D training image. Finally,the Snesim algorithm improved by multi-point geostatistics was used to construct a search tree to obtain the conditional probability,and the attribute of the volume element model was assigned based on a attribute fusion of correlative,and the mineral resources reserves were calculated. Taking the Heiniudong Ⅰ -3 orebody as an example,the average grade of copper in Ⅰ -3 orebody is calculated to be 2. 90%,the average grade of copper after mining is 2. 33%,the difference between them is only 0. 57 percentage points,which proves the correctness and effectiveness of the proposed method
    Recovery Test of a Low-grade Copper-molybdenum Ore in Xinjiang by Flotation
    LI Shaoping, LI Baiying, WANG Jinke, LIN Ziyan, CHANG Zhiguo, ZHANG Weiguang
    2023, 52(05):  254-259. 
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    The grade of Cu and Mo in a low-grade copper-molybdenum ore in Xinjiang is 0. 81% and 0. 02%,respectively. The main recoverable minerals are chalcopyrite and molybdenite, and the gangue minerals are mainly pyrite, feldspar, quartz,diopside,tremolite and calcite. In order to recover copper and molybdenum from ore effectively,mixed flotation process was used to carry out beneficiation test aiming at ores propertites. The optimum roughing conditions were determined by single factor test as grinding fineness of -0. 074 mm accounting for 60%,lime dosage of 500 g / t,sodium hexametaphosphate dosage of 30 g / t,combined collector total dosage of 60 g / t ( mass ratio of butyl xanthate to Z-200 of 1 ∶1),and 2# oil dosage of 15 g / t. On this basis,the closed-circuit flotation process of " one mixed roughing flotation,three blank cleaning flotation and three scavenging flotation" was adopted to treat the ore. Finally,the copper and molybdenum mixed flotation concentrate with Cu grade of 25. 16%,Cu recovery rate of 94. 02%,Mo grade of 0. 59% and Mo recovery rate of 90. 21% could be obtained. The comprehensive recovery of valuable metals from low grade copper molybdenum ore is realized.
    Experimental Study on Recovery of Fluorite From Skarn Type Tungsten Tailings by Magnetic and Flotation Combined Process
    WANG Zhiping, WANG Chenghang, ZOU Jianjian, LIN Hui, LI Qiang
    2023, 52(05):  260-265. 
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    In order to effectively utilize fluorite from a tungsten tailings in Jiangxi Province,based on the properties of the tailings,the beneficiation process of pre-enrichment fluorite by high-intensity magnetic separation tailing discarding and highefficiency enrichment by flotation was determined to carry out comprehensive recovery tests. After the preconcentration of tailing samples with " one roughing and one cleaning" high gradient high-intensity magnetic separation,fluorite and calcite were enriched to non-magnetic products and high-intensity magnetic medium ore. The cumulative recovery rates of CaF2 and CaCO3 reached 94. 82% and 94. 77%,respectively,while the grade of CaF2 and CaCO3 of high intensity magnetic products decreased to 3. 29% and 2. 96%,respectively. The non-magnetic product and high-intensity magnetic medium ore were combined into flotation feeding for carrying out the reagent system research. The condition test confirmed that GYSH was used as silicon mineral inhibitor,and the appropriate dosage was 3 000 g / t. GY51 was used as carbonate mineral inhibitor,and the appropriate dosage was 150 g / t. The suitable dosage of GYOZ as a fluorite collector is 150 g / t. Under the conditions of suitable reagent system, fluorite concentrate with CaF 2 grade of 96. 37%,CaF2 recovery rate of 84. 58% and CaCO3 content of 1. 57% was obtained in the closed-circuit test of the whole process. The developed process flow and reagent system can greatly reduce the flotation treatment amount of fluorite,realize the efficient recovery of fluorite,and provide a technical basis for the utilization of the same type of tungsten tailings.
    Research Status and Prospect on Mineral Processing and Metallurgical of Strategic Nickel-Cobalt Sulfide Ores Resources
    ZHANG Wenpu, ZHAO Kaile, YAN Shiqiang, SONG Jun, YANG Yaohui, WU Weilong
    2023, 52(05):  266-275. 
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    Based on the development background of " dual carbon" and the overview of nickel and cobalt resources,this paper summarizes and prospects the current research status of nickel and cobalt sulfide ore processing and smelting. The distribution and reserves of nickel and cobalt resources at home and abroad,as well as the difficulties in the mineral processing and smelting process of nickel and cobalt sulfide ore resources in China were summarized;The traditional mineral processing and smelting processes and improvements of nickel and cobalt sulfide ores in China were summarized. Research has shown that the main mineral processing methods for nickel sulfide ore include flotation,gravity separation,chemical beneficiation,and biological beneficiation;The main processing methods for cobalt sulfide ore include flotation and gravity separation. Among them,flotation has the advantages of strong applicability and fast processing efficiency,and is still the most effective and practical beneficiation process for treating nickel and cobalt sulfide ores. Mixed flotation is currently the process still used by the vast majority of nickel and cobalt sulfide ore beneficiation plants in China;The stage grinding and stage selection process is scientific and can effectively solve the problem of over crushing;The research focus of flotation reagents mainly focuses on the combination of collectors and the development of new green dispersants and depressants;The research on biological beneficiation has also made corresponding progress. Gravity separation is mainly used for pre enrichment in cobalt sulfide ore,which can improve the grade and processing capacity of the beneficiation plant. Commonly used methods include heavy medium beneficiation,spiral beneficiation,and shaker beneficiation. The metallurgical methods of nickel sulfide ore include pyrometallurgy,hydrometallurgy,and biological metallurgy;The main metallurgical methods for cobalt sulfide ore include pyrometallurgical wet metallurgy and full wet metallurgy. Among them,pyrometallurgy has the advantages of high efficiency and mature technology,which is still the main metallurgical process for nickel sulfide ore. However,it has the disadvantage of high energy consumption and high emissions,and research on relevant improvement measures has been a focus in recent years;Fire metallurgy is gradually transitioning towards low energy consumption and carbon emissions in hydrometallurgy. Roasting water leaching is a combination of fire metallurgy and hydrometallurgy,among which chlorination roasting water leaching has good application prospects. The metallurgical process of cobalt sulfide ore usually requires a roasting leaching electrolysis process. Finally,the key development directions for the research prospects of nickel cobalt sulfide ore beneficiation and smelting technology were pointed out.
    Discussion on New Process of the Intervention of SO2 Gas into Cobalt Reduction-Leaching Reaction of a Copper-Cobalt Ore in Central Africa #br#
    SHEN Louyan, LI Wenhua, HU Shenchen, ZHAO Hongbo, SHEN Li
    2023, 52(05):  276-281. 
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    In view of the difficulties in the process of cobalt reduction leaching of a copper-cobalt in Central Africa,such as low cobalt leaching rate,low utilization of SO2 gas,and environmental pollution caused by SO2 gas escape,according to the philosophy study of cobalt leaching with SO2 gas and field tests,the creative mode of SO2 gas pressurization and atmospheric pressure combination intervention is adopted by the intervention of three process routes into cobalt reduction and leaching reaction,and the supporting specialized equipment is developed. The new process and its specialized equipment significantly improve the solubility and utilization rate of SO2 gas by complete mixing of SO2 gas and solution and effective control of gas escape,accelerate the regeneration rate of reducing leaching agent Fe2+,and achieve efficient extraction of cobalt by enhancing the synergistic reduction and leaching of SO2 and Fe2+. The on-site test data showed that the new process and its specialized equipment can achieve an increase in the utilization rate of SO2 gas by above 15 percentage points,and a 3 percentage points increase in cobalt leaching rate. While increasing cobalt production capacity,it also reduces production cost and effectively solves the problem of environmental pollution caused by SO2 gas escaping. The study achievement can be used for optimization guidance of copper-cobalt mine enterprises in Central Africa and improve the existing production process of copper-cobalt minerals extraction by the hydrometallurgical process,significantly improve the leaching efficiency of cobalt,thus increasing the production capacity of cobalt,and reduce production cost by improving SO2 gas utilization rate.
    Study on Process Mineralogy of a Platinum-palladium Ore in Zimbabwe
    WANG Huai , ZHAO Shenggui , LIU Jingzhi , YU Zifeng, HU Xueping , HE Yujun
    2023, 52(05):  282-289. 
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    A platinum-palladium mine is located in Zimbabwe′s Great Dyke. In order to master the ore properties and promote the development and utilization of the resource,process mineralogy study was carried out systematically through chemical analysis,optical microscopy,scanning electron microscopy and automated mineral identification & characterization system, etc. The mineral composition,the occurrence state of platinum and palladium minerals,the distribution characteristics and the liberation characteristics of sulfide minerals were found out. The results showed that the grade of platinum and palladium in the ore are 1. 69 g / t and 1. 41 g / t,respectively. The main metallic minerals in the ore are pyrrhotite,nickelpyrite and chalcopyrite, the non-metallic minerals are enstatite and talc,and the platinum group minerals are mainly merenskyite, biteplatinite and braggite. The distribution characteristics of platinum and palladium minerals are quite complicated,and 83. 35% of platinum and palladium minerals are closely related to sulfide minerals. The particle size distribution of platinum and palladium minerals are mainly in the range of 1~ 20 μm,with the distribution rates of 91. 99% and 94. 68%. The particle size distribution of sulfide minerals is relatively uniform,with the distribution rate of +20 μm reaching 90. 65%. The distribution rate of monomer and rich intergrowth sulfide minerals in the ore reach up to 93. 84% under a grinding finessness of 85% passing 74 μm. Considering that platinum and palladium minerals in the ore have a close relationship with sulfide minerals,the sulfide minerals have a coarse dissemination size,and the ore contains a certain amount of talc and chlorite,meanwhile,platinum and palladium minerals are still embedded in the cracks and grains of gangue minerals to a certain extent,it is recommended to choose the principle process flowsheet of two-stage grinding flotation and flotation tailings gravity separation. The principle have much more advantages in reducing bad effect on flotation and improving the recovery of platinum and palladium minerals.
    Influence of Microwave Pretreatment on Leaching Effect of MgO and TFe in Iron-bearing Serpentine Tailings
    ZUO Wei, LIU Wengang, LIU Wenbao , LI Weichao , MAO Yong
    2023, 52(05):  290-295. 
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    In order to make full use of serpentine tailings resources,microwave pretreatment method was used to carry out an experimental study on the enhanced leaching of serpentine tailings. The influence of microwave pretreatment time,power,reaction time,reaction temperature,sulfuric acid concentration and liquid-solid ratio on the leaching effect was investigated,and the enhancement mechanism was analyzed by XRD,SEM,specific surface area and pore structure. The optimum processing parameters were determined by single factor test as microwave pretreatment time of 3 min,microwave power of 400 W,reaction temperature of 90 ℃ ,reaction time of 30 min,sulfuric acid concentration of 4. 0 mol / L,liquid-solid ratio of 4 mL / g. Under these conditions,the leaching rates of MgO and TFe in serpentine can reach 97. 19% and 70. 57%,respectively. Compared with traditional mechanical stirring leaching,microwave pretreatment can shorten the reaction time from 90 min to 30 min without reducing the leaching rate. The mechanism analysis shows that microwave heating removes the hydroxyl group in serpentine,reduces the structure order and crystallinity of magnesium hydroxide octahedron,and increases the dissolution rate and dissolution rate of magnesium and iron in acid. The results provide a new idea for efficient recovery of valuable components in serpentine.
    Test Study on the Vegetation Performance of Vegetative Cement-soil
    LIU Liming, FENG Shanzhou, XU Wennian, ZHOU Mingtao, LI Mingyi
    2023, 52(05):  296-305. 
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    On the basis of the vegetative cement-soil configuration model,in order to investigate the effects of cement, habitat material modifying agent,organic material and organic fertilizer on the vegetation performance of the vegetative cementsoil,the effects of four factors on the vegetation performance of the vegetated cement soil were analyzed through the single-factor proportioning test of cement,habitat material modifying agent,organic material and organic fertilizer. The results showed that each factor had different degrees of influence on the vegetation performance of the vegetative cement-soil,with the increase of cement dosage,the capacity,compactness and pH of the vegetated cement soil gradually increased,with the maximum increase of 7. 4%,51. 6% and 9. 6% respectively,and the porosity gradually decreased,with the maximum decrease of 4. 2%;While the amendment adjusted the pH of the vegetative cement-soil,it contributed to the organic matter content and quick-acting nutrients of the vegetative cement-soil to different degrees,and could effectively improve the biological characteristics of the vegetative cement-soil. The organic materials and organic fertilizers can improve the physical structure of the vegetative cement-soil and enhance the nutrient level of the vegetative cement-soil,thus improving the vegetative properties of the vegetative cement-soil. The results of this study can provide a theoretical basis for the application of ecological slope protection of vegetative cementsoil.
    Study on Adsorption Properties of Typical Iron Oxides on Cu (Ⅱ )
    ZHANG Shizhou, TANG Xuefang, WU Yong, ZANG Qimeng, XIE Zheng
    2023, 52(05):  306-313. 
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    In order to study the removal performance of goethite,hematite,magnetite and ferrihydrite on Cu(Ⅱ ) in simulated Cu(Ⅱ ) contaminated wastewater,four kinds of iron oxides were characterized by XRD,FTIR,BET specific surface area and potentiometric titration. The adsorption performance of four kinds of iron oxides on Cu(Ⅱ ) was compared by static and dynamic migration tests. The results showed that :① When the dosage was 1 g / L and the initial concentration of Cu(Ⅱ ) was 50 mg / L,the adsorption saturation time of Cu(Ⅱ ) by four iron oxides was 30 min. The adsorption effect of Cu(Ⅱ ) was significant under weak acidic conditions. The equilibrium adsorption rates of Cu(Ⅱ ) by goethite,hematite,ferrihydrite and magnetite were 61. 02%,50. 72%,70. 58% and 46. 65%,respectively. ② The adsorption process of goethite and ferrihydrite on Cu(Ⅱ ) is monolayer chemical adsorption,while hematite and magnetite are more in line with Freundlich equation,which is dominated by non-uniform multi-layer chemical adsorption. ③ During the migration process,Cu(Ⅱ ) mainly accumulated in the surface and middle layers of the soil column containing adsorbents,and was much larger than that in the deep layer. The retardation and adsorption capacity of ferrihydrite to Cu(Ⅱ ) was better than that of goethite. ④ The adsorption performance of four kinds of iron oxides on Cu(Ⅱ ) from good to bad was ferrihydrite,goethite,hematite and magnetite.
    Study on Adsorption Properties of Cd2+ in Cd-containing Simulated Wastewater with Biochar Composite Adsorbent #br#
    LIU Zehao, DAI Shujuan, JIA Chunyun, GONG Zongqiang, LI Xiaojun
    2023, 52(05):  314-319. 
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    In order to solve the problems of cadmium ion pollution in water bodies and the resource utilization of solid waste based materials,wheat straw and boron sludge were mixed in equal amounts and calcined at 700 ℃ (nitrogen oxygen displacement) for 2 h to prepare composite biochar adsorption material ( BBm). Using BBm as adsorbent,simulated wastewater containing cadmium with a Cd2+ concentration of 200 mg / L was studied for adsorption. The results of the single-factor test results showed that with the increase of BBm dosage,solution pH,speed and adsorption reaction time,the removal rate of Cd2+ by BBm increased until the removal rate no longer increased after the adsorption equilibrium. The orthogonal test results showed that the strength of each factor was as following:solution initial pH value,BBm dosage,speed and reaction time,and 100 mL of simulated wastewater (the concentration of cadmium is 200 mg / L) was adsorbed for 180 min at room temperature ( about 25 ℃ ),BBm dosage of 0. 5 g,pH value of 8 and speed of 200 r / min,and a good index of removal rate of 99. 99% was obtained. The results of adsorption isothermal fitting showed that the adsorption process of BBm to Cd2+ was in line with the Langmuir isothermal adsorption model,and the quasi-secondary kinetic model could better fit the adsorption process.
    Investigation of Radon Concentration and Radioation Level in Non-uranium Metal Mines in Anhui Province
    YIN Chunxu ZHU Weidong HE Tinggui DING Yanqiang
    2023, 52(05):  320-324. 
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    In order to understand the exposure level of miners exposed to radon radioactive hazards in metal mines in Anhui province,ten representative metal mines in Anhui province were selected to investigate and measure radon concentration radioactive levels,and the risk of lung cancer caused by miners exposed to radon was studied. Select the location where mine and ground personnel often stay or pass by,place built-in CR-39 solid track detector,monitor for one month,and then measure the accumulated radon concentration in the laboratory through the solid track measuring system. The average radon concentration of 10 metal mines in this survey is all greater than 100 Bq / m3 except for Mine H,Among them,the average concentration of underground radon in mine E reached 354 Bq / m3,and the maximum concentration of underground radon in the measured location reached 646 Bq / m3. Through analysis of variance,there was no statistical difference between the measured results of surface and underground radon concentration in 10 mines,but there was statistical difference between mine E and the other 9 mines (P <0. 05). The radon concentration of E mine is significantly higher than that of the other nine mines. The investigation and measurement results show that the concentration of radon in non-uranium metal mines in Anhui Province is higher than that in normal indoor radon concentrations. Measures such as strengthening ventilation should be taken to reduce the risk level of lung cancer caused by radon exposure in miners.
    Experimental Study on Permeation-mechanical Properties of Carbon Fiber Based EICP Mineralized Sand Soil
    ZHANG Peng, SUN Zhongping, TAO Zhigang, CHENG Liang, LÜ Qihang, WANG Yawen, ZHENG Junjie, HUO Shoudong, LI Huiru
    2023, 52(05):  325-332. 
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    Soil solidification based on Microbial Induced Carbonate Precipitation ( MICP) or Enzyme-induced Calcium Carbonate Precipitation (EICP) is a trendy green and environmentally friendly foundation treatment technology in the field of geotechnical engineering in recent years. Compared with the MICP method,the EICP method is not easily restricted by environmental factors when dealing with engineering geological problems and the cost is lower. In this paper,a series of experimental studies have been carried out to improve the seepage-mechanical properties of sandy soil by EICP method. The EICP grouting mineralization test was carried out by using the carbon fiber reinforcement method and the porosity,permeability,calcium carbonate content and other indicators of the sand were systematically analyzed. The test results showed that after adding carbon fiber to the sand,under the action of EICP mineralization,CaCO3 crystals have different deposition conditions on the surface of the fiber,the surface of the sand and the fiber are roughened to different degrees and the pores between the sand particles can be filled and cemented. When the content of carbon fiber is 1. 2%,the performance in all aspects is optimal. The above test results show that the carbon fiber-based EICP mineralization method can inhibit the brittle failure of sand and improve the permeability-mechanical properties of sand. Under the background of " Dual Carbon" ,it has good application prospects and development potential.
    Effect of Bacterial Concentration and Ratio on Solidification of Tailings by MICP Technology
    FENG Qingjie, JIN Changyu
    2023, 52(05):  333-339. 
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    In order to study the environment-friendly tailings cementing material which can replace cement,the tailings were solidified by microbial induced calcium carbonate precipitation (MICP). The effects of concentration and ratio of bacterial liquid on the solidification effect of tailings under different curing methods were studied by experiment. The results show that the curing effect increases first and then becomes smooth with the concentration of bacteria solution during the aerobic bacteria soaking curing and facultative anaerobic bacteria sealing curing. During immersion curing,the two microorganisms will not affect each other;During sealed curing,high concentration of aerobic bacteria will weaken the curing effect. The content of CaCO3 in the specimen directly affects the strength of the specimen,and the change trend of both is the same. Aerobic bacteria and facultative anaerobic bacteria jointly improve the strength of the specimen,which provides a solution to improve the curing effect of MICP technology on tailings.
    Experimental and Simulation Study on Layout of Electrothermal Wall Materials Prepared by Graphite Solid Waste
    XU Niushuan, REN Zijie, XI Huan, GAO Huimin, LIU Yuhang, YANG Yunping, SONG Yuhan
    2023, 52(05):  340-347. 
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    With the large-scale development of graphite ore and the increasing requirements of environmental protection, the resource utilization of graphite solid waste has become a research hotspot. The graphite solid waste was used to prepare electric heating plate. Different methods such as experiment study,statistical analysis and numerical simulation were used to analyze the influence of laying mode on indoor thermal environment. The results showed that the graphite solid waste based electric heating plate has a good heating effect,double wide surface heating effect is better when the two sides heating,the vertical temperature difference is 2. 7 ℃ ,the horizontal temperature difference is 2. 5 ℃ ;Choose two narrow and one wide surface when heating on three sides,indoor temperature distribution is more uniform,the vertical temperature difference is 2. 5 ℃ ,the horizontal temperature difference is 6. 5 ℃ . The four sides heating effect is the best,the vertical temperature difference is 1. 8 ℃ , the horizontal temperature difference is less than 1 ℃ ,the heating rate is the most stable.
    Research on Road Performance Evaluation of Steel Slag Asphalt Mixture Content Based on Entropy Weight TOPSIS Model
    LUO Jiaqi, CHEN Guoxin, SU Wanzhong, ZHAO Xuzhang
    2023, 52(05):  348-353. 
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    In order to study the effect of different steel slag dosing on the road performance of asphalt mixes,five asphalt mixes with different steel slag volume dosing were prepared by replacing the same size basalt coarse aggregate with steel slag by equal volume,and the high temperature,low temperature and water stability performance of the asphalt mixes were studied. The dynamic stability,rut depth,maximum flexural tensile strain,bending stiffness modulus,residual stability and freeze-thaw splitting strength ratio were selected as evaluation indexes. The comprehensive performance evaluation model of steel slag asphalt mixture was established based on entropy weight TOPSIS method,and the optimal steel slag volume content was determined. The results showed that steel slag can significantly improve the high temperature stability and water stability of asphalt mixes by replacing some basalt coarse aggregates;The low temperature crack resistance of common basalt asphalt mixes is significantly better than that of steel slag asphalt mixes. Based on the entropy-weight TOPSIS theory,the optimal volume dosing of steel slag in asphalt mixes is recommended to be 50%.
    Preparation and Performance Study of Metallurgical Slag Fibre Modified Filling Paste
    LIU Shuangshuang, LIU Di, WU Fei
    2023, 52(05):  354-360. 
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    The resource utilization of metallurgical waste is a difficult and hot issue in the mineral processing industry. The metallurgical silicon slag fiber was used to improve the properties of the mine filling paste,and the basalt fiber and carbon fiber were used as control to discuss the influence of the fiber type and content on the strength of the modified filling paste. Combined with the microscopic test results,the action mechanism of fiber in filling paste systems was analyzed. The results show that the compressive strength of the filling paste increases first and then decreases with the increase of the fiber content. The addition of silica slag fiber has the best reinforcement effect on the filling paste,followed by basalt fiber,and carbon fiber is the worst;The tensile strength enhancement effect is better than the compressive strength;Many cracks appear when the ordinary filling paste is damaged,while the fiber sample doped with silicon slag maintains high integrity when it is damaged;The bridging effect between hydration products and fibers can be effectively inhibited the expansion of the cracks in the specimen, thus enhance the bonding effect of the mortar and promote the improvement of the strength of the filling paste. This study can provide an important reference for the performance improvement of mine filling paste and the utilization of silicon slag fiber resources