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金属矿山 ›› 2009, Vol. 39 ›› Issue (04): 139-142.

• 安全与环保 • 上一篇    下一篇

TiO2/SiO2复合膜光催化降解DDNP废水试验研究

贾维肖1,2,李辽沙1,2   

  1. 1.安徽工业大学;2.安徽省冶金工程与资源综合利用重点实验室
  • 出版日期:2009-04-15 发布日期:2011-11-22
  • 基金资助:

    * 国家科技部863计划项目(编号:2007AA03Z529);安徽省科技平台项目(编号:06094039)。

Experimental Study on the Photocatalytic Degradation of DDNP Waste Water by TiO2/SiO2 Composite Film

Jia Weixiao1,2,Li Liaosha1,2   

  1. 1.Anhui University of Technology;2.Anhui Provincial Key Laboratory of Metallurgy Engineering  &  Resources Recycling
  • Online:2009-04-15 Published:2011-11-22

摘要: 采用液相沉积法在煤矸石烧结滤料表面制备了TiO2/SiO2 复合膜,研究了TiO2/SiO2 复合膜对淮南某化工厂DDNP废水的光催化降解效果。试验结果表明:在将废水稀释20倍(CODCr为318 mg/L,色度为3 750倍),使废水初始pH为3,投加占废水体积0.9%的双氧水,以及光照的同时辅之以曝气条件下,用TiO2/SiO2复合膜对废水光催化降解1 h,废水脱色率和CODCr下降率分别达到75.54%和61.51%,效果比较理想。

关键词: TiO2/SiO2 复合膜, DDNP废水, 光催化降解

Abstract: TiO2/SiO2 composite film made by liquid deposition on the surface of coal fuse sintered filter material was used to study its photocatalytic degradation effect for DNNP waste water from a Huannan chemical plant.The test result achieved a decoloration rate and CODCr decrease of 75.54% and 61.51% respectively at one hour degradation with TiO2/SiO2 composite film with also lighting and aeration, where the waste water (CODCr, 318 mg/L and chroma, 3 750 times) was first diluted by 20 times to gain an initial pH of 3, into which oxydol was added at a dosage that was 0.9% of the waste water volume.The result was ideal.

Key words: TiO2/SiO2 composite film, DNNP waste water, Photocatalytic degradation