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金属矿山 ›› 2010, Vol. 39 ›› Issue (03): 17-19+99.

• 采矿工程 • 上一篇    下一篇

黄磷渣充填胶凝材料激发剂的选择与优化

廖国燕,李夕兵,赵国彦   

  1. 中南大学
  • 出版日期:2010-03-15 发布日期:2010-11-09
  • 基金资助:

    国家自然科学基金重大项目(编号:50490274)。

Selection and Optimization of Activators for Cementitious Materials Filled with Yellow Phosphorus Slag

 LIAO  Guo-Yan, LI  Xi-Bing, ZHAO  Guo-Yan   

  1. Central South University
  • Online:2010-03-15 Published:2010-11-09

摘要: 根据黄磷渣的物理、化学和热力学的特点及其活性激发原则,以黄磷渣-磷石膏为研究对象,通过大量室内试验,以不同龄期的充填体抗压强度为指标,研究了不同激发剂种类及掺量对黄磷渣充填胶凝材料的激发效果,分析了黄磷渣在激发剂作用下的水化反应机理。试验结果表明,黄磷渣的活性在NaOH和CaO激发作用下均有较大提高,NaOH和CaO的最佳掺量分别为5%和8%。黄磷渣的水化反应产物存在水化硅酸钙,此外,磷石膏中的硫酸盐在激发黄磷渣活性中也起到了一定作用。

关键词: 黄磷渣, 碱, 激发剂, 抗压强度

Abstract: According to the physical, chemical and thermodynamic characteristics of yellow phosphorus slag as well as its activity principle, based on a large number of indoor tests and the compressive strength of fill in different period, the influences of types of alkali activator, dosage of alkali on compressive strength of cementitious materials filled with yellow phosphorus slag and its hydration reaction mechanism are analyzed. The results show that the yellow phosphorus slag is improved under NaOH and CaO activators, and the best dosage of that two alkalis are 5% and 8% respectively. The hydration product of yellow phosphorus slag includes C-S-H, in addition, the sulfate of the phosphogypsum also played a certain role in stimulating.

Key words: Yellow phosphorus slag, Alkali, Activator, Pressure resistance strength