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金属矿山 ›› 2011, Vol. 40 ›› Issue (07): 106-109.

• 矿物工程 • 上一篇    下一篇

3种捕收剂对氟碳铈矿的浮选性能研究

贾利攀,车小奎,郑其,张雷   

  1. 北京有色金属研究总院
  • 出版日期:2011-07-08 发布日期:2011-07-11

Floatation Study of Three Kinds of Collectors Towards Bastnaesite

Jia Lipan,Che Xiaokui,Zheng Qi,Zhang Lei   

  1. General Research Institute for Non-ferrous Metals,Beijing
  • Online:2011-07-08 Published:2011-07-11

摘要: 研究了不同条件下油酸钠、水杨羟肟酸和牦牛坪稀土捕收剂(主要成分为羟基萘羟肟酸)浮选氟碳铈矿的规律,并对其浮选机理进行了探讨。试验结果表明:捕收剂、硅酸钠的用量对氟碳铈矿的浮选影响显著;油酸钠和牦牛坪稀土捕收剂较水杨羟肟酸有更好的浮选效果;在氟碳铈矿的零电点pH=8.5附近,3种捕收剂对氟碳铈矿的浮选效果最佳;羟肟酸类捕收剂在氟碳铈矿表面发生络合反应,而油酸钠可能以静电吸附和分子吸附为主;药剂在矿物表面的竞争吸附或形成配合物均破坏了缔合羟基;水杨羟肟酸和牦牛坪稀土捕收剂在红外光谱图的2356 cm-1附近有新的峰形成,可能是螯合反应形成的五元螯合环。  

关键词: 油酸钠, 水杨羟肟酸, 羟基萘羟肟酸, 氟碳铈矿, 浮选

Abstract: Under different conditions,the floatation laws of sodium oleate,salicylhydroxami acid and Maoniuping rare earth collector(principal components are hydroxyl naphthalene-containing hydroximic acid) as collectors for bastnaesite are researched and the relative flotation mechanism are studied.Experimental results show:the dosage of collecting agent and sodium silicate has great influence towards bastnaesite floatation;the floatation effect of sodium oleate and Maoniuping rare earth collector is better than that of salicylhydroxami acid;round point of zero charge of bastnaesite where pH=8.5,the three kind of collecting agent have best floatation effect for bastnaesite;for collecting agents as hydroximic acid,complex reaction occers at bastnaesite surface,whereas sodium oleate may react in the manner of electrostatic adsorption and molecular adsorption;Competitive adsorption at mineral surface and formation of complex destroy association hydroxyl,salicylhydroxami acid and Maoniuping rare earth collector has new peak at 2 356 cm-1,and pentatonic chelate loop maybe formats.

Key words: Sodium oleate, Salicylhydroxami acid, Hydroxyl naphthalene hydroximic acid, Bastnaesite, Floatation