欢迎访问《金属矿山》杂志官方网站,今天是 分享到:
×

扫码分享

金属矿山 ›› 2014, Vol. 43 ›› Issue (05): 82-86.

• 矿物工程 • 上一篇    下一篇

新型阴离子捕收剂DL-1反浮选齐大山铁矿混磁精

朱一民,李伟,赵宁宁,骆斌斌,夏夕雯   

  1. 东北大学资源与土木工程学院,辽宁 沈阳 110819
  • 出版日期:2014-05-15 发布日期:2014-09-11
  • 基金资助:

    * 国家自然科学基金项目(编号:51274056),“十二五”国家科技支撑计划项目(编号:2012BAB14B05),国土资源部基金项目(编号:12120113086600)。

Reverse Flotation of the Mixed Magnetic Concentrate of Qidashan Iron Mine by a New Anion Collector DL-1

Zhu Yimin,Li Wei,Zhao Ningning,Luo Binbin,Xia Xiwen   

  1. College of Resource and Civil Engineering,Northeastern University,Shenyang 110819,China
  • Online:2014-05-15 Published:2014-09-11

摘要: DL-1为东北大学新研制的阴离子反浮选捕收剂,为了检验其性能及效果,以齐大山铁矿选矿厂铁品位为46.02%的混磁精为试样进行了反浮选试验,并借助Zeta电位检测和红外光谱分析手段对DL-1反浮选石英的机理进行了探讨。结果表明:①以DL-1为捕收剂,采用1粗1扫、中矿返回闭路流程常温反浮选试验试样,获得了铁品位为65.38%、铁回收率为89.56%的铁精矿;DL-1对温度变化的适应能力较强,且可在CaCl2用量较低的情况下高效捕收试样中的石英。②在pH=9~12的碱性水溶液中,石英与DL-1间存在静电斥力,CaCl2对石英活化后可大大削弱这种静电斥力;在pH=9~11.45的矿浆中,被Ca2+活化的石英与DL-1间既可能发生静电吸附也可能发生化学吸附,而在pH>11.45的矿浆中,被Ca2+活化的石英对DL-1有强烈的静电吸引,因而比在pH=9~11.45区间可以更好地完成对石英的吸附和捕收。③在pH=11.50时,DL-1与石英表面同时存在物理吸附、氢键及化学吸附,因而DL-1对无Ca2+活化的石英也有很好的捕收效果。

关键词: 阴离子捕收剂DL-1, 石英, 混磁精, 反浮选, 作用机理

Abstract: DL-1 is a newly anionic reverse flotation collector developed by Northeastern University.In order to test the floating properties,mixed magnetic concentrate from Qidashan Dressing Plant with Fe grade of 46.02% was used to make reverse flotation tests,and the mechanism in quartz reverse flotation by DL-1 is discussed with Zeta potential measurement and infrared spectrum analysis.The results showed that:①Iron concentrate with Fe grade of 65.38%,recovery of 89.56% was obtained through closed-circuit reverse flotation flowsheet of one roughing,one scavenging,and middles back to the flowsheet in turn with normal temperature and DL-1 as collector; DL-1 can endure temperature changes,and high efficiently collecting quartz at a lower dosage of CaCl2.②There are electrostatic repulsion between quartz and DL-1 with pH of 9~12 in aqueous alkaline solution,and can be weakened by activation of CaCl2 to quartz; electrostatic/chemical adsorption may occur between quartz activated by Ca2+ and DL-1 with pH of 9~11.45,there are strong electrostatic attraction of quartz activated by Ca2+ to DL-1 with pH>11.45,therefore DL-1 can well adsorb and collect quartz at pH range of 9~11.45.③There are physical adsorption,hydrogen bond and chemical adsorption coexist between DL-1 and quartz surface with pH of 11.45,DL-1 can also well collect quartz without Ca2+ activation.

Key words: Anionic collector DL-1, Quartz, Mixed magnetic concentrate, Reverse flotation, Mechanism