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金属矿山 ›› 2014, Vol. 43 ›› Issue (11): 171-174.

• 综合利用 • 上一篇    下一篇

无熟料钢渣矿渣水泥在热养护条件下的强度发展

仇夏杰,倪文,王思静   

  1. 北京科技大学土木与环境工程学院,北京 100083
  • 出版日期:2014-11-15 发布日期:2015-05-21

Strength Development of Steel & Iron Slag Cement without Clinker in the Thermal Curing Condition

Qiu Xiajie,Ni Wen,Wang Sijing   

  1. School of Civil and Environment Engineering,University of Science and Technology Beijing,Beijing 100083,China
  • Online:2014-11-15 Published:2015-05-21

摘要: 为了探讨以鞍钢钢渣与矿渣为主要原料生产无熟料钢渣矿渣水泥的可能性,以鞍钢钢渣与矿渣质量比A、矿渣与钢渣梯级混磨细度B、Ca(OH)2与石膏质量比C、热养护温度D为影响试件不同龄期强度的4因素进行了正交试验,并对胶凝材料的XRD图谱和净浆试块的SEM照片进行了分析。结果表明:①ABCD分别为1∶2、480 m2/kg、2∶1和35 ℃的情况下,试件的抗压强度最高,养护3,7,28 d的抗压强度分别为18.36,26.89和45.32 MPa,这4个因素对试件强度影响的主次顺序为D>A>B>C。②体系的早期强度主要来源于C-S-H凝胶,及少量的钙矾石相;体系后期强度的增强主要依赖于钙矾石相的生成。

关键词: 无熟料钢渣矿渣水泥, 梯级混磨, 热养护温度, C-S-H凝胶, 钙矾石

Abstract: In order to explore the possibility of using Anshan steel slag & iron slag as main raw materials to produce the non clinker slag cement,orthogonal test is conducted to verify different periods of concrete compressive strength with the steel slag to iron slag mass ratio A,ascade mixed grinding fineness B,Ca(OH)2 and gypsum mass ratio C,heat curing temperature D as variable factors.Meanwhile,the XRD spectra of cementitious materials and SEM photo of paste blocks are analyzed.The results showed that:when the A,B,C,D were 1∶2 480 m2/kg,2∶1 and 35 ℃,the cement obtained the highest compressive strength,and its compressive strength were 18.36,26.89,45.32 MPa after curing 3,7,28 days respectively.The strength impact of these four factors on the sample is D>A>B>C.②The early strength of the cement system roots in C-S-H gel and a small amount of ettringite;Its later strength mainly depends on the generation of ettringite.

Key words: Non clinker steel &, iron slag cement, Cascade mixed grinding, Heat curing temperature, C-S-H gel, Ettringite