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金属矿山 ›› 2015, Vol. 44 ›› Issue (03): 112-115.

• 矿物工程 • 上一篇    下一篇

某含石膏硫化钼尾矿中氧化钼钨的混合浮选试验

常学勇1,2,张艳娇1,2,赵平1,2,郭珍旭1,2   

  1. 1.中国地质科学院郑州矿产综合利用研究所,河南 郑州 450006;2.国土资源部多金属矿评价与综合利用重点实验室,河南 郑州 450006
  • 出版日期:2015-03-15 发布日期:2015-07-31
  • 基金资助:

    * 国土资源部地质调查项目(编号:121201130888600)。

Bulk Flotation for Tungsten and Molybdenum Oxide from Molybdenum Sulfide Tailing Containing Gypsum

Chang Xueyong1,2,Zhang Yanjiao1,2,Zhao Ping1,2,Guo Zhenxu1,2   

  1. 1.Zhengzhou Institute of Multipurpose Utilization of Mineral Resources,Chinese Academy of Geological Sciences,Zhengzhou 450006,China;2.Key Laboratory of Polymetallic Ores Evaluation and Comprehensive Utilization,Ministry of Land and Resources,Zhengzhou 450006,China
  • Online:2015-03-15 Published:2015-07-31

摘要: 某优先浮硫化钼的尾矿Mo、WO3品位分别为0.093%和0.12%,-0.074 mm占68.30%,钼钨主要以氧化矿物形式存在,单体解离度达85%,矿石中石膏释放的大量Ca2+和大量矿泥严重影响了氧化钼钨的回收。为高效回收这些氧化钼钨矿物,对现场优先浮硫化钼后的产品进行了选矿试验。结果表明,以硝酸铅为活化剂、苯甲羟肟酸为螯合捕收剂,采用1粗1预精2扫常温钼钨混合浮选,常温混合浮选精矿浓缩至浓度为55%,再在90 ℃恒温解吸45 min,然后采用1粗2精1扫加温精选,中矿顺序返回闭路流程处理该试样,最终取得了Mo、WO3品位分别为15.98%、25.54%、回收率分别为51.54%、63.85%的钼钨混合精矿。

关键词: 石膏, 氧化钼钨矿, 难免离子, 螯合捕收剂, 苯甲羟肟酸, 加温精选

Abstract: The grade of Mo and WO3 in a molybdenum sulfide tailing of flotation is 0.093%,0.012% respectively,with fineness of 68.30% -0.074 mm.The molybdenum and tungsten mainly exists in form of minerals oxide,and its liberation degree reaches 85%.Ca2+ dissolved from gypsum,and great deal of slime ruined the recovery of tungsten and molybdenum oxide.Beneficiation experiments were conducted on the on-site tailings of molybdenum sulfide flotation in order to high efficiently recover the tungsten and molybdenum oxide minerals.The results show that using benzohydroxamic acid as collector and lead nitrate as activator,and through the bulk W-Mo flotation process of one roughing-one precleaning-two scavenging at room temperature,bulk flotation concentrate is concentrated to 55% in density and desorption for 45 min at 90 ℃.Then,through one roughing-two cleaning-one scavenging heating cleaning separation,W-Mo rough concentrate with 15.98% Mo and recovery of 51.54%,and 25.54% WO3 and recovery of 63.85% was achieved.

Key words: Gypsum, Tungsten-molybdenum oxide ore, Inevitable ions, Chelating collector, Benzohydroxamic acid, Heating concentration