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金属矿山 ›› 2015, Vol. 44 ›› Issue (07): 173-177.

• 综合利用 • 上一篇    下一篇

防水剂B和养护温度对铁尾矿三免砖性能的影响

徐民主1,2,雷国元1,2,宋均平3,罗文斌3,谭青3,李瑞杰3   

  1. 1.武汉科技大学资源与环境工程学院,湖北 武汉 430081;2.冶金矿产资源高效利用与造块湖北省重点实验室,湖北 武汉 430081;3.武钢矿业有限责任公司,湖北 武汉 430080
  • 出版日期:2015-07-15 发布日期:2015-08-06
  • 基金资助:

    * 冶金矿产资源高效利用与造块湖北省重点实验室开放基金项目(编号:Mk201211)。

Effect of Waterproofing Agent B and Curing Temperature on Properties of the Burning-free,Autoclave Curing-free and Non-cement Building Bricks Made from Iron Tailings

Xu Minzhu1,2,Lei Guoyuan1,2,Song Junping3,Luo Wenbin3,Tan Qing3,Li Ruijie3   

  1. 1.School of Resources and Environmental Engineering,Wuhan University of Science and Technology,Wuhan 430081,China;2.Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources,Wuhan 430081,China;3.Wuhan Iron and Steel Group Mineral Co.,Ltd.,Wuhan 430080,China
  • Online:2015-07-15 Published:2015-08-06

摘要: 以某细粒低硅铁尾矿和无水泥固化剂为原料,制备免烧免蒸免水泥建材砖(简称“三免砖”)。研究了防水剂B和养护温度对制品抗压强度、耐水性和抗冻性的影响及其机制。试验结果表明:随着防水剂B掺量的增加,制品的干抗压强度和24 h吸水率均下降,饱和抗压强度和软化系数均先升后降;随着初期养护温度的升高,制品的耐水性、抗冻性和各龄期的抗压强度都显著提高。采用XRD和FI-TR分析检测手段进行的机制研究表明:水化硅酸钙胶凝、钙矾石是三免砖的强度黏结相;防水剂B的掺入不会影响强度黏结相构成;提高初期养护温度和使用防水剂能抑制制品内部的碳化反应,并提高制品耐水性能。理论分析结果可以解释养护温度和防水剂B对制品性能的影响,为三免砖制备过程中高效防水剂的筛选及养护条件的优化提供了理论依据。

关键词: 细粒低硅铁尾矿, 三免砖, 防水剂B, 养护温度, 抗压强度, 耐水性

Abstract: Burning-free,autoclave curing-free and non-cement building bricks(three-free for short) were prepared with the fine low-silica iron ore tailing and the self-made non-cement curing agent as the raw material.The effect of the content of waterproofing agent B and curing temperature on the properties of the products such as the compressive strength,water resistance,frost resistance and anti-carbonization,and also its mechanisms were studied.The results showed that with the dosage of waterproofing agent B increase,compressive strength and 24 h water absorption of products decreased while saturated compressive strength and softening coefficient are increased first and then decreased.With the increase of initial curing temperature,water resistance,frost resistance and compressive strength in every curing time are improved significantly.According to the mechanism analysis by XRD and FI-TR,the results show that hydrated calcium silicate gel and ettringite are strength binder phase of three-free bricks.Meanwhile,the addition of waterproofing agent B does not affect the composition of binding phase.The increase of initial curing temperature and the addition of waterproofing agent B can inhibit the carbonation reaction within products and improve water resistance.The results of theoretical analysis can explain the effect of curing temperature and waterproofing agent B on performance of the products.It provides theory basis for the high-effect waterproofing agent and the optimization of the curing conditions.

Key words: Fine low-silica iron ore tailing, “Three-free&rdquo, block, Waterproofing agent B, Curing temperature, Compressive strength, Water resistance