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金属矿山 ›› 2016, Vol. 45 ›› Issue (04): 77-81.

• 矿物工程 • 上一篇    下一篇

熔剂性红土镍矿球团的还原焙烧—弱磁选效果

智谦   

  1. 北京首钢国际工程技术有限公司,北京 100043
  • 出版日期:2016-04-15 发布日期:2016-08-16

Effects of Reduction Roasting-Low Intensity Magnetic Separation on Fluxed Laterite Pellets

Zhi Qian   

  1. Beijing Shougang International Engineering Technology Co.,Ltd.,Beijing 100043,China
  • Online:2016-04-15 Published:2016-08-16

摘要: 回转窑直接还原红土镍矿存在所需温度高、对耐火材料要求苛刻、还原指标差等问题。为开发一种高效低成本的红土镍矿球团还原工艺,考察了以CaO为熔剂改变红土镍矿碱度对红土镍矿球团还原焙烧—弱磁选效果的影响。结果表明:自然碱度下,在还原温度为1 400 ℃、还原时间为60 min时,所得还原产品经磨矿—弱磁选,获得的磁性产品镍、铁品位分别仅3.8%和72.9%,回收率分别为17.8%和39.8%,磁性产品中含有较多的镁橄榄石和顽火辉石;随着红土镍矿碱度的增加,红土镍矿的软熔温度先降低后提高,碱度为1.0时,红土镍矿的软熔温度最低,比自然碱度时降低了100 ℃;碱度为1.0的红土镍矿球团在1 300 ℃下还原焙烧60 min后,经磨矿—弱磁选,获得的磁性产品镍、铁品位分别为8.7%和83.8%,回收率分别为85.6%和62.8%。XRD和扫描电镜分析结果表明:自然碱度的红土镍矿还原焙烧生成的Fe-Ni合金晶粒多在5 μm以下,并且分布比较分散,还原产品中夹杂有较多的杂质;添加CaO至碱度为1.0时,Fe-Ni合金晶粒可以长大到10~50 μm,还原产品中杂质较少,镍和铁得到了明显的富集。试验结果可以为红土镍矿球团还原焙烧—磁选制取镍铁新工艺提供理论基础。

关键词: 红土镍矿, 碱度, 还原焙烧, 弱磁选, 镍铁合金

Abstract: The grate-kiln DR process for the reduction of laterite pellets requires high temperature,which brings about problems such as higher demand of refractory material and poor reducing performance.In order to develop a more efficient process with low cost,the effect of basicity was studied by addition CaO as flux in the pellets.Experimental results show that at reduction temperature 1 400 ℃ for 60 min and the roasted products via grinding-low intensity magnetic separation on natural basicity laterite,the magnetic products with nickel and iron grade of only 3.8% and 72.9%,nickel and iron recovery of 17.8% and 39.8% were obtained,there are much magnesium olivine and enstatite in magnetic products; the fusion temperature of laterite ore could be decreased by 100 ℃ by adjusting the basicity to 1.0,compared with natural basicity; at reduction temperature 1 300 ℃ for 60 min with basicity of 1.0,and the roasted products via grinding-low intensity magnetic separation,the magnetic products with nickel and iron grade of 8.7% and 83.8%,nickel and iron recovery of 85.6% and 62.8% were obtained.The XRD patterns and scanning electron microscope shown that the Fe-Ni particles generated during the reducing of laterite ore with natural basicity distributed dispersedly and the size was generally below 5 μm.What's more,forsterite and enstatite was found in the magnetic material.With the basicity increased to 1.0 through adding CaO,the size of Fe-Ni particles grown to 10~50 μm,and few impurities could be found in the magnetic product.The experimental results could provide fundamental basis for the novel process for preparation of ferronickel from laterite pellets by reduction roasting.

Key words: Nickel Laterite, Basicity, Reduction roasting, Low intensity magnetic separation, Ferronickel alloy