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金属矿山 ›› 2017, Vol. 46 ›› Issue (05): 171-176.

• 安全与环保 • 上一篇    下一篇

某铜钼浮选分离废水的化学沉淀—絮凝沉降试验

朱月锋1,孙春宝2,3,李政良2,3,李春保1,寇珏2,3,李莹1   

  1. 1.云南迪庆有色金属有限责任公司,云南 迪庆 674400;2.北京科技大学土木与资源工程学院,北京 100083;3.金属矿山高效开采与安全教育部重点实验室,北京 100083
  • 出版日期:2017-05-15 发布日期:2017-10-18

Research on Chemical Precipitation and Flocculation on a Copper Molybdenum Flotation Separation Wastewater

Zhu Yuefeng1,Sun Chunbao2,3,Li Zhengliang2,3,Li Chunbao1,Kou Jue2,3,Li Ying1   

  1. 1.Yunnan Diqing Non-ferrous Metal Co.Ltd.,Diqing 674400,China;2.School of Civil and Resources Engineering,University of Science and Technology Beijing,Beijing 100083,China;3.State Key Laboratory of High-Efficient Mining and Safety of Metal Mines,Ministry of Education,Beijing 100083,China
  • Online:2017-05-15 Published:2017-10-18

摘要: 云南某铜矿铜钼浮选分离废水硫、氟含量非常高,直接回用严重影响铜钼混合浮选指标。试验采用化学沉淀—絮凝沉降法处理该废水,考察了沉淀剂用量、搅拌反应时间对废水脱硫、脱氟的影响,絮凝剂种类、用量、pH值对反应后废水絮凝效果的影响,并对处理前后废水的回用情况进行了对比。研究表明:在废水初始pH=12.5,硫沉淀剂绿矾用量为83.33 g/L,氟沉淀剂石灰用量为40 g/L,搅拌反应时间为60 min情况下,硫去除率为93.37%,氟去除率为98.52%;新型絮凝剂M5250用量为50 mg/L时,澄清水的浊度为8.1 FTU。处理后的铜钼分离废水部分回用于矿石的磨矿和铜钼混浮作业,可明显改善铜钼混浮效果。因此,化学沉淀—絮凝沉降工艺在处理某铜钼分离废水中的硫和氟方面,具有简单、快速、高效的特征,经济效益和环境效益显著。

关键词: 化学沉淀&mdash, 絮凝沉降法, 铜钼分离, 高硫高氟

Abstract: Sulfur and Fluorine content is very high in a copper molybdenum flotation separation waste water of a copper ore in Yunnan,direct reuse seriously affect copper molybdenum mixed flotation index.Test of chemical precipitation-flocculation settlement method is used to deal with waste water,precipitating agent dosage,influence of stirring reaction time on desulfurization and fluorine removal of wastewater,types,dosage,pH value of flocculant on wastewater flocculation effect,and reuse of wastewater before and after processing condition were compared.Research shows that initial wastewater pH = 12.5,sulfur precipitant copperas dosage is 83.33 g/L,fluorine precipitant lime dosage is 40 g/L,stirring reaction time for 60 min,sulfur removal rate was 93.37%,fluorine removal rate is 98.52%;New type flocculant M5250 dosage of 50 mg/L,turbidity of clarify water is 8.1 FTU.Copper molybdenum separation waste water after processing parts used in grinding and copper molybdenum mixed floating operation,can obviously improve copper molybdenum mixed floating effect.Therefore,chemical precipitation-flocculation sedimentation process in dealing with sulfur and fluorine on copper and molybdenum separation wastewater has characteristics of simple,rapid,efficient,economic and environmental benefit is remarkable.

Key words: Chemical precipitation-flocculation process, Copper-molybdenum separation, High sulfide and high fluoride