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金属矿山 ›› 2017, Vol. 46 ›› Issue (10): 163-170.

• 采矿工程 • 上一篇    下一篇

高硫尾砂充填体性能及化学外加剂对其影响

姜关照1,2,吴爱祥1,2,李红1,2   

  1. 1.金属矿山高效开采与安全教育部重点实验室,北京 100083;2.北京科技大学土木与环境工程学院,北京 100083
  • 出版日期:2017-10-15 发布日期:2017-10-15
  • 基金资助:

    北京市科委项目(编号:Z161100001216002)。

High Sulfur Tailings Backfill Properties and Effect of Chemical Additives

Jiang Guanzhao1,2,Wu Aixiang1,2,Li Hong1,2   

  1. 1.Key Laboratory of High-Efficient Mining and Safety of Metal Mines,Ministry of Education,Beijing 100083,China;2.School of Civil and Environmental Engineering,University of Science and Technology Beijing,Beijing 100083,China
  • Online:2017-10-15 Published:2017-10-15

摘要: 金属矿尾矿中通常含有较高的硫,充填尾砂中硫含量过高,会降低后期充填体的强度。采用硫精矿与高硫尾砂共同调节全尾砂中的含硫量,研究含硫尾砂对充填体凝结时间和强度的影响,并根据研究结果提出添加硅酸钠和柠檬酸两种调控措施。试验结果表明,随着尾砂含硫量增加,充填料浆凝结时间延长,充填体强度降低。含硫量低于18%的尾砂充填体28 d强度大于1.2 MPa,可以直接用作充填骨料。硅酸钠添加量低于4%时,促凝效果明显,但由于次生膨胀相的生成,充填体28 d强度出现下降。柠檬酸添加量为0.3%时,充填料浆凝结时间增加不明显,此时充填体28 d强度达到10 MPa,且随养护时间增加未出现降低,满足充填要求。由于充填体早期强度增长受到抑制,导致其结构疏松,不断生成的次生膨胀相产物可以填充水化产物之间空隙,使充填体内部更加密实。

关键词: 高硫尾砂, 含硫量, 充填体性能, 硅酸钠, 柠檬酸

Abstract: The high sulfur content will reduce the strength of backfill.Adopting pyrite concentrate and sulfur tailings to control the sulfur content of tailings,the sulfur tailings effect on setting time and strength of filling body is studied,and according to the research results,two control measures of adding sodium silicate and citric acid are put forward.The results show that with sulfur content of tailings increasing,slurry setting time is longer,filling body strength reducing.The strength of backfill with less than 18% sulfur content is more than 1.2 MPa and the tailings can be used as filling aggregates.The sodium silicate is less than 4%,the accelerating effect is obvious.However,due to the formation of secondary expansion phase,the filling body 28d strength reduces gradually.When the citric acid is 0.3%,the increase of the setting time of the slurry is not obvious,and the body 28d strength reaches 1.0 MPa,and not decrease with the extension of curing time and meets filling requirements.Because the body early strength is restrained,its structure is loose,the secondary expansion phase is formed continuously to fill the pore between hydration product,making the body interior further dense.

Key words: High sulfur tailings, Sulfur content, Filling properties, Sodium silicate, Citric acid