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金属矿山 ›› 2019, Vol. 48 ›› Issue (03): 90-94.

• 矿物工程 • 上一篇    下一篇

某高镁低铁镍型红土镍矿石转底炉法还原提镍试验

王静静1,2,曹志成1,2,高建勇1,2,颜坤1,2   

  1. 1. 北京神雾环境能源科技集团有限公司,北京 102200;2. 北京市劣质铁矿石综合利用工程技术研究中心,北京 102200
  • 出版日期:2019-03-25 发布日期:2019-04-30

Experiment on Reduction and Extraction of Nickel from High-magnesium Low-iron Nickel Laterite by Rotary Hearth Furnace

Wang Jingjing1,2,Cao Zhicheng1,2,Gao Jianyong1,2,Yan Kun1,2   

  1. 1. Beijing Shenwu Environment & Energy Technology Co.,Ltd, Beijing 102200,China;2.Beijing Comprehensive Utilization of Low-Grade Iron Ore, Engineering and Technology Research Center, Beijing 102200,China
  • Online:2019-03-25 Published:2019-04-30

摘要: 某高镁低铁镍型红土镍矿石Fe、Ni品位分别为17.68%和1.62%,MgO含量为19.06%,镍主要以类质同象形式取代Fe、Mg存在于铁氧化物和硅酸盐矿物中,占比分别为39.65%和54.72%。为了确定该矿石的高效开发利用工艺,通过小型基础试验确定还原焙烧和磨选工艺参数,再在中径8 m的转底炉上进行还原焙烧中试试验。结果表明:试样采用煤基直接还原—水淬冷却—2阶段磨矿弱磁选工艺处理,在红土镍矿、石灰石、TN的质量配比为100∶10∶3,按碳氧物质的量之比1.2配入无烟煤,还原焙烧温度为1 280 ℃,还原焙烧时间为40 min,还原焙烧熟料水淬产品一段磨矿细度为-0.074 mm占83.31%,一段弱磁选磁场强度为190.98 kA/m,二段磨矿细度为-0.074 mm占97.43%,二段弱磁选磁场强度为127.32 kA/m的情况下,获得了Ni品位为5.63%、Fe品位为60.39%、Ni回收率为80.83%、Fe回收率为75.14%的镍铁粉;中径8 m的转底炉中试产品经磨选,获得了Ni品位为5.26%、Fe品位为59.20%、Ni回收率为80.84%、Fe回收率为74.98%的镍铁粉。该研究成果可作为工程化的依据,也为同类型红土镍矿石资源的高效开发利用提供了技术借鉴。

关键词: 红土镍矿, 转底炉, 还原, 磨矿, 弱磁选

Abstract: The low-iron, low-nickel and high-magnesium nickel laterite ore was investigated, in which contains 17.68% iron, 1.62 nickel and 19.06% MgO, respectively. Nickel mainly replaces iron and magnesium and exists in the form of isomorphism in iron oxides and silicate minerals, accounting for 39.65% and 54.72%. To determine the high-efficiency development utilization process, small-scale basic tests were conducted to obtain the parameters of the reduction-roasting and grinding-separation process and pilot-scale test was carried out on a rotary hearth furnace with a pitch diameter of 8 m. The results showed that the sample was treated by coal-based direct reduction, water quenching and two-stage grinding and low-intensity magnetic separation. The mass ratio of laterite nickel ore, limestone and TN was 100∶10∶3, mole ratio of C to O was 1.2 (anthracite) , the reduction time was lasted 40 min in the temporary of 1 280 ℃. The water-quenched calciation products at first stage grinding fineness of -0.074 mm accounting for 83.31%, and the magnetic field intensity of first stage low-intensity magnetic separation was 190.98 kA/m, second stage grinding fineness of -0.074 mm accounting for 97.43%, and the magnetic field intensity of second stage low-intensity magnetic separation was 127.32 kA/m. Under the optimal conditions, ferronickel powder product which contains 5.63% nickel and 60.39% iron with recovery of 80.83% and 75.14% can be obtained. The pilot product of the rotary hearth furnace was ground and separated. The obtained ferronickel powder product contains 5.26% nickel and 59.20% iron, while the recovery of nickel and iron were 80.84% and 74.98%, respectively. The research results can be used as the basis for engineering, and can also provide a technical reference for the efficient development and utilization of the same type of laterite nickel ore resources.

Key words: Nickel laterite ore, rotary hearth furnace, direct reduction, grinding, low-intensity magnetic separation