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金属矿山 ›› 2019, Vol. 48 ›› Issue (11): 73-78.

• 矿物工程 • 上一篇    下一篇

国外某沉积岩型难选硫氧混合铜矿石浮选试验

刘方华1,2   

  1. 1. 江西科技学院土木工程学院,江西 南昌 330098;2. 江西科技学院绿色建筑研究所,江西 南昌 330098
  • 出版日期:2019-11-15 发布日期:2020-01-03
  • 基金资助:

    基金项目:建筑安全与环境国家重点实验室暨国家建筑工程技术研究中心开放课题(编号:BSBE2018-10),江西省交通运输厅科技项目(编号:2019H0013),江西省教育厅科学技术研究项目(编号:GJJ171036),江西科技学院校级自然课题(编号:jy1801)。

Flotation Test of a Sedimentary Rock Type Refractory Sulfur-oxygen Mixed Copper Ore in Abroad

Liu Fanghua1,2   

  1. 1. School of Civil Engineering, Jiangxi University of Technology, Nanchang 330098, China; 2. Institute of Green Architecture, Jiangxi University of Technology, Nanchang 330098, China
  • Online:2019-11-15 Published:2020-01-03

摘要: 国外某沉积岩型硫氧混合铜矿石铜品位为2.96%,为确定该矿石的合理开发利用工艺,在工艺矿物学研究的基础上进行了选矿试验研究。结果表明:①矿石中的主要铜矿物有辉铜矿、赤铜矿、孔雀石、硅孔雀石,主要脉石矿物有石英、方解石、白云石;辉铜矿、赤铜矿的嵌布粒度一般在0.02~0.30 mm,孔雀石、硅孔雀石的嵌布粒度主要为0.02~1.20 mm;硫化铜占总铜的60.14%,氧化铜占39.86%。②原矿在磨矿细度为-0.074 mm占73.60%的情况下,先以丁基黄药+乙基黄药为组合捕收剂采用2粗2精1扫流程浮选硫化铜矿物,再以硫化钠为硫化剂、丁基黄药+烷基羟肟酸为捕收剂采用1粗3精2扫流程浮选氧化铜矿物,获得了Cu品位为46.92%、回收率为71.57%的硫化铜精矿和Cu品位为29.23%、回收率为16.08%的氧化铜精矿,总精矿Cu品位为42.17%、回收率为87.65%,选别指标较好。

关键词: 硫化铜矿物, 氧化铜矿物, 浮选, 综合回收

Abstract: The grade of copper is 2.96% in a sedimentary rock type sulfur-oxygen mixed copper ore in abroad. Experimental study on ore dressing was carried out on the basis of technological mineralogy to determine the reasonable development and utilization technology of the ore. The results indicated that: ①The main copper minerals are chalcocite, cuprite, malachite and chrysocolla and the main gangue minerals are quartz, calcite and dolomite. The disseminated grain size of chalcocite and cuprite is generally from 0.02 to 0.30 mm while the disseminated grain size of malachite and chrysocolla is mainly from 0.02 to 1.20 mm. Copper sulfide accounts for 60.14% and copper oxide accounts for 39.86% of the total copper content. ②With the grinding fineness of -0.074 mm accounting for 73.60%, the copper sulfide minerals were floated preferentially using combined collector(butyl xanthate+ethyl xanthate) in the process of two roughing-two cleaning-one scavenging. Then copper oxide minerals were floated in the presence of sodium sulfide as vulcanizing agent and mixed collector(butyl xanthate+alkyl hydroxamic acid) with one roughing-three cleaning-two scavenging process. The copper sulfide concentrate with Cu grade of 46.92% and Cu recovery rate of 71.57%, and copper oxide concentrate with Cu grade 29.23% and Cu recovery rate of 16.08% were achieved. The total copper grade and recovery rate was 42.17% and 87.65%, respectively, which means better separating index.

Key words: Copper sulfide minerals, Copper oxide minerals, Flotation, Comprehensive recovery