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金属矿山 ›› 2020, Vol. 49 ›› Issue (06): 42-47.

• 基因矿物加工专题 • 上一篇    下一篇

影响典型铜矿物可浮性的晶体化学基因研究

孙乾予 1,2,3 印万忠 3 宋振国 2,4   

  1. 1. 清华大学环境学院,北京 110819;2. 矿物加工科学与技术国家重点实验室,北京 100160;3. 东北大学资源与土木工程学院,辽宁 沈阳110819;4.北京矿冶科技集团有限公司,北京 100160
  • 出版日期:2020-06-15 发布日期:2020-06-23
  • 基金资助:

    矿物加工科学与技术国家重点实验室开放基金项目(编号:BGRIMM-KJSKL-2020-01)

Study on the Relationship between Floatability and Genetic Characteristics of Crystal Chemistry of Copper Minerals

Sun Qianyu1,2,3 Yin Wanzhong3 Song Zhenguo2,4   

  1. 1. School of Environment,Tsinghua University,Beijing 100084,China;2. State Key Laboratory of Science and Technology of Mineral Processing,Beijing 100160,China;3. School of Resources and Civil Engineering,Northeastern University, Shenyang 110819,China;4. BGRIMM Technology Group,Beijing 100160,China
  • Online:2020-06-15 Published:2020-06-23

摘要: 为实现“基因矿物加工”系统工程建设,探究基因特征与铜矿浮选的关系,以具有代表性的铜矿物黄铜矿、斑铜矿、孔雀石、蓝铜矿和赤铜矿作为研究对象,通过 XPS、溶解性试验、Zeta 电位、接触角等测试分析及 MS 模拟计算等分析总结了含铜矿物的基因特征。通过浮选试验得到了含铜矿物的天然可浮性为:斑铜矿>黄铜矿> 赤铜矿>孔雀石>蓝铜矿;在乙基钠黄药(NaEX)、丁基钠黄药(NaBX)、异戊基黄药(NaIAX)和丁铵黑药体系下的浮选规律为黄铜矿、斑铜矿有较好的可浮性,而孔雀石、蓝铜矿和赤铜矿的可浮性较差,可浮性优异大致规律为:斑铜矿>黄铜矿>蓝铜矿≈孔雀石>赤铜矿;结合基因特征分析得出含铜矿物的天然可浮性规律与断裂面、断裂键密度和断裂键等基因特征有关,而在 NaEX、NaBX、NaIAX 和丁铵黑药体系下铜矿物的可浮性规律与铜矿物的禁带宽度和表面 S 元素含量基因特征有关。

关键词: 含铜矿物, 基因矿物加工工程, 可浮性 , 基因特征, 晶体化学

Abstract:  In order to realize the systematic engineering construction of gene mineral processing,the relationship between gene characteristics and flotation of copper ore was investigated,this paper takes the representative copper minerals chalcopyrite,bornite,malachite,chalcopyrite and chalcopyrite as the research object,and summarizes the gene characteristics of copper bearing minerals through XPS,solubility test,zeta potential,contact angle test analysis and MS calculation. The floatability of several copper minerals has been studied under natural condition. The natural floatability of copper minerals was obtained by flotation test as follows: bornite>chalcopyrite>>cuprite>malachite>azurite;In sodium ethyl xanthate (NaEX),sodium butyl xanthate(NaBX),isoamyl xanthate(NaIAX)and ammonium butyl aerofloat flotation of chalcopyrite,bornite has good flotability,with malachite and azurite and flotability of cuprite is poorer,general rule is: bornite>chalcopyrite>azurite≈malachite>cuprite.  The results show that the natural floatability of copper minerals is related to the genetic characteristics of fracture surface,fracture bond density and fracture bond,and the floatability of copper minerals is related to the genetic characteristics of band gap width and surface S element content under the flotation reagent of NaEX,NaBX,NaIAX and ammonium butyrate.

Key words: Copper minerals, Genetic mineral processing engineering, Floatability, Genetic characteristics, Crystal chemistry