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金属矿山 ›› 2020, Vol. 49 ›› Issue (11): 100-105.

• 矿物工程 • 上一篇    下一篇

铜铅混合精矿浮选分离铜铅试验研究

蒋万君,王皓,王珊,袁敬杰   

  1. 1. 中国有色金属工业昆明勘察设计研究院有限公司,云南 昆明 650051;2. 四川省冶金地质勘查院,四川 成都 610051
  • 出版日期:2020-11-15 发布日期:2020-12-22

Experimental Study on Cu-Pb Separation of a Copper-lead Mixed Concentrate by Flotation

JIANG Wanjun,WANG Hao,WANG Shan,YUAN Jingjie   

  1. 1. Kunming Prospecting Design Institute of China Nonferrous Metals Industry Co., Ltd., Kunming 650051, China;2. Sichuan Metallurgical Geological Exploration Institute, Chengdu 610051 , China
  • Online:2020-11-15 Published:2020-12-22

摘要: 铜铅锌多金属硫化矿通常先采用混合浮选得到铜铅混合精矿,再将混合精矿进行浮选分离铜和铅,而铜铅分离是该工艺的关键。针对云南某铜铅锌多金属矿铜铅混合浮选获得的混合精矿,进行了铜铅浮选 分离试验研究,考察了脱药预处理及浮选主要因素对铜铅分离的影响。结果表明:铜铅混合精矿使用活性炭脱药可取得较好的试验效果,合适的用量为200 g/t,脱药搅拌时间为10 min。使用组合抑制剂进行抑铅浮铜 ,合适的用量为800 g/t,搅拌时间为10 min,之后依次添加石灰400 g/t、硫酸锌400 g/t、亚硫酸钠300 g/t、丁基黄药+丁铵黑药(5+5)g/t、2号油10 g/t。在优化的试验条件下,最终可分别获得铜品位为24.15% 、铜回收率为80.57%的铜精矿及铅品位为31.63%、铅回收率为65.35%的铅精矿,铜铅分离效果较好,可为该矿石的高效利用提供重要的理论指导和技术支撑。

关键词: 铜铅混合精矿, 浮选, 铜铅分离, 活性炭脱药, 组合抑制剂

Abstract: Bulk flotation was usually utilized to deal with polymetallic sulphide ore bearing Cu,Pb and Zn. Then the obtained mixed concentrate was subjected to separate Cu from Pb by flotation. The separation between Cu and Zn was considered as the crucial step for this process. With respect to a mixed concentrate obtained from Cu-Pb-Zn polymetallic ore by flotation, in this paper, experimental study on Cu-Pb flotation separation was carried out. The effects of reagent removal as well as main parameters of flotation were investigated. The experimental results indicated that favorable separation results were obtained by using activated carbon as reagent removal medium. The optimized dosage of activated carbon was 200 g/t and the stirring time for reagent removal was 10 min. By using combined depressant to float copper-bearing mineral while restraining lead-bearing mineral, the suitable dosage of depressant and stirring time were 800 g/t and 10 min, respectively. After that, lime of 400 g/t, zinc sulfate of 400 g/t, sodium sulfite of 300 g/t, butyl xanthate with ammonium butyrate black drug of (5+5) g/t, and the second oil of 10 g/t were added successively. Under the optimized test conditions, the copper concentrate with the copper grade of 24.15%, the copper recovery rate of 80.57% , and the lead concentrate with the lead grade of 31.63% and the lead recovery rate of 65.35% could be obtained respectively. The separation effect of copper and lead was fine, which laid an important theoretical basis and technical support for the efficient utilization of the studied resource.

Key words: copper-lead mixed concentrate, flotation, separation of the copper and lead, reagent removal with actived carbon, combined inhabitors