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金属矿山 ›› 2020, Vol. 50 ›› Issue (05): 132-136.

• 协同开采 • 上一篇    下一篇

矿山多属性环境协同作用对锚杆腐蚀的影响

吴赛赛,朱昊天,张 雯,程 平,刘 非   

  1. 1. 西安建筑科技大学资源工程学院,陕西 西安 710055;2. 西北有色地质矿业集团有限公司,陕西 西安 710054
  • 出版日期:2020-05-15 发布日期:2020-06-12
  • 基金资助:
    国家自然科学基金项目青年基金项目(编号:51904220),陕西省教育厅基金项目(编号:19JK0454)。

Synergic Influence of Mine Multi-attribute Environments on Rock Bolts Corrosion

Wu Saisai,Zhu Haotian,Zhang Wen,Cheng Ping,Liu Fei   

  1. 1. School of Resources Engineering, Xi'an University of Architecture and Technology, Xi'an 710055,China;2. Northwest Nonferrous Geology and Mining Group Co., Ltd., Xi'an 710054, China
  • Online:2020-05-15 Published:2020-06-12

摘要: 锚固材料失效造成围岩失稳呈现多元化特征,其中锚固材料在服役过程中受到多属性腐蚀环境协同作用造成其腐蚀越来越严重。锚杆腐蚀开裂频繁发生在富黏土地带,反映出多属性环境(包括含氧率、地 下水、矿物质等)协同作用是锚杆腐蚀的重要影响因素。为了掌握锚杆在多属性环境协同作用影响下的腐蚀规律,将锚杆服役环境以“腐蚀细胞”的方式进行了实验室模拟试验。研究表明:环境中的矿物质通过离子 交换增加水溶液离子溶度,间接加速了锚杆的腐蚀,证明了溶液中离子浓度与腐蚀速率成正相关关系;腐蚀是长期的过程,经过3个月的试验后,大部分腐蚀产物形成于螺纹和锚杆端部,以及被黏土与煤包裹的部位, 反映出矿物质能加速锚杆的腐蚀;相比于腐蚀介质仅为去离子水,锚杆在包含黏土或者煤的试验环境中腐蚀后的抗拉强度均有所降低;锚杆在煤和黏土共同作为腐蚀介质且开放的环境下,抗拉强度最小,这也间接说 明矿物质材料能加速锚杆的腐蚀。上述研究进一步表明:环境中煤、黏土、地下水可通过增加溶液总离子浓度提高环境腐蚀性,因此在含有矿物质与地下水的区域,矿山支护设计与维护时需进行防腐蚀方面的考虑。

关键词: 锚杆, 腐蚀, 协同作用, 矿物质

Abstract: The instability of the surrounding rock caused by the failure of anchoring material showed diversity, in which the failure of anchoring material caused by the corrosion at the mine multi-attribute corrosion environment was more and more serious. Rock bolts corrosion cracking occurred frequently in clay-rich areas, which indicated that the synergic influence of mine multi-attribute environments (oxygen content, groundwater and minerals) are the influencing factors. In order to study the law of corrosion under the synergic influence of the mine multi-attribute environments, the rock bolts service environment was simulated in laboratory with the application of “corrosive cell”. The study results showed that the presence of clay indirectly affected the corrosion of rock bolts by increasing the ion concentrations in aqueous solution through the ions exchanges of the minerals. Corrosion is a long-term process, after three months of testing, most of the corrosion products were formed at the end of screw and bolt as well as the part wrapped by clay and coal. The observations indicated that minerals could accelerate the corrosion of rock bolts. Compared with the tensile strength of bolt specimen corroded only by deionized water, the tensile strength of rock bolt specimen corroded by clay or coal decreased. The tensile strength of bolt was the smallest when coal and clay are used as corrosion medium, which indirectly shows that mineral materials can accelerate the corrosion of rock bolt. The study results further show that coal, clay and groundwater in the environment increased the corrosivity of the environment by increasing the total ion concentration of the solution. Therefore, in the area containing minerals and groundwater, the design and maintenance of the support system should be considered in terms of anti- corrosion.

Key words: Rock bolts, Corrosion, Synergic action, Minerals