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金属矿山 ›› 2021, Vol. 50 ›› Issue (01): 55-70.

• “十三五”矿业专题 • 上一篇    下一篇

半导体式矿业安全用气体传感器的制备及其应用研究进展

沈岩柏,李国栋,郝福来,周鹏飞,赵思凯   

  1. 东北大学资源与土木工程学院,辽宁 沈阳 110819
  • 出版日期:2021-01-15 发布日期:2021-01-18
  • 基金资助:
    国家自然科学基金项目(编号:51674067);中央高校基本科研业务费项目(编号:N180102032, N180106002);辽宁省“兴辽英才计划”项目(编号:XLYC1807160)。

Research Progress on the Preparation and Application of Semiconductor Gas Sensors Used for Mining Safety

SHEN Yanbai,LI Guodong,HAO Fulai,ZHOU Pengfei,ZHAO Sikai   

  1. School of Resources and Civil Engineering,Northeastern University,Shenyang 110819,China
  • Online:2021-01-15 Published:2021-01-18

摘要: CH4、H2S、NOx、SO2、CO、H2等矿业有毒有害气体是造成矿山安全事故的主要原因之一,直接危害员工 的身体健康和企业的财产安全,因此对其提前感知和主动预警对矿业安全具有十分重要的意义。气体传感器是一 种能够检测目标气体的种类及浓度,并将其以电信号进行输出的器件,其中半导体式气体传感器具有响应快、灵敏 度高、性能稳定、结构简单、成本低等特点,在气敏研究领域获得广泛关注,且在实际应用中占比最大。半导体式气 体传感器已被成功应用于瓦斯气体的检测,近年来也被应用于监测其他矿业有毒有害气体。介绍了半导体式矿业 安全用气体传感器的工作原理、结构及主要性能参数,阐述了模板法、水热法、溶剂热法、气相反应法、固相反应法、 溶胶-凝胶法、静电纺丝法、微波辅助法等主要的气敏材料制备工艺和目前研究进展,分析了微观结构调控、贵金属 掺杂、构建异质结三种提升半导体材料气敏性能的主要途径,阐述了矿业有毒有害监测用气体传感器的研究现状, 并指明室温响应、高性能、可穿戴气体传感器是未来矿业安全用气体传感器的研究重点。高性能半导体式气体传 感器的研究和推广,对矿产资源勘探及开发过程中产生和排放的有毒有害气体的检测、提高矿山及矿井安全生产、 实现我国矿业资源开发的健康发展具有重要意义。

关键词: 矿业安全, 半导体, 气体传感器, 研究进展

Abstract: Toxic and harmful gases in the mining industry such as CH4,H2S,NOx,SO2,CO,and H2 are one of the main reasons causing mining safety accidents. These gases may directly endanger the health of employees and the safety of the company property. Therefore,it is of great significance to realize early perception and active warning for these gases in mining safety. Gas sensor is a device that can detect the type and concentration of the target gas and output it as an electrical signal. Among different types of gas sensors,the semiconductor gas sensors have many advantages such as fast response, high sensitivity,stable performance,simple structure,and low cost,which makes them receive extensive attention in the research field of gas sensing and account for the largest proportion in practical applications. Semiconductor gas sensors have been successfully applied to the detection of mine gas,and recently they have also been used to monitor other toxic and harmful gases in mining. This paper reports the working principle,structure,and main performance parameters of the semiconductor gas sensors used for mining safety.The main preparation processessuch as template method,hydrothermal method,solvothermal method,gas phase reaction method,solid state reaction method,sol- gel method,electrospinning method,microwave-assisted method are provided,and research progress of the semiconductor gas sensing materials is given. Three main ways to improve the gas sensing performance of semiconductor materials are analyzed,namely microstructure control,noble metal doping,and construction of heterojunctions.In addition,the research status of toxic and harmful gassensors in the mining industry is described. The room-temperature response,high performance,wearable gas sensors are the research focuses on mining-safety gas sensors in the future.The research and promotion of high-performance semiconductor gas sensors are of great significance to the detection of toxic and harmful gases generated and discharged during the exploration and development of mineral resources,to improve the safe production of mines,and to realize the healthy development of mining resources in China.

Key words: mining safety, semiconductor, gas sensor, research progress