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金属矿山 ›› 2021, Vol. 50 ›› Issue (05): 205-210.

• 综合利用 • 上一篇    下一篇

广东某含铜污泥冶炼渣富集工艺研究

饶金山1,2,3 吕昊子1,2,3  陈志强1,2,3  胡红喜1,2,3  刘  勇1,2,3  蒋  英1,2,3   

  1. 1. 广东省科学院资源综合利用研究所,广东 广州 510650;2. 稀有金属分离与综合利用国家重点实验室,广东 广州 510650;3. 广东省矿产资源开发和综合利用重点实验室,广东 广州 510650
  • 出版日期:2021-05-15 发布日期:2021-05-12
  • 基金资助:
    广东省科学院项目(编号:2016GDASRC-0201,2019GDASYL-0302010);广东省基础与应用基础研究基金项目(编号:2020A1515010729)。

BeneficiationTechnology Study on a Smelting Slag from Copper Bearing Sludge in Guangdong

RAO Jinshan1,2,3    Lü Haozi1,2,3    CHEN Zhiqiang1,2,3    HU Hongxi1,2,3    LIU Yong1,2,3    JIANG Ying1,2,3   

  1. 1. Institute of Resources Comprehensive Utilization, Guangdong Academy of Science, Guangzhou 510650, China;2. State Key Laboratory of Rare Metals Separation and Comprehensive Utilization, Guangzhou 510650, China; 3. Guangdong Provincial Key Laboratory of Mineral Resources Development and Comprehensive Utilization, Guangzhou 510650, China
  • Online:2021-05-15 Published:2021-05-12

摘要: 某含铜污泥冶炼渣(以下简称铜渣)含铜3.50%,铜主要以金属铜和铜镍锡合金的形式存在,含铜物质嵌布粒度粗细不均匀,其中-0.01mm难选粒级占55%左右。对该铜渣开展浮选工艺研究,考察了磨矿细度、粗选pH和丁基黄药用量等条件对浮选指标的影响,并进行了全粒级浮选和筛分—浮选流程的开路对比试验。结果表明,在磨矿细度为-0.075 mm占85.76%的条件下,以丁基黄药为捕收剂,松醇油为起泡剂,全粒级开路浮选最终可获得铜品位为20.56%、铜回收率为65.98%的铜精矿;而筛分—浮选最终可获得铜品位15.65%、铜回收率56.52%的浮选铜精矿和铜品位22.56%、铜回收率18.63%的+0.15 mm产品,铜的综合回收率达75.15%,尾矿铜品位降低至0.49%。全粒级闭路浮选中矿易累积,而筛分—浮选闭路试验流程稳定,最终+0.15 mm产品和浮选精矿的综合铜回收率为85.15%、铜品位为11.90%,满足回炉冶炼要求。

关键词: 含铜污泥, 铜渣, 筛分, 浮选

Abstract: A smelting slag from containing copper sludge (referred to as copper slag in the following) contains 3.50% copper, which mainly exists in the form of the metal copper and Cu-Ni-Sn alloy. The dissemination particle size of copper material is not uniform, of which the refractory particle size of -0.01mm accounts for about 55%.The flotation process of copper slag was studied, and the effects of grinding fineness,roughing pH and butyl xanthate dosage on flotation indexes were investigated. The open-circuit comparison tests between whole-grain flotation and sieving and flotation processes were also carried out.The results showed that under the condition of grinding fineness of 85.76% accounting for -0.075 mm with butyl xanthate as collector and terpenol oil as foaming agent, the copper concentrate with copper grade of 20.56% and copper recovery of 65.98% can be obtained by full-grain open-circuit flotation.The copper concentrate with copper grade of 15.65% and copper recovery of 56.52% and +0.15 mm product with copper grade of 22.56% and copper recovery of 18.63% were finally obtained by sieving and flotation. The comprehensive recovery of copper reached 75.15%, and the copper grade of tailings was reduced to 0.49%.The middles of the whole-grain closed circuit flotation are easy to accumulate, and the sieving and flotation closed circuit test process is stable. The final +0.15 mm product and flotation concentrate have a comprehensive copper recovery of 85.15% and a copper grade of 11.90%, which meet the smelting requirements of the furnace.

Key words: copper-bearing sludge, copper smelting slag, screening, flotation