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金属矿山 ›› 2021, Vol. 50 ›› Issue (05): 211-220.

• 综合利用 • 上一篇    

金尾矿砂作为混凝土集料的物化性质及其改性试验

刘竞怡1,2  孙志华2  温久然 刘开平关博文 胡  勇3   

  1. 1. 陕西铁路工程职业技术学院,陕西 渭南 714000;2. 长安大学材料科学与工程学院,陕西 西安 710064;3. 江西秀川科技有限公司,江西 南昌 330000
  • 出版日期:2021-05-15 发布日期:2021-05-12
  • 基金资助:
    中国博士后科学基金项目(编号:2019M653520);江西省赣江新区科技项目(编号:GJK2019007)。

Physical and Chemical Properties of Gold Tailing Sand as Concrete Aggregate and Its Modification Test

LIU Jingyi1,2 SUN Zhihua2 WEN Jiuran2 LIU Kaiping2 GUAN Bowen2 HU Yong3   

  1. 1. Shaanxi Railway Engineering Vocational and Technical College, Weinan 714000, China; 2. School of Materials Science and Engineering, Chang'an University, Xi'an 710064, China;3. Jiangxi Xiuchuan Technology Co., Ltd., Nanchang 330000, China
  • Online:2021-05-15 Published:2021-05-12

摘要: 金尾矿砂是金矿选矿作业排放的固体废弃物,其露天堆存不仅占用土地、污染环境,还造成极大的安全隐患。以金尾矿砂代替天然砂石作为混凝土的集料,既可减少天然砂石的开采,又能实现固废资源化利用。以陕西某金矿尾矿砂作为研究对象,分析了其基本物化性质及作为混凝土集料的物化性质。在此研究基础上,通过改性剂对金尾矿砂进行了表面涂覆改性,将改性后的金尾矿砂取代部分河砂作为全集料进行了混凝土试配试验。结果表明,金矿尾矿砂粒度过细,泥块含量超标,棱角尖锐,直接作为集料对混凝土性能不利;通过改性剂涂覆可有效降低金尾矿砂颗粒间的黏聚力和内摩擦角;在改性剂SA涂覆用量为砂量0.015倍的条件下,金矿尾砂颗粒之间的黏聚力下降约56%,内摩擦角下降约13%;在取代河砂30%的条件下,表面改性后的金尾矿砂制备的无粗集料混凝土样用水量较低,而扩展度及强度明显较高;在砂灰比为1.5的条件下,掺改性金尾矿砂的混凝土强度较无改性样高出20%以上。通过调整砂灰比、用水量以及减水剂量,以改性金尾矿砂取代部分细集料可以配制出不同强度等级及不同流动性的无粗集料混凝土材料,以满足不同建筑工程的使用要求。

关键词: 金尾矿砂, 物化性质, 表面改性, 黏聚力和内摩擦角, 混凝土集料

Abstract: Gold tailing sand is a solid waste discharged from gold ore dressing operation. Its open storage not only occupies land, pollutes the environment, but also causes great safety hidden danger. Using gold tailing sand instead of natural sand as aggregate for concrete can not only reduce the exploitation of natural sand, but also realize the utilization of solid waste resources. The basic physicochemical properties of tailing sand and its physicochemical properties as concrete aggregate are analyzed regarding the tailing sand of a gold mine in Shaanxi Province as the research object. On the basis of this research, the surface of gold tailing sand was modified by modifier, and the modified gold tailing sand replaced part of river sand as the total aggregate to carry out the test of concrete mix. The results showed that the gold tailings sand is of fine particle size with excessive content of clay, sharp edges and corners, which is harmful for the the performance of concrete. Coating with modifier can effectively reduce the cohesion and internal friction angle between gold tailing sand particles. When the coating amount of SA is 0.015 times of sand dosage, the cohesion between gold tailings particles decreases by about 56%, and the internal friction angle decreases by about 13%. Under the condition of replacing 30% river sand, the water consumption of the concrete sample without coarse aggregate prepared by the surface modified gold tailing sand is lower, but the expansion and strength are obviously higher. When the sand-cement ratio is 1.5, the strength of concrete mixed with modified gold tailing sand is more than 20% higher than that without modification. By adjusting the ratio of sand to cement, water consumption and dosage of water reduction, the concrete materials without coarse aggregate with different strength grades and fluidity can be prepared by replacing some fine aggregates with modified gold tailing sand, so as to meet the requirements of different construction projects.

Key words: gold tailings sand, physical and chemical properties, surface modification, cohesion and internal friction angle, concrete aggregate