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金属矿山 ›› 2022, Vol. 51 ›› Issue (01): 65-70.

• 工业固废资源化利用新理论与新技术 • 上一篇    下一篇

基于不同机械活化方式的二元固废混凝土抗压性能研究

王凤丹1胥孝川1顾晓薇1张延年2张信龙3王青1   

  1. 1.东北大学智慧水利与资源环境科技创新中心,辽宁 沈阳 110819;2.沈阳建筑大学土木工程学院,辽宁 沈阳 110168;3.中国建筑东北设计研究院有限公司,辽宁 沈阳 110006
  • 出版日期:2022-01-15 发布日期:2022-02-14

Study on the Compressive Performance of Binary Solid Wastes Concrete Based on Different Mechanical Activation Methods

WANG Fengdan1XU Xiaochuan1GU Xiaowei1ZHANG Yannian2ZHANG Xinlong3WANG Qing1   

  1. 1.Technology Innovation Center for Intelligent Water Resources and Environment,Northeastern University,Shenyang 110819,China;2.School of Civil Engineering,Shenyang Jianzhu University,Shenyang 110168,China;3.China Northeast Architectural Design & Research Institute Co.,Ltd.,Shenyang 110006,China
  • Online:2022-01-15 Published:2022-02-14
  • Supported by:
    “十三五”国家重点研发计划项目(编号:2019YFC1907202);国家自然科学基金面上项目(编号:52074061);国家自然科学基金面上项目(编号:51974060);国家自然科学基金联合基金项目(编号:U1903216);辽宁省重大科技专项(编号:2020JH1/10300005);辽宁省“兴辽英才计划”项目(编号:XLYC1905016)

摘要: 为了改善二元固废混凝土的抗压性能,基于不同机械活化方式研究了铁尾矿-粉煤灰复合掺合料对二元固废混凝土抗压性能的影响,并采用X射线衍射、扫描电镜和热重分析等检测手段探究了铁尾矿-粉煤灰复合掺合料混凝土抗压强度增强的水化机理。当采用先掺后磨的机械活化方式时,铁尾矿-粉煤灰复合掺合料的混凝土抗压强度增强效果最明显,28 d龄期可达70.6 MPa。不同机械活化方式导致水化产物结构不同,同时改变了掺合料参与二次水化反应的程度;采用先掺后磨的机械活化方式,能促进水泥熟料的进一步水化,消耗更多Ca(OH)2参与二次水化反应,生成更多更致密的网状C—S—H凝胶。从混凝土抗压强度及混凝土胶凝材料的水化硬化机理来看,采用先掺后磨的机械活化方式活化效果更优,利于二元固废混凝土的强度发展。

关键词: 混凝土, 铁尾矿, 粉煤灰, 二元掺合料, 抗压强度

Abstract: In order to improve the compressive performance of binary solid waste concrete,the effect of iron tailingsfly ash composite admixture on the compressive performance of binary solid waste concrete was investigated based on different mechanical activation methods.The hydration mechanism of compressive strength enhancement of iron tailingsfly ash composite admixture concrete was analyzed by using tests such as Xray diffraction (XRD),scanning electron microscopy (SEM) and thermogravimetric (TGDSC) analysis.The compressive strength enhancement of concrete with iron tailingsfly ash composite admixture was most obvious when the mechanical activation method of blended before grinded was adopted,reaching 70.6 MPa at 28 d of age.Different mechanical activation methods lead to different structures of hydration products,while changed the degree of involvement of the admixture in the secondary hydration reaction.The mechanical activation method of blended before grinded can contribute to the further hydration of cement clinker,consume more Ca(OH)2 to participate in the secondary hydration reaction and generate more and denser reticular C—S—H gels.From the point of view of concrete compressive strength and the hydration and hardening mechanism of concrete cementing materials,the activation effect of mechanical activation by blended before grinded was better,which facilitated the strength development of binary solid waste concrete.

Key words: concrete, iron tailings, fly ash, binary admixture, compressive strength