欢迎访问《金属矿山》杂志官方网站,今天是 分享到:
×

扫码分享

金属矿山 ›› 2022, Vol. 51 ›› Issue (07): 198-205.

• 矿物工程 • 上一篇    下一篇

铝土矿选洗矿泥混凝沉降试验及机理研究

韦桥权1成官文1张宇玲1张正林2黄振艺2农国武2   

  1. 1.桂林理工大学环境科学与工程学院,广西 桂林 541006;2.中国铝业股份有限公司广西分公司,广西 平果 531400
  • 出版日期:2022-07-15 发布日期:2022-07-31
  • 基金资助:
    广西重点研发计划项目(编号:桂科 AB20297039);中国铝业股份有限公司科技攻关项目(编号:gxzz201903)。

Experimental and Mechanism Research on Coagulation Settlement of Bauxite Ore Dressing Slime

WEI Qiaoquan1CHENG Guanwen1ZHANG Yuling1ZHANG Zhenglin2HUANG Zhenyi2NONG Guowu2   

  1. 1.College of Environmental Science and Engineering,Guilin University of Technology,Guilin 541006,China;2.Guangxi Branch of Aluminum Corporation of China Limited,Pingguo 531400,China
  • Online:2022-07-15 Published:2022-07-31

摘要: 铝土矿选洗矿泥具有颗粒细小、带负电、呈流态状、pH呈弱碱性等特点,难以自然沉降。为改善矿泥的混凝沉降效果,以平果铝业三期矿泥为研究对象,考察了聚合氯化铝(PAC)、聚合氯化铁(PFC)和聚丙烯酰胺(PAM)对矿泥的混凝沉降性能,并对其作用机理进行了研究。结果表明:投加PAC或PFC使矿泥体系pH降低、电导率升高、矿泥颗粒Zeta电位增大、粒径变小,沉降效果较差,PAC或PFC不适合作为该铝土矿矿泥的混凝剂;阴离子型聚丙烯酰胺(APAM)主要利用极性基团—CONH2与矿泥中的高岭石和一水硬铝石发生氢键作用,矿泥混凝沉降效果明显,适宜投加量为40~60 g/t,最佳投加量为60 g/t;非离子型聚丙烯酰胺(NPAM)主要利用大分子链缠绕包裹作用,矿泥混凝沉降效果较明显,适宜投加量为50~70 g/t,最佳投加量为70 g/t;阳离子型聚丙烯酰胺(CPAM)主要利用静电吸附作用对矿泥颗粒进行吸附,矿泥混凝沉降效果一般,适宜投加量为60~80 g/t,最佳投加量为80 g/t。

关键词: 铝土矿矿泥, 沉降特性, pH值, Zeta电位分析, 电导率分析, 粒径分布, FTIR分析

Abstract: Bauxite ore dressing slime has the characteristics of small particles,negatively charged,fluid state and pH of weakly alkaline,which is difficult to settle naturally.In order to improve the coagulation and settlement effect of the slime,take the slime produced in the third stage of Pingguo Aluminum as the research object,investigate the coagulation and settling performance of polyaluminum aluminum chloride (PAC),polyaluminum ferric chloride (PFC) and polyacrylamide (PAM) on the slime,and study their mechanism of action.The results showed that the addition of PAC or PFC makes the pH of the slime system decrease,the conductivity increases,the Zeta potential of the slime particles increases,the particle size becomes smaller,and the sedimentation effect is poor.PAC or PFC is not suitable as a coagulant for the slime.Anionic polyacrylamide (APAM) mainly uses the polar group —CONH2 to hydrogen bond with the kaolinite and diaspore in the slime,the coagulation and sedimentation effect of the sludge is very obvious,the suitable dosage is 40~60 g/t,and the best dosage is 60 g/t.Non-ionic polyacrylamide (NPAM) mainly uses macromolecular chains to wrap around,and the coagulation and sedimentation effect of the sludge is obvious,the suitable dosage is 50~70 g/t,and the best dosage is 70 g/t.Cationic polyacrylamide (CPAM) mainly uses electrostatic adsorption to adsorb sludge particles,the coagulation and sedimentation effect of sludge is average,the suitable dosage is 60~80 g/t,and the best dosage is 80 g/t.

Key words: bauxite ore slime,settlement characteristic,pH value,Zeta potential analysis,conductivity analysis,particle size distribution,FTIR analysis