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金属矿山 ›› 2022, Vol. 51 ›› Issue (09): 100-106.

• 矿物工程 • 上一篇    下一篇

磨矿方式对闪锌矿和黄铁矿浮选动力学影响研究

高恩霞1,2 张春1 李悦鹏1 罗建辉1 高瑞琢3 冉金城1
  

  1. 1. 山东理工大学资源与环境工程学院,山东 淄博 255000;2. 山东招金科技有限公司,山东 烟台 265400;3. 青岛金星矿业股份有限公司,山东 青岛 266748
  • 出版日期:2022-09-15 发布日期:2022-10-13
  • 基金资助:
    国家自然科学基金项目(编号:52104259);山东省自然科学基金项目(编号:ZR2020QB192)

Effects of Grinding Methods on the Flotation Kinetics of Sphalerite and Pyrite

GAO Enxia1,2 ZHANG Chun1 LI Yuepeng1 LUO Jianhui1 GAO Ruizhuo3 RAN Jincheng1   

  1. 1. School of Resources and Environmental Engineering,Shandong University of Technology,Zibo 255000,China;2. Shandong Zhaojin Technology Company Limited,Yantai 265400,China;3. Qingdao Jinxing Mining Company Limited,Qingdao 266748,China
  • Online:2022-09-15 Published:2022-10-13

摘要: 为了研究磨矿方式对闪锌矿和黄铁矿浮选行为的影响,通过 6 种浮选动力学模型,分别考察了干磨、湿磨及磨矿时间下 2 种矿物的粒度组成及动力学参数。 结果表明,6 种动力学模型均表现出了良好的拟合效果。 氧化速率、磨矿方式、粒度组成共同决定了闪锌矿和黄铁矿的浮选表现。其中,黄铁矿较闪锌矿具更高的氧化速率及更低的浮选回收率。 湿磨产品较干磨更细,所有试验中-0.015 mm 微细粒级的产率最高,这有利于新生表面的暴露,并导致黄铁矿的快速富集,但同时释放更多 Fe3+,降低了闪锌矿的浮选速率。干磨产品粒度组成更粗且颗粒表面粗糙度更高,这促使闪锌矿和黄铁矿干磨后的 ε 值较湿磨更高。

关键词: 磨矿方式, 闪锌矿, 黄铁矿, 浮选动力学, 粒度

Abstract: In order to study the effects of grinding methods on the flotation performance of sphalerite and pyrite,the particle size composition and flotation kinetic parameters of these two minerals under different grinding methods and grinding time were investigated by six flotation kinetic models. The results showed that all the six models can well fitted the flotation test data. The flotation performances of sphalerite and pyrite were determined by oxidation rate,grinding method and particle size composition. Pyrite presented a higher oxidation rate and lower flotation recovery compared with sphalerite. The products obtained from wet grinding were finer than dry grinding. In all tests,the yield of -0. 015 mm size fraction was the highest,which was conducive to the exposure of more new surface and led to the rapid enrichment of pyrite. However,wet grinding accelerated the dissolution of Fe3+ from the grinding medium,which reduced the flotation rate of sphalerite. The dry grinding samples exhibited coarser particle size composition and higher surface roughness,inducing higher ε∞ values of sphalerite and pyrite compared with wet grinding.