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金属矿山 ›› 2022, Vol. 51 ›› Issue (09): 140-145.

• 矿物工程 • 上一篇    下一篇

磨矿介质对氰化尾渣浸出提金效果的影响研究

王家奇1,2 李艳军1,2 余建文1,2 徐海龙1,2 张小龙1,2
  

  1. 1. 东北大学资源与土木工程学院,辽宁 沈阳 110819;2. 难采选铁矿资源高效开发利用技术国家地方联合工程研究中心,辽宁 沈阳 110819
  • 出版日期:2022-09-15 发布日期:2022-10-13
  • 基金资助:
    国家自然科学基金项目(编号:52074067,52104248);中国博士后科学基金项目(编号:2021M700724)

Influence of Grinding Medium on Leaching Effect of Cyanide Tailings for Gold Extraction

WANG Jiaqi1,2 LI Yanjun1,2 YU Jianwen1,2 XU Hailong1,2 ZHANG Xiaolong1,2   

  1. 1. School of Resources and Civil Engineering,Northeastern University,Shenyang 110819,China;2. National-local Joint Engineering Research Center of High-efficient Exploitation Technology for Refractory Iron Ore Resources,Shenyang 110819,China
  • Online:2022-09-15 Published:2022-10-13

摘要: 为对比陶瓷介质和铸铁介质搅拌磨矿对氰化尾渣中金浸出效果的影响,以中国黄金集团三和金业有限公司的金矿氰化尾渣为研究对象,开展了浸出提金试验。研究结果表明,在磨矿细度-6 μm 占 90%、JC 浸出剂用量 40 kg / t 及浸出时间 12 h 的条件下,采用陶瓷介质磨矿可获得浸出渣 Au 1. 29 g / t、浸出率 54. 45%的技术指标,采用铸铁介质磨矿可获得浸出渣 Au 2. 15 g / t、浸出率 39. 45%的技术指标。与传统铸铁介质磨矿相比,陶瓷介质磨矿条件下金的浸出率显著提高。 在陶瓷介质磨矿过程中加入 Fe3+后,金的浸出效果明显下降,表明 Fe3+的加入不利于金的浸出。 机理分析表明,铸铁介质磨矿过程中会产生Fe3+,Fe3+会在矿物表面形成羟基氧化铁( FeOOH),阻碍了 CN-的扩散过程,恶化浸出环境,从而降低了金的浸出率。

关键词: 磨矿介质, 搅拌磨, 氰化尾渣, 浸出, 铁离子

Abstract: In order to compare the influence of ceramic medium and cast iron medium stirring grinding on the leaching effect of gold in cyanide tailings,the gold leaching tailings of China Gold Group Sanhe Gold Industry Co. ,Ltd. were taken as the research object,and the gold leaching experiment was carried out. The research results show that the optimal process parameters in this experiment are grinding fineness of -6 μm accounting for 90%,dosage of JC leaching agent of 40 kg / t and leaching time of 12 h. Under the optimal process parameters,the technical indicators of leaching slag Au grade of 1. 29 g / t and leaching rate of 54. 45% can be obtained by using ceramic media grinding,and the technical indicators of leaching slag Au grade of 2. 15 g / t and leaching rate of 39. 45% can be obtained by using cast iron medium grinding. The leaching rate of gold under the condition of ceramic media grinding is significantly higher than that of traditional cast iron media grinding. After adding Fe3+ in the ceramic media grinding process,the leaching effect of gold was significantly decreased,indicating that the addition of Fe3+ was not conducive to the leaching of gold. Mechanism analysis shows that Fe3+ will be generated during the grinding process of cast iron medium,and Fe3+ will form iron oxyhydroxide (FeOOH) on the mineral surface,which hinders the diffusion process of CN- and deteriorates the leaching environment,thereby reducing the leaching rate of gold.