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金属矿山 ›› 2022, Vol. 51 ›› Issue (09): 238-243.

• 综合利用 • 上一篇    下一篇

碱激发赤泥基可控低强度材料的制备与性能研究

宋迪1 庞来学1 杨达1 卢明阳1 赵永强2 陈仁山1
  

  1. 1. 山东交通学院交通土建工程学院,山东 济南 250357;2. 山东江泰建材科技有限公司,山东 济南 250014
  • 出版日期:2022-09-15 发布日期:2022-10-13
  • 基金资助:
    山东省自然科学基金项目(编号:ZR2020ME231);山东省重点扶持区域引进急需紧缺人才项目(编号:2021);2019年省级水利科研与技术推广项目(编号:SDSLKY201909)

Study on Preparation and Properties of Controlled Low Strength Materials with Alkali Activated Red Mud

SONG Di1 PANG Laixue1 YANG Da1 LU Mingyang1 ZHAO Yongqiang2 CHEN Renshan1   

  1. 1. College of Transportation Civil Engineering,Shandong Jiaotong University,Jinan 250357,China;2. Shandong Jiangtai Building Materials Science and Technology Co. ,Ltd. ,Jinan 250014,China
  • Online:2022-09-15 Published:2022-10-13

摘要: 以赤泥、粉煤灰以及矿粉为原材料,NaOH 为激发剂、聚羧酸减水剂为分散剂制备了可控低强度材料,研究了不同赤泥、粉煤灰配比下材料的工作性能和力学性能。当赤泥与粉煤灰的质量比为 2 ∶ 1、矿粉的掺量为 10%, NaOH 掺量为 1. 5%时,拌合物流动度最高为 236 mm,试件 28 d 的无侧限抗压强度最大为 6. 5 MPa,满足可控低强度材料的规范要求。利用 XRD、FTIR、SEM 探究了可控低强度材料的矿物组成、微观结构,结果发现赤泥、粉煤灰以及矿粉在 NaOH 作用下水化形成了 C—S—H、钙矾石(AFt)以及少量水化硫铁酸钙、C4AF;材料的强度发展与水化产物的絮状、蜂窝状以及片状结构密切相关。研究结果为工业固废在可控低强度材料领域的规模化应用提供了新的技术途径。

关键词: 化学活化, 赤泥, 粉煤灰, 无侧限抗压强度, 流动性

Abstract: Controlled low-strength materials(CLSM) were prepared with red mud,fly ash and mineral powder as raw materials,NaOH as activator and polycarboxylate superplasticizer as dispersant. The working and mechanical properties of the materials under different mixture ratios of red mud and fly ash were studied. When the dosage of red mud and fly ash is 2 ∶1,the dosage of mineral powder is 10% and the dosage of NaOH is 1. 5%,the maximum fluidity of mixing flow is 236 mm,and the maximum unconfined compressive strength of the specimen at 28 days is 6. 5 MPa,which meets the specification requirements of controlled low-strength materials. XRD,FTIR and SEM were used to explore the mineral composition and microstructure of controlled low-strength materials. It was found that red mud,fly ash and mineral powder were hydrated to form C—S—H,AFt, a small amount of hydrated calcium pyrite and C4AF. The strength development of materials depends on the microstructure of flocculent,honeycomb and sheet. The research results provide a new technical way for the large-scale application of industrial solid waste in the field of controlled low-strength materials.